基于Paircopula函数和标准化径流指数的水文干旱频率分析——以南盘江流域为例

选取南盘江流域3个水文站52 a（1961~2012年）的逐月径流资料,联合两个相邻站点,分别计算标准化径流指数（SSFI）,运用游程理论识别52 a来不同站点干旱特征,并用Pair copula函数计算不同站点的联合重现期。结果表明：（1）52 a来3个站点干旱特征值的最大值都出现在2011~2012年;从单个站点看,52 a来沾益站的干旱次数、最大干旱历时、最大干旱烈度均大于高谷马站和江边街站,最大干旱峰值出现在江边街站;从联合站点看,中游以上高谷马站和沾益站的干旱特征值均大于中游以下高谷马站和江边街站,3个站点联合识别的干旱特征值大于中下游站点联合识别干旱特征值,小于中上游站点联合识别干旱特征值,上游干旱更严重;（2）Frank Pair copula函数的RMSE、AIC和BIC值最小,拟合程度最高,适合运用于南盘江流域干旱频率分析中;（3）运用Frank Pair copula函数计算得到3个水文站点2009~2012年的连续干旱重现期都在100~200 a,是52 a来最严重的一次干旱     

基于典型道路谱的模拟运输振动试验方法研究

针对深圳某一路段使用美国Lansmont公司开发的SAVER环境应力记录仪记录汽车运输过程中的环境应力,利用相关处理软件整理分析数据,最后在实验室中的通过电磁振动台的随机振动模式来进行模拟重现从而实现“Fieldtolab”。该方法用短时间的实验室内试验来代替长时间的实际运输过程,不仅绿色环保,而且省时省力,是一种值得推广的试验方法。     

陇东油田井场油泥微生物处理应用

为解决石油开采及油井措施作业过程中原油散落井场产生油泥,污染井场周围土壤、水体、空气的现状,文章介绍了一种针对生态环境脆弱的陇东油田井场油泥微生物处理技术,可以实现对井场油泥环保、经济、有效处理。     

Possible alkylation of inorganic Hg(II) by photochemical processes in the environment

Contamination of surface waters by pesticides continues to be the focus of concern for water authorities due to the growing evidence of their deleterious effects on aquatic life. In this context, the present work investigates the occurrence of 16 selected pesticides belonging to the classes of triazines, phenylureas, organophosphates, chloroacetanilides and thiocarbamates in surface waters from the Llobregat River (NE Spain) and some of its tributaries (Anoia and Rubí) and assesses their potential impact on the aquatic organisms by applying a recently developed index, the Short-term Pesticide Risk Index for the Surface Water System (PRISW-1), which takes into account the pesticides concentrations and their overall toxicity against three aquatic organisms (algae, Daphnia, and fish). Chemical analysis, performed by means of a fully automated method based on isotope dilution on-line solid phase extraction-liquid chromatography-electrospray-tandem mass spectrometry (on-line SPE-LC-ESI-MS/MS), revealed diuron and diazinon as the most ubiquitous and abundant compounds with levels up to 818 and 132 ng L⁻¹, respectively. Total pesticide concentrations, which in only 1 out of 66 samples surpassed 500 ng L⁻¹, were higher in the tributaries than in the river but their contribution in terms of mass-loads to the overall pesticide pollution of the Llobregat River was relatively small. Contamination increased downstream of the river and was clearly influenced by rainfall and hence river flow. Application of the PRISW-1 index indicated that, although pesticides levels fulfilled the European Union Environmental Quality Standards (EQS) for surface waters, the existing pesticide contamination poses a low to high ecotoxicological risk for aquatic organisms, that algae and macro-invertebrates are at higher risk than fish, and that the organophosphates diazinon and malathion and the phenylurea diuron are the major contributors to the overall toxicity and therefore the most problematic compounds.     

