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211.
Johannes Fresner Jürgen Jantschgi Stefan Birkel Josef Bärnthaler Christina Krenn 《Journal of Cleaner Production》2010,18(2):128-136
Cleaner Production is an organized approach to minimize industrial waste and emissions by increasing the efficiency of the use of materials and energy. It is propagated especially by UNIDO and UNEP as an approach to identify preventive measures to cut on waste and emissions from industrial activities. Case studies conducted by the authors in the last 10 years demonstrate, that in a number of cases water consumption per production unit of industries from the surface treatment sector, from food processing and from the textile industry could be reduced by 30–90%, auxiliary materials consumption could be reduced by 30–50%, and energy consumption of processes could be reduced by 15–25%. All these measures were actually economically beneficial for the companies, most of these measures paid back in less than one year [1].The standard approach to apply Cleaner Production originates from chemical engineering. It follows the steps of: Drawing a process flow sheet – collecting input/output data – doing mass and energy balances – identify sources for waste and emissions – set priorities – identify options. In the process of option generation one generally relies on expert knowledge or on checklists which are available in different manuals or in the best available technology reference (BREF) notes.1 This approach is strong with teams with an (chemical) engineering background.The authors wanted to develop a generic approach for option identification especially for teams with little formal engineering background or teams which have to go beyond their professional experience by using elements of the so-called TRIZ method (Theory of inventive problem solving, or originally Russian: “” (Teoria reschenija isobretatjelskich sadatsch)). TRIZ offers very strong tools for developing process improvement options on a generic level without specific technological knowledge about the process which shall be improved. The authors have found from their research that especially the concept of the Ideal Final Result, and the Laws of Evolution form a conceptual framework which can aid effectively in the identification of improvement options in a systematic way. 相似文献
212.
Daniel Hunkeler Patrick Hhener Stefano Bernasconi Josef Zeyer 《Journal of contaminant hydrology》1999,37(3-4)
A concept is proposed to assess in situ petroleum hydrocarbon mineralization by combining data on oxidant consumption, production of reduced species, CH4, alkalinity and dissolved inorganic carbon (DIC) with measurements of stable isotope ratios. The concept was applied to a diesel fuel contaminated aquifer in Menziken, Switzerland, which was treated by engineered in situ bioremediation. In the contaminated aquifer, added oxidants (O2 and NO3−) were consumed, elevated concentrations of Fe(II), Mn(II), CH4, alkalinity and DIC were detected and the DIC was generally depleted in 13C compared to the background. The DIC production was larger than expected based on the consumption of dissolved oxidants and the production of reduced species. Stable carbon isotope balances revealed that the DIC production in the aquifer originated mainly from microbial petroleum hydrocarbon mineralization, and that geochemical reactions such as carbonate dissolution produced little DIC. This suggests that petroleum hydrocarbon mineralization can be underestimated if it is determined based on concentrations of dissolved oxidants and reduced species. 相似文献
213.
Barel-Cohen K Shore LS Shemesh M Wenzel A Mueller J Kronfeld-Schor N 《Journal of environmental management》2006,78(1):16-23
Natural (estradiol, estrone, testosterone, estriol) and synthetic hormones (ethinylestradiol) are constantly excreted into the environment from human and animal sources but little is known of their transport. The purpose of this study was to determine how far along a 100 km river course that hormones could be detected after contamination with sewage effluent or fishpond effluent. Fourteen sites in the Lower Jordan River drainage were sampled (two sites above the sewage effluent contamination, eight sites below the contamination and four tributaries) before and after the dry season of 2002 (Spring and Fall). Samples were tested for testosterone, estrogen (estrone and estradiol combined), estriol, ethinylestradiol, ammonia and fecal coli. It was found that the fecal coli count dropped exponentially (from 250,000 to 60/100 ml3) and the ammonia dropped from 15 to less than 1mg/l over the initial 25 km stretch. Over the same stretch, the hormone values declined by half from their maximum values for testosterone (3.3 ng/l), estriol (8.8 ng/l), ethinylestradiol (6.1 ng/l), and estrogen (4.9 ng/l). From 67 to 100 km mark, testosterone (4.8 ng/l) and estrogen (2.4 ng/l) were still elevated while ethinylestradiol and estriol were >or=1.5 ng/l. The high level of testosterone and estrogen between 67 and 100 km marks was probably due to major discharge from fishponds between 23 and 27 km marks. Levels of ethinylestradiol above 1 ng/l, a level which can affect fish, was seen in 70% (12/16) of the samples tested. The data suggest that hormones in readily measured quantities can be transported considerable distances from the source of pollution. 相似文献
214.
Gutiérrez Miriam Molero Rafael Gaju Miquel van der Steen Josef Porrini Claudio Ruiz José Antonio 《Environmental science and pollution research international》2020,27(10):10436-10448
Environmental Science and Pollution Research - Nectar of honeybee colonies has been used in order to identify heavy metals and establish the benefit of this type of studies as a tool for... 相似文献
215.
Markéta Měrková Markéta Julinová Josef Houser Jan Růžička 《Journal of Polymers and the Environment》2018,26(6):2227-2233
Due to its widespread use and water solubility, poly(vinyl alcohol) (PVA) has the potential to find its way into various water or soil ecosystems. Despite the fact that many bacterial species with the capacity of utilizing PVA have been found and described, the influences of some environmental factors on their capabilities to biodegrade PVA have not been adequately studied. Therefore, study was made of the effects of two environmental factors on PVA degradation exhibited by two Sphingomonas strains. Both strains originated from common wastewater treatment plants, and proved to be considerably sensitive to increased inorganic salt concentrations; in brief, 13.3 mmol/l either of phosphate or chloride ions significantly delayed the degradation process or inhibited it entirely. In contrast to such halosensitivity, both strains were able to rapidly utilize PVA under suitable conditions, even when low inoculum sizes were applied. Initial cell densities, ranging from 100 to 107 cells/ml, were used in two series of degradation trials and PVA degradation occurred in all cases; merely delays extending over several days in the degradation process were noted when inoculum sizes of 100–103 cells/ml were applied. 相似文献
216.
