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141.
Juhasz AL Smith E Weber J Rees M Rofe A Kuchel T Sansom L Naidu R 《Chemosphere》2008,71(10):1963-1969
Considerable information is available in the literature regarding the uptake of arsenic (As) from contaminated soil and irrigation water by vegetables. However, few studies have investigated As speciation in these crops while a dearth of information is available on As bioavailability following their consumption. In this study, the concentration and speciation of As in chard, radish, lettuce and mung beans was determined following hydroponic growth of the vegetables using As-contaminated water. In addition, As bioavailability was assessed using an in vivo swine feeding assay. While As concentrations ranged from 3.0 to 84.2mg As kg(-1) (dry weight), only inorganic As (arsenite and arsenate) was detected in the edible portions of the vegetables. When As bioavailability was assessed through monitoring blood plasma As concentrations following swine consumption of As-contaminated vegetables, between 50% and 100% of the administered As dose was absorbed and entered systemic circulation. Arsenic bioavailability decreased in the order mung beans>radish>lettuce=chard. 相似文献
142.
With costs of energy and materials increasing compared to other inputs in manufacturing, labour and capital can no longer be regarded as the only criteria for choice of appropriate technology. In the article below the authors offer a broader range of inputs and conclude that optimizing only labour and capital results in erroneous technology choices. 相似文献
143.
Kumar KS Rao SP Krishnaiah L Rao KS Naidu GR Chiranjeevi P 《Environmental monitoring and assessment》2004,98(1-3):191-199
A new simple, rapid selective and highly sensitive chromogenic reagent dibromo-p-methyl-carboxyazo (DBMCA) was synthesized and studied in detail for the spectrophotometric detection of lead. In 0.25 M phosphoric acid medium, which greatly increases the selectivity, Lead reacts with DBMCA to form a 1:2 blue complex having a sensitivity absorption peak at 646 nm. Under optimal conditions, Beer's Law is obeyed over the range from 0.09 to 0.8 microg mL(-1) Pb (II) and the apparent molar absorptivity is 1.03 x 10(5) mL(-1) cm(-1). The detection limit and the variation coefficient were found to be 2.12 microg mL(-1) and 1.0% respectively. It is found that, except for Ca (II) and Ba (II) all foreign ions studied do not interfere with detection. The interference caused by Ca (II) and Ba (II) can be easily eliminated by prior extraction with potassiumiodide-methylisobutylketone. The proposed method has been applied successfully for to the detection of Lead in vegetable leaves with good results. 相似文献
144.
Murtaza G Haynes RJ Kim KR Zia MH Naidu R Belyaeva ON 《Environmental science and pollution research international》2012,19(3):636-645
Purpose
The study examines if a short period of reaction after addition of biosolids to soils can reduce the solubility and potential phytotoxicity of biosolid-borne Zn and Cu. 相似文献145.
Nasreen Islam Khan David Bruce Ravi Naidu Gary Owens 《Environmental geochemistry and health》2009,31(Z1):221-238
Dietary intake of water and food has been identified as one of the major pathways for arsenic (As) exposure in the rural population
of Bangladesh. Therefore, realistic assessment and measurement of dietary intake patterns are important for the development
of an accurate estimate of As exposure and human health risk assessment. One important consideration is to identify an appropriate
tool for measuring dietary intake. In this study an interviewer-administered Food Frequency Questionnaire (FFQ) was implemented
to determine age and gender specific dietary intake. The developed FFQ was unique because it developed a synergy between field
dietary assessment and As concentration measurements in various environmental media. The resulting integrated database provided
an accurate framework for the process of As exposure and human health risk assessment. The preliminary results reported here
from the FFQ demonstrated that this technique could be used in rural areas as a tool to assess As exposure and the associated
human health risk. 相似文献
146.
147.
Kauser Jahan Raúl Ordóñez Ravi Ramachandran Shira Balzer Michael Stern 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):395-404
Nonylphenol is the primary breakdown product of nonylphenol ethoxylates, a certain class of nonionic surfactants. Nonylphenol
has been found to be toxic to aquatic organisms and has been suspected of being harmful to humans due to its xenoestrogenic
properties. Although there are known releases of nonylphenol to the environment, there is a lack of data describing the extent
of biodegradation. This study thus focuses on much needed information on the biodegradation kinetics of nonylphenol. Oxygen
uptake, cell growth and nonylphenol removal data were collected using batch reactors in an electrolytic respirometer. Nonylphenol
removal, cell growth and substrate removal rates were modeled by the Monod, Haldane, Aiba, Webb, and Yano equations. The differential
equations were solved by numerical integration to simulate cell growth, substrate removal, and oxygen uptake as a function
of time. All models provided similar results with the Haldane model providing the best fit. The values of the kinetic parameters
and the activation energy for nonylphenol were determined. These values can be used for predicting fate and transport of nonylphenol
in the environment. The validity of applying each model to the biodegradation of nonylphenol was analyzed by computing the
R
2 values of each equation. 相似文献
148.
