溶胶-凝胶Ag-Al2O3催化剂还原稀燃氮氧化物的研究

系统地研究了培烧条件、氧气浓度、C／N摩尔比等因素对溶胶-凝胶Ag(5)-Al2O3催化剂活性的影响。实验结果表明,氧气浓度对催化剂活性的影响表现为促进低温活性和抑制高温活性;催化剂的最佳焙烧条件为焙烧温度600℃和升温速率5C／min;催化剂的活性随着C／N摩尔比的降低而降低。此外,还考察了空速对Ag(5)-Al2O3催化剂活性的影响。结果表明,该催化剂在较大的空速范围内具有良好的活性。     

Phthalic acid esters in grains,vegetables, and fruits: concentration,distribution, composition,bio-accessibility,and dietary exposure

Environmental Science and Pollution Research - Grain, vegetable, and fruit samples were collected from Xi’an City in Northwest China and analyzed for the characteristics, bio-accessibility,...     

Frontier science and challenges on offshore carbon storage

● The main direct seal up carbon options and challenges are reviewed. ● Ocean-based CO₂ replacement for CH₄/oil exploitation is presented. ● Scale-advantage of offshore CCS hub is discussed. Carbon capture and storage (CCS) technology is an imperative, strategic, and constitutive method to considerably reduce anthropogenic CO₂ emissions and alleviate climate change issues. The ocean is the largest active carbon bank and an essential energy source on the Earth’s surface. Compared to oceanic nature-based carbon dioxide removal (CDR), carbon capture from point sources with ocean storage is more appropriate for solving short-term climate change problems. This review focuses on the recent state-of-the-art developments in offshore carbon storage. It first discusses the current status and development prospects of CCS, associated with the challenges and uncertainties of oceanic nature-based CDR. The second section outlines the mechanisms, sites, advantages, and ecologic hazards of direct offshore CO₂ injection. The third section emphasizes the mechanisms, schemes, influencing factors, and recovery efficiency of ocean-based CO₂-CH₄ replacement and CO₂-enhanced oil recovery are reviewed. In addition, this review discusses the economic aspects of offshore CCS and the preponderance of offshore CCS hubs. Finally, the upsides, limitations, and prospects for further investigation of offshore CO₂ storage are presented.     

二氧化碳咸水层封存的研究现状和问题

二氧化碳咸水层封存作为目前最具潜力的碳减排技术,已经在国内外开展了一定的研究探索和工程应用,文章结合国际重要的封存工程,介绍和分析了封存机理、潜力评估、场址筛选、环境监测等四方面的研究现状,展示了封存工程中采用的相关技术和取得的成果,并针对本领域亟待解决的问题提出下一步工作建议。     

毒死蜱对六种淡水节肢动物的毒性与风险评价

采用静态法测定了毒死蜱对六种水生节肢动物的48 h毒性.试验结果表明,按实测浓度计,毒死蜱对大型溞Daphnia magna、老年低额溞Simocephalus vetulus、多刺裸腹潘Moina macrocopa、锯缘真蚤Eucyclops serrulatus、介形虫Pseudocandona sp.、花翅摇蚊Chironomus kiiensis幼虫的48 h-LC50(单位:μg· L-1)分别为0.523、0.0528、0.178、7.32、2.75、90.3.这表明毒死蜱对于上述6种水生节肢动物均属于剧毒.将稻田施药下的环境浓度预测值(EECs)与基于实测浓度的48 h-LC50相比对,得到毒死蜱相对于6种水生节肢动物的急性风险商值(RQ)分别为10.29、52.95、27.20、0.73、1.96、0.06.这说明除了摇蚊幼虫,按推荐剂量使用的毒死蜱对于其他5种水生节肢动物有较高程度的急性风险.     

