The use of plate heat exchangers to improve energy efficiency in phosphoric acid production

This paper originated as a part of a comprehensive research project designed to develop ecologically sustainable, environmentally friendly, resource- and energy-saving industrial process technology for the production of a wide class of phosphorus containing substances. The essential feature of the research was designed for the replacement of tubular heat exchangers with Plate heat exchangers (PHEs) and for the installation of these units in new locations in the processes to optimally improve energy efficiency and to prevent pollution. Despite the severe operating conditions in the production of phosphoric acid PHEs of various designs find the application in these processes. For such a corrosive environment as a phosphoric acid production plant, the Hastelloy G30 alloy is used as the material for the plates and synthetic rubber EPDM is used as the material for inter-plate gaskets. The analysis of the data shows, that using mixed groupings of plates in the unit allows one to obtain optimal solutions. The simulation of barometric mixing condenser recycled water cooling with plate heat exchanger shows the possibility of an application which minimizes the waste water pollution by closing the condenser cooling water circuit. Software was developed for calculations of units working both with liquid and phase changing streams.     

Application of multivariate statistical methods for groundwater physicochemical and biological quality assessment in the context of public health

Three representative areas (lowland, semi-mountainous, and coastal) have been selected for the collection of drinking water samples, and a total number of 28 physical, chemical, and biological parameters per water sample have been determined and analyzed. The mean values of the physical and chemical parameters were found to be within the limits mentioned in the 98/83/EEC directive. The analysis of biological parameters shows that many of the water samples are inadequate for human consumption because of the presence of bacteria. Cluster analysis (CA) first was used to classify sample sites with similar properties and results in three groups of sites; discriminant analysis (DA) was used to construct the best discriminant functions to confirm the clusters determined by CA and evaluate the spatial variations in water quality. The standard mode discriminant functions, using 17 parameters, yielded classification matrix correctly assigning 96.97% of the cases. In the stepwise mode, the DA produced a classification matrix with 96.36% correct assignments using only ten parameters (EC, Cl^???, NO₃ ^???, HCO₃ ^???, CO₃ ^???2, Ca^?+?2, Na^?+?, Zn, Mn, and Pb). CA and factor analysis (FA) are used to characterize water quality and assist in water quality monitoring planning. CA proved that two major groups of similarity (six subclusters) between 17 physicochemical parameters are formed, and FA extracts six factors that account for 66.478% of the total water quality variation, when all samples’ physicochemical data set is considered. It is noteworthy that the classification scheme obtained by CA is completely confirmed by principal component analysis.     

Air pollution sources of PM10 in Buenos Aires City

To elucidate the sources of PM(10) air pollution from the experimental information collected in a local air quality monitoring campaign we have applied two methods, effective variance and genetic algorithms, in the solution of the chemical mass balance. The comparison of these two mathematical approaches show that the identification of the possible sources and the evaluation of its contributions are quite independent of them. The role of possible different sources for major and trace elements and the significance of standardizing available data is also addressed. We also present a simple method for identifying the number of candidate sources, a key element defining the dimension of the search space.     

Improving the adsorption capacity and solid structure of natural volcanic soil using a foaming-sintering process based on recycled polyethylene terephthalate (PET).

The volcanic soils of southern Chile have demonstrated a high capacity to adsorb environmental pollutants, but for an industrial application, a stable solid material is necessary. The objective of this work was to produce a stable ceramic material through a process involving volcanic soil-polyurethane foam produced with recycled polyethylene terephthalate (PET)-polyols, and further thermal treatment. The selected foam formulation with 35.4% volcanic soil (< 63 microm) seems to be the most suitable for thermal treatment, with temperature steps at 700, 850, 1000 and 1200 degrees C. The porous ceramic material obtained has a stable solid form and an improved chlorophenols adsorption capacity (comparable to natural zeolites) that makes it suitable for advanced wastewater treatment and landfill leachate depuration.     

Treatment of cork boiling wastewater using chemical oxidation and biodegradation

Three cultures were enriched from cork boiling wastewater using tannic acid as the selective carbon substrate, at 25 degrees C and pH 7.2, 25 degrees C and pH 4.7 and 50 degrees C and pH 4.7. The enrichment culture obtained at neutral pH was composed of five culturable isolates, whereas from each acidic enrichment two bacterial strains were isolated. Mesophilic isolates were Gram negative bacteria belonging to the genera Klebsiella, Pseudomonas, Stenotrophomonas and Burkholderia. Thermophilic isolates were members of the genus Bacillus. Despite the capability of the enrichment cultures to use tannic acid as single carbon and energy source, those cultures were unable to reduce the total polyphenols or the total organic carbon content of cork boiling wastewater. In order to increase the bioavailability of the organic carbon in cork boiling wastewater, biodegradation was preceded by Fenton oxidation. It was demonstrated that the combined process, using small amounts of Fenton reagents and biodegradative inoculum added almost simultaneously to cork boiling wastewater, leads to TOC reductions of more than 90%.     

High mercury bioaccumulation in Pacific salmons from the Sea of Okhotsk and the Bering Sea

Mercury (Hg) accumulation in fishes is a serious threat for food security because mercury induces dieseases. Here we studied the total mercury content in four species of Pacific salmon (pink, chum, sockeye and chinook), caught in the Sea of Okhotsk, the Bering Sea, and the Kuril oceanic waters. Results show that the lowest concentration of mercury was found in the pink salmon, and the highest was 5–6 times higher in sockeye. Hg concentrations exceed several times those in other species of Pacific salmon from the North Pacific     

Job control and occupational health: the moderating role of national R&D activity

Workers (n = 17 275) from 14 European Union (EU) member states provided data on job control, job dissatisfaction, perceived risk of occupational stress, and absence. For each state, level of research and development (R&D) activity was assessed. Associations between individual levels of control and occupational health were stronger where national R&D activity was higher. The moderation occurred for individuals' levels of control in relation to job dissatisfaction, perceived risk of occupational stress, and absence. The findings with job dissatisfaction and absence were replicated in a sample of workers from 10 Eastern European former Communist countries (n = 7926). Copyright © 2007 John Wiley & Sons, Ltd.