Industrial pollution transport. Part 1. Formulation of the problem and air pollution estimates

A pollution transport problem is formulated in a limited area. As the pollution sources we take emissions from industrial plants. Physically and mathematically suitable conditions are prescribed on the open boundaries. We show that the problem (as well as its adjoint) is well posed in the sense that a weak solution exists, is unique and depends continuously on its data. Direct and adjoint estimates of the average pollution concentration in an ecologically important zone are given, and the sensitivity of these estimates to perturbations in model parameters is analyzed.     

DEVELOPMENT AND APPLICATION OF A MODFLOW PREPROCESSOR USING PERCOLATION THEORY FOR FRACTURED MEDIA1

ABSTRACT: The discrete heterogeneity of fracture distribution and hydraulic discontinuity are the primary difficulties in the modeling of flow in fractured media. The equivalent porous medium (EPM) approach, however, which has been frequently applied to simulate flow in fractured media due to its ease of use, ignores this. This practice results in some severe limitations such as hydraulic head averaging and an inability to handle preferred fluid pathways. The PMF package (a Preprocessor to MODFLOW for Fractured media) was developed employing percolation theory to address these limitations and to utilize the simplicity of the EPM approach at the same time. This preprocessor was applied to a fractured rock aquifer around Cranberry Lake in northern New Jersey. The calibration using hydraulic head observations, validation using water balance, and evaluation using residuals show that the model generated by the PMF package can provide a superior simulation of ground water flow to the EPM approach.     

Effects of changes in climate on landscape and regional processes, and feedbacks to the climate system

Biological and physical processes in the Arctic system operate at various temporal and spatial scales to impact large-scale feedbacks and interactions with the earth system. There are four main potential feedback mechanisms between the impacts of climate change on the Arctic and the global climate system: albedo, greenhouse gas emissions or uptake by ecosystems, greenhouse gas emissions from methane hydrates, and increased freshwater fluxes that could affect the thermohaline circulation. All these feedbacks are controlled to some extent by changes in ecosystem distribution and character and particularly by large-scale movement of vegetation zones. Indications from a few, full annual measurements of CO2 fluxes are that currently the source areas exceed sink areas in geographical distribution. The little available information on CH4 sources indicates that emissions at the landscape level are of great importance for the total greenhouse balance of the circumpolar North. Energy and water balances of Arctic landscapes are also important feedback mechanisms in a changing climate. Increasing density and spatial expansion of vegetation will cause a lowering of the albedo and more energy to be absorbed on the ground. This effect is likely to exceed the negative feedback of increased C sequestration in greater primary productivity resulting from the displacements of areas of polar desert by tundra, and areas of tundra by forest. The degradation of permafrost has complex consequences for trace gas dynamics. In areas of discontinuous permafrost, warming, will lead to a complete loss of the permafrost. Depending on local hydrological conditions this may in turn lead to a wetting or drying of the environment with subsequent implications for greenhouse gas fluxes. Overall, the complex interactions between processes contributing to feedbacks, variability over time and space in these processes, and insufficient data have generated considerable uncertainties in estimating the net effects of climate change on terrestrial feedbacks to the climate system. This uncertainty applies to magnitude, and even direction of some of the feedbacks.     

Dual oil concentration estimates in ecologically sensitive zones

Propagation of the oil spilling from a damaged oil tanker is considered in a limited sea area. Direct and adjoint estimates of the average oil concentration in special zones are derived by using solutions of the 2-D main and adjoint oil transport problems, respectively. The dual estimates complement each other nicely in studying the oil spill consequences. While the direct estimates are preferable to get a comprehensive idea of the oil spill impact on the whole area, the adjoint ones are specially useful and economical when the accident site-dependence or/and the oil spill rate-dependence of the oil concentration is/are studied only in a few ecologically sensitive zones. Indeed, each adjoint estimate explicitly relates the average oil concentration in a zone to the oil spill rate using the adjoint solution values at the accident site. Being independent of the two parameters (the accident site and oil spill rate), the adjoint solution can be found for each zone regardless of a concrete accident and used repeatedly for various possible values of these parameters. Several examples explain how to decide between two estimates.Thanks to special boundary conditions, the main and adjoint problems are both well-posed according to Hadamard (1923). The dual estimates can be generalized to the three dimensions. The balanced, absolutely stable and compatibie main and adjoint 3-D numerical algorithms by Skiba (1993) can easily be adapted to the problem discussed here.     