Brassinosteroid alleviates phenanthrene and pyrene phytotoxicity by increasing detoxification activity and photosynthesis in tomato

The present study was carried out to investigate the effects of exogenously applied 24-epibrassinolide (BR) on growth, gas exchange, chlorophyll fluorescence characteristics, lipid peroxidation and antioxidant systems of tomato seedlings grown under different levels (0, 10, 30, 100 and 300 μM) of phenanthrene (PHE) and pyrene (PYR) in hydroponics. A concentration-dependent decrease in growth, photosynthetic pigment contents, net photosynthetic rate (Pn), stomatal conductance (Gs), maximal quantum yield of PSII (Fv/Fm), effective quantum yield of PSII (Φ_PSII), photochemical quenching coefficient (qP) has been observed following PHE and PYR exposure. By contrast, non-photochemical quenching coefficient (NPQ) was increased. PHE was found to induce higher stress than PYR. However, foliar or root application of BR (50 nM and 5 nM, respectively) alleviated all those depressions with a sharp improvement in the activity of photosynthetic machinery. The activities of guaicol peroxidase (GPOD), catalase (CAT), ascorbate peroxidase (APX) and glutathione reductase (GR) as well as content of malondialdehyde (MDA) were increased in a dose-dependent manner under PHE or PYR treatments. Compared with control the highest increments of GPOD, CAT, APX, GR and MDA by PHE/PYR alone treatments were observed following 300 μM concentration, which were 67%, 87%, 53%, 95% and 74% by PHE and 42%, 53%, 30%, 86% and 62% by PYR, respectively. In addition, both reduced glutathione (GSH) and oxidized glutathione (GSSG) were induced by PHE or PYR. Interestingly, BR application in either form further increased enzymatic and non enzymatic antioxidants in tomato roots treated with PHE or PYR. Our results suggest that BR has an anti-stress effect on tomato seedlings contaminated with PHE or PYR and this effect is mainly attributed by increased detoxification activity.     

Seasonal variations of CH(4) and N(2)O emissions in response to water management of paddy fields located in Southeast China

Water management is one of the most important practices that affect methane (CH₄) and nitrous oxide (N₂O) emissions from paddy fields. A field experiment was designed to study the effects of controlled irrigation (CI) on CH₄ and N₂O emissions from paddy fields, with traditional irrigation (TI) as the control. The effects of CI on CH₄ and N₂O emissions from paddy fields were very clear. The peaks of CH₄ emissions from the CI paddies were observed 1-2 d after the water layer disappeared. Afterward, the emissions reduced rapidly and remained low until the soil was re-flooded. A slight increase of CH₄ emission was observed in a short period after re-flooding. N₂O emissions peaks from CI paddies were all observed 8-10 d after the fertilization at the WFPS ranging from 78.1% to 85.3%. Soil drying caused substantial N₂O emissions, whereas no substantial N₂O emissions were observed when the soil was re-wetted after the dry phase. Compared with TI, the cumulative CH₄ emissions from the CI fields were reduced by 81.8% on the average, whereas the cumulative N₂O emissions were increased by 135.4% on the average. The integrative global warming potential of CH₄ and N₂O on a 100-year horizon decreased by 27.3% in the CI paddy fields, whereas no significant difference in the rice yield was observed between the CI and TI fields. These results suggest that CI can effectively mitigate the integrative greenhouse effect caused by CH₄ and N₂O emissions from paddy fields while ensuring the rice yield.     

突发性河流污染事故水质预警模型

研究河流中污染物的输移扩散及其影响因素,引入死区预警模型及其解析解,模拟污染物在水体中的时空变化,进而预测污染物到达下游特定地点的浓度值及相应时间.实例模拟结果,尤其是对下游断而污染物最大浓度值及其出现时间的预测结果较好,表明建立的模型能够较准确地模拟河流中污染物的输移扩散规律.本研究可为环境风险管理及突发性环境污染应急预案的制定提供科学依据.     

多目标决策方法在防台风中的应用

提出了一种基于不确定信息和蒙特卡罗模拟的多目标决策方法,在投入一定的情况下,选取最合适的台风防灾减灾措施.该方法允许决策者对不同属性指标给出相应的效用函数和属性权重区间值,通过随机选取权重值和效用函数区间内的值相乘得出结果,并使用蒙特卡罗模拟技术对结果进行了敏感性分析.最后,以浙江省台风灾害防灾减灾措施的比较为例,详细讨论了该方法的应用.     

高速铁路动车组列车的噪声特性

测量了车速达250 km/h的高速铁路动车组列车不同距离、不同高度处的噪声,分析了其时间、频谱及空间分布特性,并与普通客运列车比较.结果表明,动车组列车噪声表现为较强的脉冲性,频谱较宽,为2 500 Hz内的宽频噪声,200 Hz以下的低频成分很强;不同高度处最大声压级随距离的衰减规律基本类似,但不同高度处频谱不同.