Radka Kodeov Nadia Vignozzi Marcela Rohokov Tereza Hjkov Martin Ko
rek Marcello Pagliai Josef Kozk Jirka imnek 《Journal of contaminant hydrology》2009,104(1-4):107
When soil structure varies in different soil types and the horizons of these soil types, it has a significant impact on water flow and contaminant transport in soils. This paper focuses on the effect of soil structure variations on the transport of pesticides in the soil above the water table. Transport of a pesticide (chlorotoluron) initially applied on soil columns taken from various horizons of three different soil types (Haplic Luvisol, Greyic Phaeozem and Haplic Cambisol) was studied using two scenarios of ponding infiltration. The highest infiltration rate and pesticide mobility were observed for the Bt1 horizon of Haplic Luvisol that exhibited a well-developed prismatic structure. The lowest infiltration rate was measured for the Bw horizon of Haplic Cambisol, which had a poorly developed soil structure and a low fraction of large capillary pores and gravitational pores. Water infiltration rates were reduced during the experiments by a soil structure breakdown, swelling of clay and/or air entrapped in soil samples. The largest soil structure breakdown and infiltration decrease was observed for the Ap horizon of Haplic Luvisol due to the low aggregate stability of the initially well-aggregated soil. Single-porosity and dual-permeability (with matrix and macropore domains) flow models in HYDRUS-1D were used to estimate soil hydraulic parameters via numerical inversion using data from the first infiltration experiment. A fraction of the macropore domain in the dual-permeability model was estimated using the micro-morphological images. Final soil hydraulic parameters determined using the single-porosity and dual-permeability models were subsequently used to optimize solute transport parameters. To improve numerical inversion results, the two-site sorption model was also applied. Although structural changes observed during the experiment affected water flow and solute transport, the dual-permeability model together with the two-site sorption model proved to be able to approximate experimental data. 相似文献
217.
Methanotrophic activity in a diffusive methane/oxygen counter-gradient in an unsaturated porous medium 总被引:1,自引:0,他引:1
Microbial methane (CH4) oxidation is a main control on emissions of this important greenhouse gas from ecosystems such as contaminated aquifers or wetlands under aerobic onditions. Due to a lack of suitable model systems, we designed a laboratory column to study this process in diffusional CH4/O2 counter-gradients in unsaturated porous media. Analysis and simulations of the steady-state CH4, CO2 and O2 gas profiles showed that in a 15-cm-deep active zone, CH4 oxidation followed first-order kinetics with respect to CH4 with a high apparent first-order rate constant of approximately 30 h(-1). Total cell counts obtained using DAPI-staining suggested growth of methanotrophic bacteria, resulting in a high capacity for CH4 oxidation. This together with apparent tolerance to anoxic conditions enabled a rapid response of the methanotrophic community to changing substrate availability, which was induced by changes in O2 concentrations at the top of the column. Microbial oxidation was confirmed by a approximately 7 per thousand enrichment in CH4 stable carbon isotope ratios along profiles. Using a fractionation factor of 1.025+/-0.0005 for microbial oxidation estimated from this shift and the fractionation factor for diffusion, simulations of isotope profiles agreed well with measured data confirming large fractionation associated with microbial oxidation. The designed column should be valuable for investigating response of methanotrophic bacteria to environmental parameters in future studies. 相似文献
218.
Vermeirssen EL Asmin J Escher BI Kwon JH Steimen I Hollender J 《Journal of environmental monitoring : JEM》2008,10(1):119-128
There is an increasing need to monitor concentrations of polar organic contaminants in the aquatic environment. Integrative passive samplers can be used to assess time weighted average aqueous concentrations, provided calibration data are available and sampling rates are known. The sampling rate depends on environmental factors, such as temperature and water flow rate. Here we introduce an apparatus to investigate the sampling properties of passive samplers using river-like flow conditions and ambient environmental matrices: river water and treated sewage effluent. As a model sampler we selected Empore SDB-RPS disks in a Chemcatcher housing. The disks were exposed for 1 to 8 days at flow rates between 0.03 and 0.4 m s(-1). Samples were analysed using a bioassay for estrogenic activity and by LC-MS-MS target analysis of the pharmaceuticals sulfamethoxazole, carbamazepine and clarithromycin. In order to assess sampling rates of SDB disks, we also measured aqueous concentrations of the pharmaceuticals. Sampling rates increased with increasing flow rate and this relationship was not affected by the environmental matrix. However, SDB disks were only sampling in the integrative mode at low flow rates <0.1 m s(-1) and/or for short sampling times. The duration of linear uptake was particularly short for sulfamethoxazole (1 day) and longer for clarithromycin (5 days). At 0.03 m s(-1) and 12-14 degrees C, the sampling rate of SDB disks was 0.09 L day(-1) for clarithromycin, 0.14 L day(-1) for sulfamethoxazole and 0.25 L day(-1) for carbamazepine. The results show that under controlled conditions, SDB disks can be effectively used as passive sampling devices. 相似文献
219.
Palovčík Jakub Jadrný Josef Smejkalová Veronika Šmírová Barbora Šomplák Radovan 《Journal of Material Cycles and Waste Management》2023,25(1):550-564
Journal of Material Cycles and Waste Management - Estimation of mixed municipal waste composition is important for the option of suitable waste treatment. Many studies have presented their... 相似文献