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11.
Nonvolatile neutral organic compounds in tap water were examined by high-pressure liquid chromatography, infrared spectrometry, 1H- and 13C-FT-NMR, gel permeation chromatography, elementary analysis, and field desorption mass spectrometry. Neutral organic compounds in 10 m3 of tap water were continuously extracted by the Amberlite XAD-2 resin column, and separated into four fractions by silica-gel column chromatography. Removal of volatile compounds in fraction 3 including polar oxygenated compounds was carried out with microdistillation column under high vacuum by using a diffusion pump. Nonvolatile organic compounds isolated from tap water were identified as poly(vinyl acetate) derivatives with molecular weights ranging from 300 to 1300. 相似文献
12.
We investigated the horizontal distributions of (228)Ra and (226)Ra in surface waters of the northwestern North Pacific Ocean and Okhotsk Sea. Ratios of (228)Ra/(226)Ra were relatively large in the Tsugaru Current (0.6-0.8) and Okhotsk Sea (0.4-0.5), and small in the Western Subarctic Gyre (<0.2) and the Oyashio (0.25-0.3). (228)Ra/(226)Ra ratios in western Subarctic Water (SAW) rose slightly upon mixing with Okhotsk Water (OKW), before becoming the Oyashio Water (OYW). Also, ratios in the OYW increased during mixing with Tsugaru Current Water (TCW). Estimating from (228)Ra/(226)Ra ratios and (226)Ra activities with a simple two-end members-mixing model, we assumed that approximately 23% of the OYW originated from the OKW and the coastal region off northern Honshu (Japan) was strongly influenced by the TCW. From a diagram of (228)Ra activities against salinity, we could roughly divide surface seawater in the study area into the five water masses, which were SAW, OYW, OKW, TCW, and Subtropical Water (STW). 相似文献
13.
To study the role of zooplankton in the transport of (137)Cs in the ocean, zooplankton samples were collected in October 2005 and June 2006 in the western North Pacific Ocean. The peak zooplankton biomass was observed in the surface layer, and gelatinous plankton was more abundant in October 2005 than in June 2006 reflecting exchange of water masses. The concentrations of (137)Cs in zooplankton varied from 11 to 24 mBq kg wet(-1) and were higher in October 2005 than in June 2006. The elevated abundance of gelatinous zooplankton probably led to higher concentration of (137)Cs in zooplankton in October 2005. Annual export fluxes of (137)Cs by ontogenetic vertical migrant copepods were estimated to be 0.8 and 0.6 mBq m(-2) year(-1) at 200 and 1000 m depths, respectively; this suggested that transport of (137)Cs by zooplankton may be no trivial pathway. 相似文献
14.
Masashi Kato Shoko Onuma Yoko Kato Nguyen D. Thang Ichiro Yajima Mohammad Zahirul Hoque 《毒物与环境化学》2013,95(9):1609-1612
Toxic elements present in well water that is used for drinking pose a threat to the human health in many countries. However, there are few reports on the toxic elements in well water in Malaysia. Since a native doctor informed us about the increasing number of patients with depigmented skin (vitiligo) in Rosob Village, Sabah State, Malaysia, the origin of diseases associated with well water was suspected. Thus, the concentrations of 15 toxic elements in 52 well water samples from Rosob (n = 21), and the control areas of Pitas (n = 8) and Telaga (n = 23) within the same state were measured. No toxic elements with levels exceeding that of the WHO health-based guidelines were detected in the well water samples from Pitas and Telaga. On the other hand, the concentration levels of arsenic (As), uranium (U), and manganese (Mn), independently found in 19% (4/21), 4.8% (1/21), and 19% (4/21), respectively, of the well water samples from Rosob, exceeded the levels given in the WHO health-based guidelines. In the well water samples from Rosob, the average concentration of Mn was found to be higher and its maximum value with levels up to 10-fold higher, respectively, than the value in the WHO health-based guidelines. Significant correlations between Mn and As and between Mn and U were noted. Thus, for the first time, the results of this pilot study showed that the levels of the toxic elements in 42.9% (9/21) of well water samples from Rosob in Malaysia were higher than the values in WHO health-based guidelines indicating the need for further studies. 相似文献
15.
