Survey of dioxin sources in the Baltic Region (extended summary)

The present paper summarises the results of the project: 'Survey of Anthropogenic Sources of Dioxins and Furans in the Baltic Region'. As a part of the project, inventories have been carried out in Estonia, Latvia, Lithuania and Poland by applying the toolkit for quantification of dioxin and furan releases developed by UNEP Chemicals. The main route of direct releases to the environment is emission to air. Total emission to air from Poland was estimated at 490 (88-1,300) g I-TEQ/year, whereas the emissions from Estonia, Latvia and Lithuania were estimated as being 14 (2.4-54), 23 (2.6-63) and 17 (2.6-38) g I-TEQ, respectively. In general, the uncertainty on the estimates is very high, and recommendations regarding further development of the inventories have been made, and measures for reducing the releases have been provided.     

Raw materials for fermentative hydrogen production

The basics of hydrogen production by thermophilic fermentation and photofermentation are outlined. Various types of biomass, which can be used as raw materials for hydrogen fermentation are named and the methods of biomass pretreatment are highlighted. The approach to technical assessment of biomass suitability is reviewed and several promising raw materials are compared with respect to the attainable hydrogen yield.     

A Contribution to the Study of the Antidust Respirators’ Real Performance

In most industrial enterprises, hazardous factors are present in quantities exceeding permissible levels. Such a situation requires using antidust respiratory protection. It has been suggested, however, that filters for respirators are not assessed properly and that lab results might not be related to real filtering efficiency in industry. This article contains test results of some commercially available filtering half-masks, including the effect of loading with real dust, high humidity, high temperature, and a combination of loading with dust and high humidity on the half-masks’ performance. The results show that the effect of these factors is considerable and that a combination of loading with silica dust and exposing to high humidity can cause a complete loss of performance.     

Deposition and Resuspension of Selected Aerosols Particles on Electrically Charged Filter Materials for Respiratory Protective Devices

The primary aim of the study was to analyse the non-steady state of filtration for selected electrostatic filter materials designed for use in respiratory protective devices. The obtained results showed that the filtration process in electrostatic filters was dependent in the main on the following factors: type of the filter material, electrostatic field strength of the material, and the charge of the aerosol.

To a lesser degree the filtration process depended on the sign of the charge and the relative humidity of the air. A significant correlation was found between the increase in the penetration and the decrease in breathing resistance while the filter was being loaded.

The effect of resuspension (tearing off and re-deposition of dust agglomerates inside the filter) on the filtration process very significant. It was also observed that under certain conditions electrostatic filter materials lost their protection properties.     

Health Risk Assessment of Occupational Exposure to a Magnetic Field From Magnetic Resonance Imaging Devices

Health care staff who operate magnetic resonance imaging (MRI) devices are exposed to a static magnetic field of significant spatial heterogenity always produced by MRI magnets during the whole shift. They can also be exposed to pulses of a time-varying magnetic field (gradient field) present only during patients’ examinations. The level of the workers’ exposure depends both on the type of the magnet and on the ergonomic design of each MRI device.

The paper presents methods used for measuring and assessing workers’ exposure. It also discusses the results of inspection measurements carried out next to approximately 20 MRI devices of approximately 0.2–2.0 T. The presented characteristic and overview of the variability of workers’ exposure to a variety of MRI devices supports the need for data on monitoring occupational exposure to MRI. International exposure assessment standards and guidelines (International Commission on Non-Ionizing Radiation Protection [ICNIRP], Institute of Electrical and Electronics Engineers [IEEE], American Conference of Governmental and Industrial Hygienists [ACGIH], European Commission directive), and those established in Poland are also compared.     

Comparison of methods for leaching heavy metals from composts

This paper presents the determination of total iron, copper, zinc, chromium, nickel, lead, cadmium and mercury contents in the compost obtained from sorted municipal organic solid waste applying the following methods of sample mineralization: 40% hydrofluoric acid with preliminary incineration of a sample, a mixture of concentrated nitric(V) and chloric(VII) acids with preliminary incineration of organic matter and a mixture of nitric(V) and chloric(VII) acids without sample incineration. The speciation analysis of Tessier was used to estimate the bioavailability of the metals. Elution degrees of the mobile forms of the metals from the compost with 10% nitric(V) acid and 1 mol/dm(3) hydrochloric acid were compared. The contents of the elements in the eluates were determined applying atomic absorption spectrometry.     

