Arsenic in groundwater in six districts of West Bengal,India

Arsenic in groundwater above the WHO maximum permissible limit of 0.05 mg l^–1 has been found in six districts of West Bengal covering an area of 34 000 km² with a population of 30 million. At present, 37 administrative blocks by the side of the River Ganga and adjoining areas are affected. Areas affected by arsenic contamination in groundwater are all located in the upper delta plain, and are mostly in the abandoned meander belt. More than 800 000 people from 312 villages/wards are drinking arsenic contaminated water and amongst them at least 175 000 people show arsenical skin lesions. Thousands of tube-well water in these six districts have been analysed for arsenic species. Hair, nails, scales, urine, liver tissue analyses show elevated concentrations of arsenic in people drinking arsenic-contaminated water for a longer period. The source of the arsenic is geological. Bore-hole sediment analyses show high arsenic concentrations in only few soil layers which is found to be associated with iron-pyrites. Various social problems arise due to arsenical skin lesions in these districts. Malnutrition, poor socio-economic conditions, illiteracy, food habits and intake of arsenic-contaminated water for many years have aggravated the arsenic toxicity. In all these districts, major water demands are met from groundwater and the geochemical reaction, caused by high withdrawal of water may be the cause of arsenic leaching from the source. If alternative water resources are not utilised, a good percentage of the 30 million people of these six districts may suffer from arsenic toxicity in the near future.     

Sustainability of metal recovery from E-waste

The issue of E-waste disposal is concerning all the stakeholders, from policymakers to the end users which have accelerated the research and development on environmentally sound disposal of E-waste. The recovery of metals (gold, tantalum, copper, iron etc.) from E-waste has become an important focus. The mechanical recycling, thermo-chemical processes like pyrolysis, pyro-, hydro- and biometallurgical processes can play important roles in the Metal Recovery from E-waste (MREW) technology. For the industrial application of the MREW technology, it is important to analyze the sustainability. In this paper, two case studies have been presented on E-waste recycling industries in India and China. Based on the literature data, an attempt has been made to assess qualitatively the overall sustainability of MREW technology considering the three pillars, i.e., environmental, economic and social. Two conceptual frameworks with (Option-2) and without (Option-1) pyrolysis for integrated MREW units have been developed and the generalized energy and environmental impact analysis has been made using the principles of LCA. The impacts of two options have been compared. Option 2 has been found to be more efficient and sustainable. It has been realized that climate change, fossil fuel depletion, water depletion, eutrophication, acidification, fresh and marine water ecotoxicity are possible impact categories. The recommendations based on the generalized assessment are in good agreement with the findings of previous researchers on individual steps of MREW unit. The findings of this paper are expected to be beneficial to researchers and stakeholders for research directions and decision making on MREW.

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Extraction of keratin from keratinous wastes: current status and future directions

Journal of Material Cycles and Waste Management - This review aims to trace the developments of keratin extraction techniques over the last 70 years and possibilities for future research....     

Minimum turbulence assumptions and u* and L estimation for dispersion models during low-wind stable conditions

The U.S. Environmental Protection Agency (EPA) short-distance dispersion model, AERMOD, has been shown to overpredict by a factor of as much as 10 when compared with observed concentrations from continuous releases at the Oak Ridge, TN (OR), and Idaho Falls, ID (IF), field experiments during stable periods when wind speeds often dropped below 1 m/sec. Some of this overprediction tendency can be reduced by revising AERMOD's meteorological preprocessor's parameterizations of the friction velocity, u _* , during low-wind stable conditions, thus increasing the calculated σ _v and σ _w and hence the lateral and vertical dispersion rates. Observations show that as the mean wind speed approaches zero at night, there is always significant σ _v and σ _w over time periods of 15 to 60 min, while standard Monin–Obukhov Similarity Theory (MOST) predicts that σ _v and σ _w will approach zero. This paper focuses on the u _* estimation methods and the minimum turbulence (σ _v and σ _w ) assumptions in AERMOD (beta option 4) and two widely used U.S. operational dispersion models, AERMOD (v12345) and SCICHEM. The U.S. EPA has provided results of its tests with the OR and IF data, with its base AERMOD version and its December 2012 modified versions, which assume adjustments to the low-wind u _* and increases in the minimum σ _v parameterization. SCICHEM has relatively small mean bias for both data sets. The revised AERMOD shows much less mean bias, agreeing more with SCICHEM.