Effects of seismic intensity and socioeconomic status on injury and displacement after the 2007 Peru earthquake

Earthquakes are a major cause of displacement, particularly in developing countries. Models of injury and displacement can be applied to assist governments and aid organisations in effectively targeting preparedness and relief efforts. A stratified cluster survey was conducted in January 2008 to evaluate risk factors for injury and displacement following the 15 August 2007 earthquake in southern Peru. In statistical modelling, seismic intensity, distance to rupture, living conditions, and educational attainment collectively explained 54.9 per cent of the variability in displacement rates across clusters. Living conditions was a particularly significant predictor of injury and displacement, indicating a strong relationship between risk and socioeconomic status. Contrary to expectations, urban, periurban, and rural clusters did not exhibit significantly different injury and displacement rates. Proxies of socioeconomic status, particularly the living conditions index score, proved relevant in explaining displacement, likely due to unmeasured aspects of housing construction practices and building materials.     

Degradation of carbon tetrachloride by iron metal: Complexation effects on the oxide surface

Dehalogenation of chlorinated aliphatic contaminants at the surface of zero-valent iron metal (Fe⁰) is mediated by the thin film of iron (hydr)oxides found on Fe⁰ under environmental conditions. To evaluate the role this oxide film plays in the reduction of chlorinated methanes, carbon tetrachloride (CCl₄) degradation by Fe⁰ was studied under the influence of various anions, ligands, and initial CCl₄ concentrations ([P]_o). Over the range of conditions examined in these batch experiments, the reaction kinetics could be characterized by surface-area-normalized rate constants that were pseudo-first order for CCl₄ disappearance (k_CCl4), and zero order for the appearance of dissolved Fe²⁺ (k_Fe²⁺). The rate of dechlorination exhibits saturation kinetics with respect to [P]_o, suggesting that CCl₄ is transformed at a limited number of reactive surface sites. Because oxidation of Fe⁰ by CCl₄ is the major corrosion reaction in these systems, k_Fe²⁺ also approaches a limiting value at high CCl₄ concentrations. The adsorption of borate strongly inhibited reduction of CCl₄, but a concomitant addition of chloride partially offset this effect by destabilizing the film. Redox active ligands (catechol and ascorbate), and those that are not redox active (EDTA and acetate), all decreased k_CCl4 (and k_Fe²⁺). Thus, it appears that the relatively strong complexation of these ligands at the oxide–electrolyte interface blocks the sites where weak interactions with the metal oxide lead to dehalogenation of chlorinated aliphatic compounds.     

Integral use of plants and their residues: the case of cocoyam (<Emphasis Type="Italic">Xanthosoma sagittifolium</Emphasis>) conversion through biorefineries at small scale

During last decades, there has been a growing interest of decreasing the environmental impact generated by humans. This situation has been approached from different perspectives being the integral use of raw materials as one of the best alternatives. It was estimated that 3.7?×?10⁹ tonnes of agricultural residues are produced annually worldwide. Then, the integral use of feedstocks has been studied through the biorefinery concept. A biorefinery can be a promissory option for processing feedstocks in rural zones aiming to boost the techno-economic and social growth. However, many plants produced at small scale in rural zones without high industrial use contribute with residues usually not studied as raw materials for other processes. Cocoyam (Xanthosoma sagittifolium) is a plant grown extensively in tropical regions. Nigeria, China, and Ghana are the main producers with 1.3, 1.18, and 0.9 million tonnes/year, respectively. In Colombia, there are no technified crops, but it is used where it is grown mainly as animal feed. This plant consists of leaves, stem, and a tuber but the use is generally limited to the leaves, discarding the other parts. These discarded parts have great potential (lignocellulose and starch). This work proposes different processing schemes using the parts of the plant to obtain value-added products, and their techno-economic and environmental assessment. The simulation was performed with Aspen Plus and the economic package was used for the economic assessment. For the environmental assessment, Waste Algorithm Reduction of the U.S. EPA was implemented. The obtained results showed that the integral use of plants under a biorefinery scheme allows obtaining better techno-economic and environmental performance and that small-scale biorefineries can be a promissory option for boosting rural zones.     

Source apportionment of polycyclic aromatic hydrocarbons in Lake Baikal water and adjacent air layer

The composition of polycyclic aromatic hydrocarbons (PAHs) in Lake Baikal water and adjacent air layer and PAH emission composition profiles of possible sources were investigated. Analysis of emission composition data showed that the source profiles could not be grouped by fuel type or pyrogenic/petrogenic origin. Because of the similarity of source PAH profiles, the drawing of 3D mixing diagrams was the only way to check whether some of the potential PAH sources were the true sources. The mixing diagrams showed that the sources of air pollution were paper mills and wood burning and that the sources of water pollution were coal-fired and oil-fired boilers. The common source for both air and water was only oil and petroleum products. To determine the locations of PAH sources, their contributions to air and water pollution were calculated and mapped. Based on the results, air and water were polluted from both local and regional sources. The location of the zone influenced by a particular source was conditioned by physical properties of source emission, direction of air/water flows that transfer PAHs and temperature differences between mixing air/water flows.