Photochemical behaviour of the systemic fungicide carboxin

Irradiation of carboxin (1) with a 500 W UV lamp (filter Pyrex) in CH3CN leads to the products 3, 5-8, 12-14 depending upon the reaction conditions. All photo-products were isolated and characterized. Photooxidation occurred even if unsensitized, while photoalteration was very slow in the absence of oxygen. The main oxygenated-products 3 and 13 were also recovered under biomimetic conditions by exposure of an aqueous solution of 1 to sunlight.     

Life cycle energy and CO2 emissions analysis of food packaging: an insight into the methodology from an Italian perspective

Packaging is strictly connected to environmental issues as it is a product characterised by high material consumption rate; it is often transported over long distances and has a short life. Providing environmental analysis is, therefore, urgent to identify energy and resources efficient solutions. The paper, taking advantage of a real case study, presents a life cycle-based comparative analysis among three different food packaging systems. The paper compares the life cycle of tin steel, polypropylene and glass-based packaging of an Italian preserves producer. The analysis leads to the conclusion that, for the baseline scenario, polypropylene packaging represents the greenest solution, whereas glass packaging is the worst choice. The paper presents a scenario analysis varying both the method used for accounting for recycling as well as the recycling rates of the packaging materials. Changes in overall results with parameters analysis changing are calculated and highlighted throughout the paper. The impact of a reuse policy of the glass-based solution is also analysed; a model for disposable glass packaging is proposed and the obtained results are compared with the single use polypropylene and tin steel-based packaging. In order to analyse the impact of different End of Life scenarios on the present case study, collecting as well as recycling rates of some European countries have been used. The results revealed a significant fluctuation both in energy consumption and in CO₂ emission as the nation changes. Summing up, a methodology for packaging environmental impact analysis is applied to a real case study, some crucial aspects of the methodology have been analysed in depth in order to give a contribution in packaging environmental impact analysis.     

Passive acoustic monitoring of the decline of Mexico's critically endangered vaquita

The vaquita (Phocoena sinus) is the world's most endangered marine mammal with approximately 245 individuals remaining in 2008. This species of porpoise is endemic to the northern Gulf of California, Mexico, and historically the population has declined because of unsustainable bycatch in gillnets. An illegal gillnet fishery for an endangered fish, the totoaba (Totoaba macdonaldi), has recently resurged throughout the vaquita's range. The secretive but lucrative wildlife trade with China for totoaba swim bladders has probably increased vaquita bycatch mortality by an unknown amount. Precise population monitoring by visual surveys is difficult because vaquitas are inherently hard to see and have now become so rare that sighting rates are very low. However, their echolocation clicks can be identified readily on specialized acoustic detectors. Acoustic detections on an array of 46 moored detectors indicated vaquita acoustic activity declined by 80% between 2011 and 2015 in the central part of the species’ range. Statistical models estimated an annual rate of decline of 34% (95% Bayesian credible interval –48% to –21%). Based on results from 2011 to 2014, the government of Mexico enacted and is enforcing an emergency 2‐year ban on gillnets throughout the species’ range to prevent extinction, at a cost of US$74 million to compensate fishers. Developing precise acoustic monitoring methods proved critical to exposing the severity of vaquitas’ decline and emphasizes the need for continual monitoring to effectively manage critically endangered species.     

Evaluating the causal basis of ecological success within the scleractinia: an integral projection model approach

Many tropical corals have declined in abundance in the last few decades, and evaluating the causal basis of these losses is critical to understanding how coral reefs will change in response to ongoing environmental challenges. Motivated by the likelihood that marine environments will become increasingly unfavorable for coral growth as they warm and become more acidic (i.e., ocean acidification), it is reasonable to evaluate whether specific phenotypic traits of the coral holobiont are associated with ecological success (or failure) under varying environmental conditions including those that are adverse to survival. Initially, we asked whether it was possible to identify corals that are resistant or sensitive to such conditions by compiling quantitative measures of their phenotypic traits determined through empirical studies, but we found only weak phenotypic discrimination between ecological winners and losers, or among taxa. To reconcile this outcome with ecological evidence demonstrating that coral taxa are functionally unequal, we looked beyond the notion that phenotypic homogeneity arose through limitations of empirical data. Instead, we examined the validity of contemporary means of categorizing corals based on ecological success. As an alternative means to distinguish among functional groups of corals, we present a demographic approach using integral projection models (IPMs) that link organismal performance to demographic outcomes, such as the rates of population growth and responses to environmental stress. We describe how IPMs can be applied to corals so that future research can evaluate within a quantitative framework the extent to which changes in physiological performance influence the demographic underpinnings of ecological performance.     