Implications:

Suggestions are made for improvements to dispersion models such as AERMOD to correct overpredictions during light-wind stable conditions. Methods for estimating u_*, L, and the minimum turbulence parameters (σ_v and σ_w) are reviewed and compared. SCICHEM and the current operational version and an optional beta version (December 2012) of AERMOD are evaluated with tracer data from low-wind stable field experiments in Idaho Falls and Oak Ridge. It is seen that the operational version of AERMOD overpredicts by a factor of 2 to 10, while the optional beta version of AERMOD and SCICHEM have much less bias.     

Fuzzy synthetic evaluation of treated wastewater reuse for agriculture

Reuse of treated wastewater (TWW) for agriculture is in practice in many countries. TWW reuse requires wastewater collection, treatment and recycling, which is associated with cost as well as risk to human and ecological systems. In contrast, it can increase agricultural production and reduce environmental risks by reducing wastewater discharge into the natural environment. In Saudi Arabia, where available water resources are extremely limited, TWW reuse can save significant amount of non-renewable groundwater used in agricultural development, which is a strategic goal for the country. In this paper, a multicriteria decision-making approach was developed where cost, risk, benefits and social acceptance of TWW reuse were considered to be the main criteria. A multistage hierarchy risk management model was constructed for this evaluation. Fuzzy synthetic evaluation technique was incorporated where fuzzy triangular membership functions were developed to capture uncertainties of the basic criteria. The analytic hierarchy process was used to determine the relative importance of various criteria at different hierarchy levels. This study indicated that TWW reuse could have positive impact on agriculture, risk reduction and groundwater conservation.     

Arsenic removal methods for drinking water in the developing countries: technological developments and research needs

Arsenic pollution of drinking water is a concern, particularly in the developing countries. Removal of arsenic from drinking water is strongly recommended. Despite the availability of efficient technologies for arsenic removal, the small and rural communities in the developing countries are not capable of employing most of these technologies due to their high cost and technical complexity. There is a need for the “low-cost” and “easy to use” technologies to protect the humans in the arsenic affected developing countries. In this study, arsenic removal technologies were summarized and the low-cost technologies were reviewed. The advantages and disadvantages of these technologies were identified and their scopes of applications and improvements were investigated. The costs were compared in context to the capacity of the low-income populations in the developing countries. Finally, future research directions were proposed to protect the low-income populations in the developing countries.     

Monitoring and modelling of siloxanes in a sewage treatment plant in the UK

Monitoring of cyclic volatile methylsiloxanes (cVMS) carried out at Anglian Water’s Broadholme sewage treatment plant (STP) is described. The method deployed used headspace gas chromatography/mass spectrometry (HS-GC/MS) and the addition of isotopically labelled cVMS to correct for partitioning in samples containing high levels of particulate and dissolved organic carbon. The method was capable of measuring cVMS in raw sewage samples, with recoveries of 80%, 85% and 71% respectively, for D₄, D₅ and D₆. The limit of quantification was 0.2 μg L⁻¹ for all three substances. Recoveries close to 100% were observed for all cVMS spiked into treated effluent (LOQ = 0.01 μg L⁻¹). Despite the volatile nature of cVMS and its ubiquitous presence in the ambient atmosphere, the methods deployed showed excellent recoveries, reproducibility and quantification limits. A distinct diurnal variation in cVMS concentration, probably linked with the use of personal care products was observed for raw sewage but not in treated sewage effluent. The estimated per capita consumption of D₅ (∼2.7 mg cap⁻¹ d⁻¹) derived for the population served by this plant was significantly lower than that derived in the Environment Agency (UK) risk assessment (11.6 mg cap⁻¹ d⁻¹). The cVMS were highly removed during sewage treatment with efficiencies greater than 98%. The methods and findings of this pilot study can be used as the basis for future studies on the fate of cVMS substances in STPs.     