Ajay Kumar Sabyasachi Rout R. K. Singhal P. M. Ravi R. M. Tripathi 《Journal of Coastal Conservation》2016,20(4):289-297
Bio-diffusion mixing rates (Db) were estimated from depth profiles of excess 210Pb and 137Cs in three sediment cores collected from Mumbai Harbour Bay (MHB) using a steady state vertical advection - diffusion model. The mean of 210Pb and 137Cs derived Db values along the studied area were obtained to be about 23 and 36 cm2y?1 respectively. These derived values were within the range of literature values reported for other equivalent environment internationally. The relatively higher Db values for 137Cs profiles demonstrated that particles have diffused more intensely within the surface layer of sediments over 1 year. Conversely, low Db values for 210Pb indicate slow mixing rates in the sediment profile which might be resulted from low 210Pb flux and diffusion of 222Rn to the seafloor. The significant differences between 210Pb and 137Cs derived Db values among cores indicate that there appeared to be as regional differences in sediment properties and local variability in the intensity of seafloor mixing. Furthermore, Db values also depend on differences in characteristic time and depth scales of radionuclides in cores, benthic fauna abundances, organic carbon flux to the sediments and primary production in overlying surface waters. Comparison of 210Pb derived Db values with those calculated from 137Cs distributions reveals better agreement for core 2 than core 1 and 3. The agreement may be fortuitous because 137Cs appears significantly deeper than 210Pb in all cores. It was also observed that Db values increases as sediment accumulation rate increases for both radionuclide. 相似文献
149.
为探究湛江近海域海洋沉积物中类二噁英多氯联苯(dioxin-like polychlorinated biphenyls,Dl PCBs)的生物学毒性效应,选取湛江近海域2个地点(近工业区TS和近生活区JSW)采集沉积物样品,制备近海域沉积物Dl PCBs提取物,将斑马鱼胚胎暴露于不同浓度的Dl PCBs提取物,测定斑马鱼胚胎7-乙氧基异吩恶唑脱乙基酶(ethoxyresorufin-O-deethylase,EROD)活性和cyp1a m RNA相对表达量。结果发现,JSW采样点Dl PCBs提取物染毒组EROD酶活性变化与TS采样点Dl PCBs提取物一致,在各染毒浓度下,斑马鱼仔鱼EROD酶活性为对照组的1.1~1.8倍。TS和JSW采样点不同浓度Dl PCBs提取物暴露斑马鱼胚胎96 h后,使斑马鱼仔鱼cyp1a m RNA相对表达量是对照组的3.36~19.45倍。说明一定浓度的近海沉积物Dl PCBs能诱导斑马鱼仔鱼EROD酶活性和cyp1a m RNA表达量升高,且呈现浓度-效应关系。 相似文献
150.
The present study was undertaken to evaluate biochemical markers of chronic carbofuran exposure to rats in terms of lipid peroxide and intrasynaptosomal calcium levels and to correlate them with the histopathological changes in brain regions. A significant increase in lipid peroxidation (LPO) in terms of thiobarbituric acid reactive substances (TBARS) was observed in the cerebral cortex (65%) and brain stem (33%) after carbofuran exposure. This was accompanied by a significant increase (87%) in the intracellular free-Ca2+ [Ca2+]i levels. N-acetylcysteine (NAC) administration, on the other hand, reversed the carbofuran-induced increase in LPO and [Ca2+]i. Histopathological studies of carbofuran-exposed brain revealed high frequency of pyknotic neurons in the cerebral cortex and microhaemorrhages in the brain stem. NAC supplementation to carbofuran-treated animals resulted in normalisation of the brain architecture as seen by a reduction in the number of pyknotic nuclei in the cerebral cortex. These findings indicate that increased LPO and elevated [Ca2+]i levels are involved in the development of carbofuran neurotoxicity and are eventually responsible for the pathological alterations. The study also demonstrates potential neuroprotective effect of NAC treatment in carbofuran neurotoxicity. 相似文献