Contamination of polychlorinated biphenyls and organochlorine pesticides in breast milk in Korea: Time-course variation,influencing factors,and exposure assessment

Breast milk is a noninvasive specimen to assess maternal and infant exposure to polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs). In this study, 206 breast milk samples were collected from 87 participants during lactation, at <7, 15, 30, or 90 days postpartum in four cities in Korea. The total concentrations of PCBs (ΣPCB) and OCPs (ΣOCP) ranged from <LOQ to 84.0 (median: 12.1) ng g⁻¹ lipid weight and from <LOQ to 559 (median: 144) ng g⁻¹ lipid weight, respectively. The residue levels of these contaminants measured in our study were relatively lower than those reported for European, African and Asian populations. Within a month postpartum typically after day seven the levels of ΣPCB and ΣOCP significantly increased. Some OCP compounds were correlated with maternal age, BMI, parity, and delivery mode. Certain types of dietary habits such as seafood and noodle consumption were significantly associated with ΣPCB and ΣOCP. The estimated daily intakes (EDIs) of ΣPCB and ΣOCP were 45.2–127 ng kg⁻¹ bw day⁻¹ and 625–1259 ng kg⁻¹ bw day⁻¹ during lactation, respectively, which are lower than the threshold values proposed by the US EPA and Health Canada. The exposure of Korean infants to chlordanes via breast milk had a potential health risk which deserves further investigation.     

Volatile Organic Compounds in Ambient Air at Four Residential Locations in Seoul, Korea

To investigate the environmental behavior of volatile organic compounds (VOCs) in urban areas, their concentrations were measured at four urban monitoring sites (namely, N, S, E, and W) in Seoul, Korea (February to December 2009). A total of 27 compounds were quantified that consist of four chemical groups: aromatic (AR), halogenated aromatic, halogenated paraffin, and halogenated olefin. Results were evaluated by focusing on these four functional groups just mentioned and their summation term as total VOC (TVOC) along with several individual species (mainly AR species, that is, benzene, toluene, ethylbenzene, and xylene). The highest concentration of chemical groups was found from AR (71.1±42.1?ppbC), while that for individual species confirmed the dominance of toluene (7.48±3.88?ppb). The analysis of spatial distribution indicated that high TVOC levels were recorded at sites N and W, while it was not so significant such as S and E in terms of TVOC budget. Seasonal variation of these VOCs was characterized by the peak values in December to reflect the combined effects of pronounced source activities and meteorological conditions. Analysis of spatial variations in VOC levels between the four urban sites indicated that their distributions are tightly affected by local source processes in each area.     

Catalytic wet oxidation of ammonia: why is N2 formed preferentially against NO3 -?

The role of catalyst and the reason for the preferential formation of N(2) in the catalytic oxidation reaction of ammonia in water over a Ru (3wt.%)/TiO(2) catalyst were elucidated. It was verified that the catalyst in the reaction had no direct relevance to the selective formation of N(2), but was responsible only for the oxidation of aqueous ammonia, NH(3)(aq), finally giving a molecule of nitrous acid. The preferential production of N(2) was experimentally demonstrated due to the homogeneous aqueous phase reaction of the nitrous acid-dissociated NO(2)(-) with NH(4)(+) ions. Even under the highly oxidizing condition, NO(2)(-) was much more likely to react with NH(4)(+) to form N(2) than being oxidized over the catalyst to NO(3)(-) as long as NH(4)(+) was available in solution.     

Mid‐Range Streamflow Forecasts Based on Climate Modeling – Statistical Correction and Evaluation1

Abstract: Mid‐range streamflow predictions are extremely important for managing water resources. The ability to provide mid‐range (three to six months) streamflow forecasts enables considerable improvements in water resources system operations. The skill and economic value of such forecasts are of great interest. In this research, output from a general circulation model (GCM) is used to generate hydrologic input for mid‐range streamflow forecasts. Statistical procedures including: (1) transformation, (2) correction, (3) observation of ensemble average, (4) improvement of forecast, and (5) forecast skill test are conducted to minimize the error associated with different spatial resolution between the large‐scale GCM and the finer‐scale hydrologic model and to improve forecast skills. The accuracy of a streamflow forecast generated using a hydrologic model forced with GCM output for the basin was evaluated by forecast skill scores associated with the set of streamflow forecast values in a categorical forecast. Despite the generally low forecast skill score exhibited by the climate forecasting approach, precipitation forecast skill clearly improves when a conditional forecast is performed during the East Asia summer monsoon, June through August.     

Using the Triad Approach to expedite the acquisition of an Abbott district school site

The Triad Approach was field‐tested to determine if characterization objectives could be met for a brownfields property that had been identified as a future elementary school site. The new school is in response to a New Jersey Supreme Court ruling (the Abbott decision) that directed the state of New Jersey to fund school construction in poorer districts to expand physical facilities to relieve overcrowding. The Triad Approach is promoted by the United States Environmental Protection Agency as a process that has the potential to improve the timeliness and efficiency of site characterization, and the New Jersey Department of Environmental Protection (NJDEP) recently issued a policy statement supporting its potential. Aggressive school construction deadlines are contingent on property acquisitions that are relatively faster than the traditional investigatory process. In addition, given the future sensitive population, the investigations must be thorough. This case study is among the first studies to document the use of the Triad Approach for a future school site. The Triad Approach was used to define site conditions for six areas of concern in a two‐month time frame (from the start of the planning process to completed investigation). © 2004 Wiley Periodicals, Inc.     

