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51.
Jasmeet Kaur Bonamali Pal 《Environmental science and pollution research international》2013,20(6):3956-3964
This study demonstrates the influences of position, number of nitrogen (N) atoms and –C–N– or –N=N– linkage present in the six membered heterocyclic compounds such as pyridine, pyrazine, and pyridazine on their photocatalytic degradation by Au, Ag, and Fe+2 deposited TiO2 photocatalyst. The photodegradation rate of these heterocyclic compounds follow the order pyridine > pyrazine > pyridazine due to the different extent of hydroxylation and difference in position and number of N atoms in the aromatic moiety. The Au photodeposition significantly improved the TiO2 photoactivity as compared to Ag and Fe+2 loading. The presence of two N atoms in pyrazine and pyridazine as compared to one N atom in pyridine hamper the nucleophilc attack of OH radicals in comparison to easy hydroxylation of pyridine ring. There is 1 N atom, 4C–C, 1C–N and 1C=N bond in pyridine, 2 N atoms in the 1 and 4 positions, 2C–C, 2C–N bonds and 2C=N bonds in pyrazine, and pyridazine ring contains 2 N atoms in the 1 and 2 positions, 3C–C, 1N–N bond and 2C=N bonds. The bond strength/energy decreases gradually as: C=N– (615 KJ/mol)?>?–N=N– (418 KJ/mol)?>?–C–C– (347 KJ/mol)?>?–C–N– (305 KJ/mol)?>?–N–N– (163 KJ/mol). As pyridine has 1C–N, 1C=N, and no N–N bond, it photodegrades easily as compared to 1 N–N and 2C=N bonds of pyridazine of lowest photodecomposition rate. The improved photoactivity of Au–TiO2 is explained on the basis of its favorable redox potential, work function, and electron-capturing capacity, etc. 相似文献
52.
Bharat Bhushan Vashisht D. J. Mulla S. K. Jalota Samanpreet Kaur Harsimran Kaur Sher Singh 《Regional Environmental Change》2013,13(5):989-998
Wheat (Triticum aestivum L.) is grown as a rainfed crop in the sub-mountainous region of the Punjab state of India, with low crop and water productivity. The present study aims to assess the effect of climate change scenario (A1B) derived from PRECIS—a regional climate model—on wheat yield and water productivity. After minimizing bias in the model climate data for mid-century (2021–2050), evapotranspiration (ET) and yield of wheat crop were simulated using Decision Support System for Agrotechnology Transfer, version 4.5, model. In the changed climate, increased temperature would cause reduction in wheat yield to the extent of 4, 32 and 61 % in the mid-century periods between 2021–2030, 2031–2040 and 2041–2050, respectively, by increasing water stress and decreasing utilization efficiency of photosynthetically active radiation. The decreases in crop water productivity would be 40, 56 and 76 %, respectively, which are caused by decreased yield and increased ET. Planting of wheat up to November 25 till the years 2030–2031 seems to be helpful to mitigate the climate change effect, but not beyond that. 相似文献
53.
Environmental Geochemistry and Health - A comprehensive radio-ecological evaluation of soil samples of Solan and Shimla districts of Himachal Pradesh has been carried out for risk and dose... 相似文献
54.
Al-Harrasi Ahmed Behl Tapan Upadhyay Tanuj Chigurupati Sridevi Bhatt Shvetank Sehgal Aayush Bhatia Saurabh Singh Sukhbir Sharma Neelam Vijayabalan Shantini Palanimuthu Vasanth Raj Das Suprava Kaur Rajwinder Aleya Lotfi Bungau Simona 《Environmental science and pollution research international》2022,29(28):42404-42432
Environmental Science and Pollution Research - The human coronavirus disease (COVID-19) pandemic is caused by a novel coronavirus; the Severe Acute Respiratory Syndrome Coronavirus (SARS-CoV-2).... 相似文献
55.
Mukherjee Tuhin Behl Tapan Sharma Sanchay Sehgal Aayush Singh Sukhbir Sharma Neelam Mathew Bijo Kaur Jasleen Kaur Ratandeep Das Mayukh Aleya Lotfi Bungau Simona 《Environmental science and pollution research international》2022,29(6):8109-8125
Environmental Science and Pollution Research - Vasoactive intestinal peptide (VIP) is a neuropeptide that is produced by the lymphoid cells and plays a major role in immunological functions for... 相似文献
56.
Kaur Rajwinder Sood Ankita Lang Damanpreet Kaur Bhatia Saurabh Al-Harrasi Ahmed Aleya Lotfi Behl Tapan 《Environmental science and pollution research international》2022,29(18):26063-26077
Environmental Science and Pollution Research - Developing therapies for neurodegenerative diseases are challenging because of the presence of blood–brain barrier and Alzheimer being one of... 相似文献
57.
Kaur Ishnoor Behl Tapan Aleya Lotfi Rahman Habibur Kumar Arun Arora Sandeep Bulbul Israt Jahan 《Environmental science and pollution research international》2021,28(30):40515-40532
Environmental Science and Pollution Research - The world has never been prepared for global pandemics like the COVID-19, currently posing an immense threat to the public and consistent pressure on... 相似文献
58.
Kaur Rajwinder Sood Ankita Kanotra Muskan Arora Sandeep Subramaniyan Vetriselvan Bhatia Saurabh Al-Harrasi Ahmed Aleya Lotfi Behl Tapan 《Environmental science and pollution research international》2021,28(39):54531-54550
Environmental Science and Pollution Research - Nutrition plays a significant role in the prevention and treatment of common diseases. Some superb dietary choices such as functional foods and... 相似文献
59.
Mandal Reshu Kaur Sukhbir Gupta Vinod kumar Joshi Amit 《Environmental geochemistry and health》2022,44(10):3215-3238
Environmental Geochemistry and Health - Heavy metals (HMs) have a very significant clinical role in the pathogenesis, progression and management of cardiovascular diseases (CVDs). The prevalence of... 相似文献
60.
Glyphosate is used widely to control weeds. Glyphosate is a broad spectrum, non-selective, systemic and post-emergent herbicide. Glyphosate excessive use and impact on the environment is promoting the analysis of glyphosate in water, soil and food materials. Methods to analyse glyphosate at low levels are needed because glyphosate has a short half-life due to easy microbial degradation. Glyphosate has a high polarity and solubility in water, has high binding affinity with soil and is non-volatile. The absence of chromophoric groups in the molecular structure makes the detection difficult. Therefore, detection can be achieved by derivatisation, which makes glyphosate more volatile and stable for spectroscopic analysis. Derivatisation is commonly done by alkyl chloroformates, acylating agents, 9-fluoroenylmethylchloroformate, 4-methoxybenzenesulfonylfluoride and o-phthalaldehyde. Immunosensors allow detection at microlevels. Nanocrystals and nanotechnology allow detection at nanolevels. Here, we review methods to derivatise and analyse glyphosate. 相似文献