The modal low frequency noise of an elastically supported circular plate.

The modal low frequency noise generated by a vibrating elastically supported circular plate embedded into a flat infinite baffle has been examined. The main aim of this study is the analysis of the radiation efficiency. Low frequency approximated formulas have been presented. They are valid for all the limiting boundary conditions of the plate with its edge clamped, guided, simply supported or free as well as for all the intermediate axisymmetric boundary configurations. The formulas are expressed in the elementary form, useful for numerical computations. They are a generalization of some earlier published results. First, they are valid for axisymmetric and asymmetric modes since both kinds of modes play an important role in the low frequency range. Second, a single formula for the radiation efficiency, valid for all the axisymmetric boundary configurations, has been proposed. A numerical example for the sound power radiation has been given for some hatchway covers mounted on a ship deck.     

In-vehicle VOCs composition of unconditioned, newly produced cars

The in-vehicle volatile organic compounds （VOCs） concentrations gains the attention of both car producers and users. In the present study, an attempt was made to determine if analysis of air samples collected from an unconditioned car cabin can be used as a quality control measure. The VOCs composition of in-vehicle air was analyzed by means of active sampling on Carbograph 1TD and Tenax TA sorbents, followed by thermal desorption and simultaneous analysis on flame ionization and mass detector （TD-GC/FID-MS）. Nine newly produced cars of the same brand and model were chosen for this study. Within these, four of the vehicles were equipped with identical interior materials and five others differed in terms of upholstery and the presence of a sunroof; one car was convertible. The sampling event took place outside of the car assembly plant and the cars tested left the assembly line no later than 24 hr before the sampling took place. More than 250 compounds were present in the samples collected; the identification of more than 160 was confirmed by comparative mass spectra analysis and 80 were confirmed by both comparison with single/multiple compounds standards and mass spectra analysis. In general, aliphatic hydrocarbons represented more than 60% of the total VOCs （TVOC） determined. Depending on the vehicle, the concentration of aromatic hydrocarbons varied from 12% to 27% of total VOCs. The very short period between car production and sampling of the in-vehicle air permits the assumption that the entire TVOC originates from off-gassing of interior materials. The results of this study expand the knowledge of in-vehicle pollution by presenting information about car cabin air quality immediately after car production.     

Betaine removal during thermo- and mesophilic aerobic batch biodegradation of beet molasses vinasse: influence of temperature and pH on the progress and efficiency of the process

The key issue in achieving a high extent of biodegradation of beet molasses vinasse is to establish the conditions for the assimilation of betaine, which is the main pollutant in this high-strength industrial effluent. In the present study, aerobic batch biodegradation was conducted over the temperature range of 27-63°C (step 9°C), at a pH of 6.5 and 8.0, using a mixed culture of bacteria of the genus Bacillus. Betaine was assimilated at 27-54°C and the pH of 8.0, as well as at 27-45°C and the pH of 6.5. The processes where betaine was assimilated produced a high BOD(5) removal, which exceeded 99.40% over the temperature range of 27-45°C at the pH of 8.0, as well as at 27°C and the pH of 6.5. Maximal COD removal (88.73%) was attained at 36°C and the pH of 6.5. The results indicate that the process can be applied on an industrial scale as the first step in the treatment of beet molasses vinasse.     

Locking of retractable type fall arresters--test method and stand.

Retractable type fall arresters are very effective personal equipment protecting against falls from a height. These devices are used under different atmospheric conditions and in the presence of various types of industrial pollution. For this reason appropriate locking after conditioning simulating extreme conditions of a worksite is one of the essential characteristics of retractable type fall arresters. This article presents the requirements for locking of the devices. A previously used locking test method and its disadvantages are discussed. The article suggests an improved test method and test equipment. Measurement of the test mass acceleration is the most important improvement introduced into the test method. The article shows laboratory tests used to verify the method, which turned out to be a valuable source of information concerning the performance of retractable type fall arresters.