Influence of atmospheric dispersion and new particle formation events on ambient particle number concentration in Rochester, United States, and Toronto, Canada

Continuous measurements of particle number concentrations were performed in Rochester, NY, and Toronto, Ontario, Canada during the 2003 calendar year. Strong seasonal dependency in particle number concentration was observed at two sites. The average number concentration of ambient particles was 9670 +/- 6960 cm(-3) in Rochester, whereas in Toronto the average number of particles was 28,010 +/- 13,350 cm(-3). The particle number concentrations were higher in winter months than in summer months by a factor of 1.5 in Rochester and 1.6 in Toronto. In general, there were also distinct diurnal variations of aerosol number concentration. The highest weekdays/weekends ratio of number concentration was typically observed during the rush-hour period in winter months with a ratio of 2.1 in Rochester and 2.0 in Toronto. The correlation in the total particle number concentrations between the two urban sites was stronger in winter because of the common urban traffic patterns, but weaker in summer because of local sulfur dioxide (SO2)-related particle formation events in Rochester in the summer. Strong morning particle formation events were frequently observed during colder winter months. Good correlations between particle number and carbon monoxide (CO) as well as temperature suggested that motorvehicle emissions lead to the formation of new particles as the exhaust mixes with the cold air. Regional nucleation and growth events frequently occurred in April. Local SO2-related particle formation events most frequently occurred in August. SO2 and UV-B were highly correlated with particle concentration, suggesting a high association of photochemical processes with these local events. A high directionality in a northerly direction was observed for particle number and SO2, indicating the influence of point sources located north of Rochester.     

Utilization of coal fly ash as a slow-release granular medium for soil improvement

This work proposes a new potential application of waste coal fly ash as a K fertilizer support. Fly ash was reacted with KOH to facilitate the impregnation of K as well as to enhance the bonding force. In particular, the applied process resulted in a significant slow-releasing characteristic of fertilizer elements. To examine the effect of K impregnation, a few detailed leaching tests were carried out in terms of process variables such as reaction time and temperature, sintering time and temperature, and KOH concentration. The current experiment presented an optimum preparation condition that is competitive with conventional commercial fertilizers. The manufactured ash fertilizers inhibited release of the K elements. It was also found through the continuous leaching test with pure water that the ash fertilizer had excellent moisture absorbability. However, the effects of some trace elements in fly ash on soil health and crop productivity as well as environmental considerations need to be established with long-term studies.     

Impact of pH buffer capacity of sediment on dechlorination of atrazine using zero valent iron

This research investigated the role of the pH buffer capacity of sediment on the dechlorination of atrazine using zero valent iron (ZVI). The buffer capacity of the sediment was quantified by batch experiments and estimated to be 5.0 cmol OH^? · pH^?1. The sediments were spiked with atrazine at 7.25-36.23 mg kg^?1 (6.21 × 10^?7–3.09 × 10^?6 mol atrazine · g^?1 sediment) for the batch experiments. The buffer capacity of the sediment maintained the sediment suspension at neutral pH, thereby enabling continuous dechlorination until the buffer capacity of the sediment was depleted. The pseudo-first order dechlorination constants were estimated to be in the range of 1.19 × 10^?2?7.04 × 10^?2 d^?1 for the atrazine-spiked sediments.     

Factors influencing natural occurrence of fluoride-rich groundwaters: a case study in the southeastern part of the Korean Peninsula

Factors regulating the occurrence of fluoride in groundwater were investigated using natural isotope tracers and geochemical data in the southeastern part of Korea where about 10% of the total public water-supply wells (n=422) inspected in this study had fluoride levels exceeding the drinking water limit of Korea (1.5 mg/l). The F-rich public wells are mostly distributed along the major faults, especially in the terrain of the F-rich granitic rocks. The stable isotope analysis results provide substantial information for the relative ages of groundwaters. It is revealed that the F-rich groundwaters are deeply circulating paleogroundwaters and occur along the faults due to upward flow along the fault plane. While reacting with granitic rocks for a prolonged period, the F concentrations of groundwater are continuously enriched even after the groundwater reaches an equilibrium state with respect to fluorite (CaF2) due to removal of Ca by precipitation of calcite (CaCO3). These observations reflect that rock chemistry, groundwater age, well depth, and geologic structure are the important factors controlling the occurrence of high F groundwaters. However, high F groundwaters are rarely observed in the fault zones where the associated fractures are widely developed. Isotopic signature provides an evidence for deep penetration of recently recharged groundwater into the wide fault zone, indicating that the hydrologic condition of the fault is also an important factor controlling the occurrence of high F groundwaters.