Yoshida Y Ito A Murakami M Murakami T Fujimoto H Takeda K Suzuki S Hori M 《Journal of the Air & Waste Management Association (1995)》2007,57(10):1164-1171
Alkylphenol polyethoxylates (APEOs) have been widely used as nonionic surfactants in a variety of industrial and commercial products. Typical compounds are nonylphenol polyethoxylates (NPEOs) and octylphenol polyethoxylates (OPEOs), which serve as precursors to nonylphenol (NP) and octylphenol (OP), respectively. NP and 4-t-OP are known to have endocrine disrupting effects on fish (medaka, Oryzias latipes), so it is important to know the concentrations of APEOs in the environment. Because the analytical characteristics of these compounds depend on the length of the ethoxy chain, it is necessary to use appropriate compounds as internal standards or surrogates. We synthesized two 13C-labeled surrogate compounds and used these compounds as internal standards to determine NPEOs and OPEOs by high-performance liquid chromatography (LC)-mass spectrometry. Method detection limits were 0.015 microg/L for NP (2)EO to 0.037 microg/L for NP(12)EO, and 0.011 microg/L for OP(3,6)EO to 0.024 microg/L for OP (4)EO. NPEO concentrations in water from a sewage treatment plant were less than 0.05-0.52 microg/L for final effluent and 1.2-15 microg/L for influent. OPEO concentrations were less than 0.05-0.15 microg/L for the final effluent and less than 0.05-1.1 microg/L for influent. 相似文献
16.
K. Omasa F. Hosoi T. M. Uenishi Y. Shimizu Y. Akiyama 《Environmental Modeling and Assessment》2008,13(4):473-481
In this study, we confirmed the utility of airborne and portable on-ground scanning light detection and ranging (LIDARs) for
three-dimensional visualization of an urban park and quantification of biophysical variables of trees in the park. The digital
canopy height model (DCHM) and digital terrain model generated from airborne scanning LIDAR data provided precise images of
the ground surface and individual tree canopies. The heights of 166 coniferous and broadleaf trees of 11 species in the park
were estimated from the DCHM images with slight underestimation (mean error = −0.14 m, RMSE = 0.30 m). Portable on-ground
scanning LIDAR provided images of individual trees with detailed features. Tree height and trunk diameter were estimated to
be within 0.31 m and 1 cm, respectively, from the on-ground LIDAR images. We combined airborne and on-ground LIDAR images
to overcome blind regions and created a complete three-dimensional model of three standing trees. The model allowed not only
visual assessment from all viewpoints but also quantitative estimation of canopy volume, trunk volume, and canopy cross-sectional
area. 相似文献
17.
This study attempts a risk-benefit analysis of the Japanese government decision of the prohibition of the mercury electrode process used for production of caustic soda in 1973. The reduction in human health risk and the costs incurred due to the decision are evaluated, on the basis of which an implicit value of its benefit-risk (BRR) ratio is estimated. Human health risk is evaluated in terms of loss of life expectancy, which enables us to quantify and compare human health risks, irrespective of cancer or noncancer toxic risks. The value of BRR of the decision is calculated to be 570 million yen, approximately U.S. $5.7 million, per life-year saved. Comparing the BRR values of a couple of other policies enacted or proposed in Japan, ranging from 24 to 45 million yen per life-year saved, its value is very high. This result implies that the decision in study is not cost-effective. 相似文献
18.
19.
Michihiro Kitagawa Kentaro Sugiura Hiroko Omi Yoshiaki Akiyama Kiyoko Kanayama Masaru Shinya Tadao Tanaka Hirobumi Yura Haruhiko Sago 《黑龙江环境通报》2002,22(1):17-21
To isolate fetal cells from maternal blood, we developed a new method based on galactose-bearing conjugation. Nucleated red blood cells (NRBCs), which highly express galactose on their surface, were selectively attached to a substrate coated with a galactose-containing polymer via soybean agglutinin (SBA), a galactose-specific lectin. Cord blood samples were used to evaluate enrichment efficacy of NRBCs by this method. Blood samples were obtained from 131 pregnant women between 6 and 27 gestational weeks. After preliminary condensation of fetal cells by Ficoll gradient centrifugation, NRBCs were enriched using galactose-positive selection by adjusting SBA concentration. We isolated one to severalhundred NRBCs (mean±SD, 7.8±8.5) in 2.3 ml of peripheral blood samples from 96% of pregnantwomen. The isolated NRBCs were analyzed by a Y-chromosome FISH probe in eight cases carrying male fetuses. Y-signals were detected in all eight cases and more than half of the NRBCs wereoffetal origin. The study demonstrates that our new method using galactose-specific lectin provides effective enrichment of fetal NRBCs allowing non-invasive prenatal diagnosis. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
20.
Yuanyuan Zhang Masashi Kuroda Shunsuke Arai Fumitaka Kato Daisuke Inoue Michihiko Ike 《Frontiers of Environmental Science & Engineering》2019,13(5):68