Photolysis of oxyfluorfen in aqueous methanol

Photolysis of oxyfluorfen, an herbicide of the nitrodiphenyl ether class, was studied in aqueous methanol under UV and sunlight. UV irradiation was carried out in a borosilicate glass photoreactor (containing 250 ppm oxyfluorfen in 50% aqueous methanol) equipped with a quartz filter and 125 watt mercury lamp (maximum output 254 nm) at 25 ± 1°C. Sunlight irradiation was conducted at 28 ± 1°C in borosilicate Erlenmeyer flasks containing 250 ppm oxyfluorfen in 50% aqueous methanol. The samples from both the irradiated conditions were withdrawn at a definite time interval and extracted to measure oxyfluorfen content by gas chromatography-flame ionization detector for rate study. The half-life values were 20 hours and 2.7 days under UV and sunlight exposure, respectively. Photolysis of oxyfluorfen yielded 13 photoproducts of which three were characterized by infrared spectrophotometer and ¹H NMR and ¹³C NMR spectroscopy. The rest of the photoproducts were identified by gas chromatography-mass spectrometry (GC-MS) and thin layer chromatography (TLC). An ionization potential 70 eV was used for electron impact-mass spectrometry (EI-MS) and methane was used as reagent gas for chemical ionization-mass spectrometry (CI-MS). Two of the photoproducts were also synthesized for comparison. The main phototransformation pathways of oxyfluorfen involved nitro reduction, dechlorination, and hydrolysis as well as nucleophiles displacement reaction.     

Spatio-temporal analysis of climatic variables in the western part of Bangladesh

Monitoring and detecting trends of climatic variables like rainfall and temperature are essential for agricultural developments in the context of climate change. The present study has detected trends in annual and cropping seasonal rainfall and temperature data for the period of 1961–2011 using Mann–Kendall (MK) test, Spearman’s rho (SR) test and modified Mann–Kendall test that has been applied to the significant lag-1 serial correlated time series data, and slope has been estimated using Sen’s Slope estimator for twelve meteorological stations located in the western part of Bangladesh covering about 41 % of the country. Almost 71 % trends explored by MK test in annual rainfall are statistically insignificant, and SR test also complies it. The spatial distribution of rainfall trend shows insignificant positive trends in major part of the area. Significant positive trends both by MK test and by SR test at 95 % confidence levels are observed at rates of 8.56, 11.15 and 13.66 mm/year at Dinajpur, Rangpur and Khepupara stations, respectively, and the Kharif season rainfall of these stations also shows significant increasing trends except Dinajpur. On the other hand, significant decreasing trends in annual rainfall are found at Bhola (?11.67 mm/year) and Rajshahi (?5.951 mm/year) stations and decreasing trends in rainfall dominated the Pre-Kharif season over the area. But, 83.33 % of the stations show rising trends in annual mean temperature with significant positive trends (as observed by both MK test and SR test) at Rangpur, Bogra, Faridpur, Jessore and Bhola stations where the rate of changes vary from 0.013 °C/year at Faridpur to 0.08 °C/year at Bhola. Most of the trends in Rabi and Pre-Kharif seasons of mean temperatures are not statistically significant. However, all stations except Barisal show significant rising trends in temperature in Kharif season. To cope with this changing pattern of rainfall and temperature, effective adaptation strategies should be taken to keep up the agricultural production that is related to livelihood of the most people and to ensure the country’s food security.     

Heterotrophic bacteria in drinking water distribution system: a review

The microbiological quality of drinking water in municipal water distribution systems (WDS) depends on several factors. Free residual chlorine and/or chloramines are typically used to minimize bacterial recontamination and/or regrowth in WDS. Despite such preventive measures, regrowth of heterotrophic (HPC) and opportunistic bacteria in bulk water and biofilms has yet to be controlled completely. No approach has shown complete success in eliminating biofilms or HPC bacteria from bulk water and pipe surfaces. Biofilms can provide shelter for pathogenic bacteria and protect these bacteria from disinfectants. Some HPC bacteria may be associated with aesthetic and non-life threatening diseases. Research to date has achieved important success in understanding occurrence and regrowth of bacteria in bulk water and biofilms in WDS. To achieve comprehensive understanding and to provide efficient control against bacteria regrowth, future research on bacteria regrowth dynamics and their implications is warranted. In this study, a review was performed on the literature published in this area. The findings and limitations of these papers are summarized. Occurrences of bacteria in WDS, factors affecting bacteria regrowth in bulk water and biofilms, bacteria control strategies, sources of nutrients, human health risks from bacterial exposure, modelling of bacteria regrowth and methods of bacteria sampling and detection and quantification are investigated. Advances to date are noted, and future research needs are identified. Finally, research directions are proposed to effectively control HPC and opportunistic bacteria in bulk water and biofilms in WDS.