An integrated ecosystem service assessment in an artificial desert oasis of northwestern China

Spatially explicit integrated assessment of ecosystem services is a new and important research field in landscape ecology. The objective of this paper was to develop an integrated process-based modeling method to simulate changes in multiple ecosystem services in 2000–2009 at pixel and regional scales in the Zhangye oasis of northwestern China. Six ecosystem service indicators were selected and quantified using process-based models, including net primary production (NPP), grain production, net oxygen production (NOP), carbon sequestration (CS), water conservation, and soil conservation. Analytical results were as follows: (1) At the oasis scale, NPP, NOP, CS, water conservation, and soil conservation decreased from 2000 to 2009, whereas grain production increased. (2) At the pixel scale, the spatial changes in NPP were similar to those in NOP and CS, but changes in grain production showed the opposite pattern. Water conservation and soil conservation showed somewhat unintuitive spatial patterns. (3) The impact of land-use forms on ecosystem services showed that grazing and township construction both had negative impacts on all services, but that nature conservation and wetland development had positive impacts on all services. This research showed that the integrated modeling can be proposed as an environmental decision-making tool in similar case studies.     

考虑冰风载荷影响的输电线路运行风险评估方法*

为预防在极端冰灾环境下大规模停电事故的发生，提出1种考虑冰风载荷的输电线路运行风险评估方法。在极端冰风环境下，计算输电线路与杆塔所承受的总载荷，利用强度与应力干涉模型确定输电线路与杆塔的故障率，同时结合串联可靠性原理确定线路故障综合概率；利用非贯序蒙特卡洛法与线路故障综合概率设置预想故障集，结合直流潮流优化模型计算每条线路的失负荷量；综合考虑负荷等级与抢修恢复时间，确定线路失负荷的经济价值并定义为故障后果；将故障后果与线路故障综合概率的乘积定义为输电线路风险评估指标。以实际拓扑结构修正的IEEE30节点开展算例分析。结果表明:所提方法可对输电线路运行风险进行有效评估。     

Polystyrene microplastics induce blood–testis barrier disruption regulated by the MAPK-Nrf2 signaling pathway in rats

Environmental Science and Pollution Research - As a persistent pollutant, microplastics (MPs) have been reported to induce sperm quantity decrease in mice. However, the related mechanism remains...     

膜分离—变压吸附耦合工艺处理催化剂载体生产废气

采用膜分离—变压吸附耦合工艺处理DQ催化剂载体生产过程产生的高浓度挥发性有机物（VOCs）废气。实验结果表明：在进气正己烷和非甲烷总烃的质量浓度分别为95 000~212 000 mg/m³和100 000 ~220 000 mg/m³、渗余侧压力0.25 MPa、渗透侧真空度0.09 MPa、进气流量15 Nm³/h的条件下,膜分离单元对废气中正己烷及非甲烷总烃的平均去除率分别为97.88%和97.29%;变压吸附单元对正己烷及非甲烷总烃的平均去除率分别为99.35%和99.33%;整套装置对正己烷及非甲烷总烃的平均总去除率分别为99.99%和99.98%。平均正己烷回收率达95.56%。处理后废气中非甲烷总烃质量浓度小于70 mg/ m³,达到北京市DB 11/ 447—2007 《炼油与石油化学工业大气污染物排放标准》的一级指标。     

用稳健统计法处理方法标准验证实验中方法检出限数据

方法检出限是分析方法基本性能参数之一。根据《环境监测分析方法标准制修订技术导则》(HJ 168—2010)的要求,此参数需要6家以上实验室基于特定样品测试数据的标准偏差得到。目前,标准文本大多采用各家实验室方法检出限中最大值。研究提出用稳健统计法处理方法验证数据,无需识别和删去离群值,可将离群值的影响降到最小。基于4组公开发表数据和2组实测数据,比较了不同方法计算结果。结果表明:参与统计的3组数据29个检测项目中,常规方法确认的方法检出限被判为离群值占27.6%。取最大值存在数值偏高的风险。提出了用曼德尔k检验法识别1组方法检出限数据中的离群值,该方法同样可以用于实验室数据与标准文本中方法检出限符合性判断。