Does community resilience decrease social–ecological vulnerability? Adaptation pathways trade-off in the Bolivian Altiplano

Worsening climate change impacts and environmental degradation are increasingly supporting policies and plans in framing a linear understanding of resilience building and vulnerability reduction. However, adaptations to different but interacting drivers of change are unclear in the mix of opportunities and threats related to increasing connections, emerging technologies, new patterns of dependency and possible lock-in effects. This paper discusses a more open-ended understanding of the relationship between resilience and vulnerability, highlighting emerging trade-offs among adaptive capacities and exposures to different (and new) threats as they relate to social–ecological sustainability. The transition of the Southern Bolivian Altiplano, from being a remote rural area of subsistence farming to a global leader in quinoa production and exportation, has been taken as a study case. Results from 18 workshops organised within different communities provide insights about a range of trade-offs between community resilience attributes and social–ecological vulnerability induced from land use changes, livestock strategies, communities’ behavioural change and institutions’ emerging policies. The main theoretical advances of the paper relate to the need for critically framing multiple threat exposures and adaptive capacity trade-offs, contributing to arguing the usually positive meaning of resilience, and taking into account “to whom or to what is positive which adaptation” and “which trade-off should be accepted, and why”. Framing adaptive pathways through these questions would serve as a tool for addressing sustainable development goals, while avoiding lock-ins or unsustainable path dependencies.     

Assessment of Jatropha curcas L. biodiesel seed cake toxicity using the zebrafish (Danio rerio) embryo toxicity (ZFET) test

Consequent to the growing demand for alternative sources of energy, the seeds from Jatropha curcas remain to be the favorite for biodiesel production. However, a significant volume of the residual organic mass (seed cake) is produced during the extraction process, which raises concerns on safe waste disposal. In the present study, we assessed the toxicity of J. curcas seed cake using the zebrafish (Danio rerio) embryotoxicity test. Within 1-h post-fertilization (hpf), the fertilized eggs were exposed to five mass concentrations of J. curcas seed cake and were followed through 24, 48, and 72 hpf. Toxicity was evaluated based on lethal endpoints induced on zebrafish embryos namely egg coagulation, non-formation of somites, and non-detachment of tail. The lowest concentration tested, 1 g/L, was not able to elicit toxicity on embryos whereas 100 % mortality (based also on lethal endpoints) was recorded at the highest concentration at 2.15 g/L. The computed LC50 for the J. curcas seed cake was 1.61 g/L. No further increase in mortality was observed in the succeeding time points (48 and 72 hpf) indicating that J. curcas seed cake exerted acute toxicity on zebrafish embryos. Sublethal endpoints (yolk sac and pericardial edema) were noted at 72 hpf in zebrafish embryos exposed to higher concentrations. The observed lethal endpoints induced on zebrafish embryos were discussed in relation to the active principles, notably, phorbol esters that have remained in the seed cake even after extraction.     

On-field investigation and process modelling of End-of-Life Vehicles treatment in the context of Italian craft-type Authorized Treatment Facilities

The present article analyses the current situation of End-of-Life-of-Vehicles (ELVs) management in Europe, with particular attention on Italian condition. Similarly to other European countries, metal recycling is the main activity of the whole system, but such situation is evolving due to the 2000/53/EC Directive, which sets out targets for Reuse, Recycling and Recovery of ELVs. Due to the relevance of the ELVs problem, in 2008 Italian Ministry of Environment subscribed a framework agreement with competent stakeholders as carmakers, dismantlers, shredders. The main result is an industrial plan to promote (amongst other objectives) technological progress for residual waste (Automotive Shredder Residue – ASR) treatment. According with Italian Trial 2006 analysis about ELVs, Reuse and Recycling rate is currently estimated to be about 81%.At the present time, dismantling plants constitute the first collection points for ELVs; for this reason, during 2009 an investigation has been done over a number of ten Authorized Treatment Facilities (ATFs) operating in Italy. The first step of the analysis was aimed to find out major practices and methods through observations of ATFs activities and interviews to operators. Furthermore, the depollution and dismantling treatments of about 70 different ELVs have been observed and timed in detail over a period of three months. The results included the identification of most relevant critical issues in ELVs treatment, such as distortions between scrapping activities and Directive’s regulation, and the assessment of the time and of the resources needed to perform each operation.In the second step of the survey, a process simulation model has been built on the basis of such data. The model was aimed to include the real variability and all the uncertainties that are typical of dismantling activities; it is intended as a tool for process layout planning and for its management. Some control parameters have been introduced; these are able to dynamically modify process path depending on ELVs queues and priorities. The model can also be used for the economic assessments of single operations or of the whole treatment activity.     

Two-stage estimation of ungulate abundance in Mediterranean areas using pellet group count

A design-based strategy for estimating wildlife ungulate abundance in a Mediterranean protected area (Maremma Regional Park) is considered. The estimation is based on pellet group count (clearance count technique) in a set of plots, whose size and number is established on the basis of practical considerations and available resources. The sampling scheme involves a preliminary stratification and subsequent two-stage sampling. In the first stage, large strata (defined through habitat features) are partitioned into spatial units and a sample of units is selected by means of a sampling scheme ensuring inclusion probabilities proportional to unit size, but avoiding the selection of contiguous units. Then, the abundances of the selected units are estimated in a second stage, in which plots are located using a random scheme ensuring an even coverage of the units. In small strata, only the second stage is performed. Unbiased estimators of abundance and conservative estimators of their variances are derived for each strata and for the whole study area. The proposed strategy has been applied since the Summer of 2006 and the estimation results reveal substantial improvement with respect to the previous results obtained by means of an alternative strategy.