Cold DeNOx development for oxyfuel power plants

Flue gas purification is a necessary method to avoid emission of sour gases like SO_x and NO_x into the environment. Another important aspect is the zero CO₂ emission from coal-fired power plants. Oxyfuel technology is one of the processes to reach this goal. LINDE KCA Dresden in cooperation with Vattenfall Europe is operating a pilot plant producing liquefied CO₂. Product specification and material requirements make flue gas purification for the removal of SO_x and NO_x unavoidable. The new oxyfuel technologies offer new process conditions for flue gas purification which are not available at atmospheric conditions.At Linde laboratories, catalytic and non-catalytic DeNOx and DeSOx processes have been screened for oxyfuel application. After first feasibility studies, laboratory experiments and economic evaluations, it was decided to develop a process based on wet scrubber systems to remove NO_x from flue gas, simultaneously producing ammonia nitrites which can be thermally decomposed into nitrogen in a second step. After demonstration of the single process steps on laboratory scale, a pilot scrubber was erected and commissioned in 2010 at Schwarze Pumpe Oxyfuel Pilot Plant. In September 2010, the successful completion of the pilot tests demonstrated the NO_x removal efficiency of this technology. The data from the pilot plant tests have been used to finalise a kinetic model describing the NO_x absorption behaviour regarding NO_x removal rate and nitrite selectivity for demonstration of plant scale up. This DeNOx-process is now marketed under the name “LICONOX”.     

Dealing with double trouble: consequences of single and double herbivory in Brassica juncea

In their natural environment, plants are often attacked simultaneously by many insect species. The specificity of induced plant responses that is reported after single herbivore attacks may be compromised under double herbivory and this may influence later arriving herbivores. The present study focuses on the dynamics of induced plant responses induced by single and double herbivory, and their effects on successive herbivores. Morphological (leaf length, area and trichome density) and chemical changes (leaf alkenyl and indole glucosinolates) in Brassica juncea were evaluated 4, 10, 14 and 20 days after damage by the specialist Plutella xylostella alone, or together with the generalist Spodoptera litura. To assess the biological effect of the plant’s responses, the preference and performance of both herbivores on previously induced plants were measured. We found that alkenyl glucosinolates were induced 20 days after damage by P. xylostella alone, whereas their levels were elevated as early as 4 days after double herbivory. Trichome density was increased in both treatments, but was higher after double herbivory. Interestingly, there was an overall decrease in indole glucosinolates and an increase in leaf size due to damage by P. xylostella, which was not observed during double damage. S. litura preferred and performed better on undamaged plants, whereas P. xylostella preferred damaged plants and performed better on plants damaged 14 and 10 days after single and double herbivory, respectively. Our results suggest that temporal studies involving single versus multiple attacker situations are necessary to comprehend the role of induced plant responses in plant–herbivore interactions.     

Prenatal diagnosis of Pierre–Robin sequence as part of Stickler syndrome

Stickler syndrome or hereditary progressive arthro-ophthalmopathy, is an autosomal dominant condition characterized by ocular manifestations, arthritic changes, orofacial features and deafness, in variable degrees. We report the first case of prenatal diagnosis of Stickler syndrome in a child with a Pierre–Robin sequence (PRS) causing a polyhydramnios. When isolated polyhydramnios is not explained by immunological, metabolic or infectious causes, swallowing difficulty due to PRS must be considered. As PRS is aetiologically heterogenous, the prognosis depends on the cause. Genetic investigations and familial history must be taken into account. Here, in a context of familial Stickler syndrome, making the prenatal diagnosis of PRS as part of Stickler syndrome allowed us to reassure the parents and to anticipate airway trouble at the child's birth. Copyright © 2002 John Wiley & Sons, Ltd.     

EVALUATION OF NITRATE DATA IN THE OCKLAWAHA RIVER BASIN,FLORIDA (1953–2002)1

ABSTRACT: Nitrate levels in the Ocklawaha River Basin in north central Florida were reviewed over a 50‐year period. Data were obtained from the literature, U.S. Environmental Protection Agency (USEPA) STOrage and RETrieval (STORET), and U.S. Geological Survey (USGS) databases. The study objective was to determine whether nitrate concentrations are increasing and if so, whether this increase is linked to land use changes. Increasing nitrate levels were seen at 5 of the 14 stations, while other stations showed no trend or a decreasing trend. Median nitrate concentrations in the Ocklawaha River increased from 0.07 mg‐N/L to 0.78 mg‐N/L at sites downstream from the Silver River. Throughout the Rodman Reservoir, median nitrate concentrations decreased from 0.48 mg‐N/L to 0.01 mg‐N/L and increased to 0.04 mg‐N/L after the Kirkpatrick Dam. Flow and concentration relationships were correlated for five stations. At four of the five stations nitrate concentrations decreased in response to increasing flow, likely the result of dilution with nitrate poor water. Changes in land use over a 20‐ year period (1970 to 1990) also were monitored. Sources of nitrate have been linked by isotopic analysis to organic and inorganic fertilizers, which appear to be related to increased urbanization and an increase in lawns that require nutrient fertilization.     

From the Editors

Editorial Introduction

From the Editors     

Identifying the sources and timing of ancient and medieval atmospheric lead pollution in England using a peat profile from Lindow bog, Manchester

A peat core from Lindow bog near Manchester, England, was precisely cut into 2 cm slices to provide a high-resolution reconstruction of atmospheric Pb deposition. Radiocarbon and (210)Pb age dates show that the peat core represents the period ca. 2000 BC to AD 1800. Eleven radiocarbon age dates of bulk peat samples reveal a linear age-depth relationship with an average temporal resolution of 18.5 years per cm, or 37 years per sample. Using the Pb/Ti ratio to calculate the rates of anthropogenic, atmospheric Pb deposition, the profile reveals Pb contamination first appearing in peat samples dating from ca. 900 BC which clearly pre-date Roman mining activities. Using TIMS, MC-ICP-MS, and SF-ICP-MS to measure the isotopic composition of Pb, the (208)Pb/(206)Pb and (206)Pb/(207)Pb data indicate that English ores were the predominant sources during the pre-Roman, Roman, and Medieval Periods. The study shows that detailed studies of peat profiles from ombrotrophic bogs, using appropriate preparatory and analytical methods, can provide new insight into the timing, intensity, and predominant sources of atmospheric Pb contamination, even in samples dating from ancient times.