Life-cycle greenhouse gas emissions and economic analysis of alternative treatments of solid waste from city markets in Vietnam

We utilize life cycle assessment to trace conversion of degradable organic carbon (DOC) contained in organic waste from city markets in Da Nang, Vietnam. Our methodology makes explicit the process of conversion of DOC under aerobic and anaerobic conditions, as well as the balance of nutrients. Greenhouse gas emissions were calculated for six alternative scenarios: (i) anaerobic landfilling (current situation); (ii) semi-aerobic landfilling; (iii) landfill gas capture; (iv) composting; (v) pre-composting before landfill; and (vi) biogas production. We calculate that 1 t of waste in anaerobic landfilling emits 1.70 t CO₂-eq. with life-cycle perspective. Lowest emission occurs in biogas scenario with 0.26 t CO₂-eq./t. Composting occupies an intermediate position with 0.39 t CO₂-eq./t. Likewise, we estimate that cost of emission reduction in solid waste sector of Vietnam is 15.13 US$/t CO₂-eq., given by alternative of composting and taking anaerobic landfilling as reference. On the other hand, if social cost of carbon (SCC) is incorporated lowest cost to treat 1 t of waste is given by composting and semi-aerobic landfilling at discount rate of 5 %. However, using lower discount rates, and consequently higher values of SCC, composting and biogas production become the alternatives with lowest treatment costs.     

Biomarkers and bioindicators of the health condition of Ameca splendens and Goodea atripinnis (Pisces: Goodeaidae) in the Ameca River, Mexico

Pollution of water bodies causes stress on organisms inhabiting them. Determination of biomarkers and bioindicators on fish populations reflects whether they are subject to stress. We assessed two populations of Ameca splendens and Goodea atripinnis in a reference site (spring "El Rincon") and De La Vega reservoir, which receives wastewater of a sugar industry, on Ameca River course. We analyzed level of lipid peroxidation and enzymatic activities of gamma-glutamyl-transpeptidase, acetylcholinesterase and ethoxyresorufin-O-deethylase as biomarkers; we also studied age classes and various body indexes. Environmental factors were recorded and a water quality index was assessed. Water quality was better in the spring than in the reservoir. Organisms inhabiting the reservoir presented higher oxidative stress by the lipid peroxidation levels, and neurotoxic impacts by the acetylcholinesterase and some detoxification mechanisms were evident by the gamma-glutamyl-transpeptidase and ethoxyresorufin-O-deethylase activities. Integrated Biomarker Response demonstrate that De La Vega reservoir is a more stressing place to organisms living there, particularly for A. splendens. In both species, males were more affected than females. Condition and reproductive parameters in reservoir showed evidences of physiological changes due to xenobiotics exposure and suggest a tactic of the organisms to survive in this site. Both biomarkers and body indexes revealed that A. splendens is a more sensitive species than G. atripinnis to environmental stress.     

A One Year Study on the Concentrations of Norovirus and Enteric Adenoviruses in Wastewater and A Surface Drinking Water Source in Norway

Enteric viruses transmitted via the faecal-oral route occur in high concentrations in wastewater and may contaminate drinking water sources and cause disease. In order to quantify enteric adenovirus and norovirus genotypes I and II (GI and GII) impacting a drinking source in Norway, samples of surface water (52), wastewater inlet (64) and outlet (59) were collected between January 2011 and April 2012. Samples were concentrated in two steps, using an electropositive disc filter and polyethylene glycol precipitation, followed by nucleic acid extraction and analysis by quantitative polymerase chain reaction. Virus was detected in 47/52 (90.4 %) of surface water, 59/64 (92 %) of wastewater inlet and 55/59 (93 %) of wastewater outlet samples. Norovirus GI occurred in the highest concentrations in surface water (2.51e + 04) and adenovirus in wastewater (2.15e + 07). While adenovirus was the most frequently detected in all matrices, norovirus GI was more frequently detected in surface water and norovirus GII in wastewater. This study is the first in Norway to monitor both sewage and a drinking water source in parallel, and confirms the year-round presence of norovirus and adenovirus in a Norwegian drinking water source.     

Sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of the Biobio River in south central Chile

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in the environment; there are concerns about them due to their toxic properties. Human activities could significantly contribute to the total PAH burden in river sediments. In this work, we document the analysis of PAHs in sediments taken in the middle stretch of the Biobio River in south central Chile. This river is a principal system, draining more than 24,000 km² and subjected to a diverse variety of human-made stressors (pulp mill and urban effluents, agricultural drainage systems, etc). During 2003, several sediment samples were taken in more than 45 sampling sites located in the river’s middle stretch. Due to the granulometric characteristics (mainly sandy sediments), only 17 samples were analyzed, taking into consideration the presence of a fine section within the sediment sample. Using HPLC with fluorescence detection, 15 EPA priority PAHs and perylene were analyzed. The composition of PAHs in the sediment samples is rather similar between sites and levels averaged 104 ± 78 ng g⁻¹ d.w. The highest levels were detected downstream from an industrial discharge. A good correlation was observed between PAH levels and organic carbon content in the tested sediments; however, concentrations above 134 ng g⁻¹ d.w. did not indicate correlation. The samples PAH ratios (Flu/Pyr and Chr/B(a)A) reveal a strong pyrolytic PAH pattern in the sediments tested, supporting evidence indicating that PAHs come mainly from pyrolytic sources. This result contrasts with previous records that have shown a natural influence in the upper basin and a petrogenic pattern near the mouth.     

Analyzing SO 2 concentrations and wind directions during a short monitoring campaign at a site far from the industrial pole of La Plata, Argentina

This article presents and discusses SO2 air quality concentrations (ppbv) together with wind velocities and directions measurements carried out between September 1st and December 21st 2005 at a site located 8.5 km away from the Industrial Pole of La Plata area. As the city and its surroundings have no official monitoring network, the current work enlarges the air quality information available from the zone and sets some initial considerations to the future siting of monitoring stations. The statistical analysis of the data was performed using techniques of tests for outliers and trends, dissimilarity measures and robust regression. In relation to SO2 concentrations, low values were found during this short campaign considering daily averages (with a maximum of 8.5 ppbv) and hourly averages (with a maximum of 25.9 ppbv); World Health Organization guidelines were never surpassed. Nevertheless, a strong dependence between wind directions carrying air pollutants from the Industrial Pole and hourly concentration peaks were found. Due to low monthly SO2 concentrations and because a decreasing time trend was found, the authors propose, as an example, the implementation of an alternative discontinuous method to the continuous analyzer used in the current campaign. Our results state that sampling every 7 days at 13:00-13:59 hours (local time) would be enough to get representative values of the air quality. As a general remark it is possible to highlight that longer and systematic studies should be encouraged to confirm the seasonal wind pattern and to evaluate the air quality.     

Cytogenetic biomonitoring of oral mucosa cells of crack cocaine users

The aim of the present study was to comparatively evaluate genomic damage (micronucleus) and cellular death (pyknosis, karyolysis, and karyorrhexis) in exfoliated oral mucosa cells from crack cocaine users by micronucleus test. A total of 30 crack cocaine users and 30 health controls (non-exposed individuals) were included in this setting. Individuals had epithelial cells from cheek mechanically exfoliated, placed in fixative, and dropped in clean slides, which were checked for the above nuclear phenotypes. The results pointed out significant statistical differences (p?<?0.05) of micronucleated oral mucosa cells from crack cocaine users. Exposure to crack cocaine caused an increase of other nuclear alterations closely related to cytotoxicity such as karyolysis in oral cells as well. In summary, these data indicate that crack cocaine is able to induce chromosomal breakage and cellular death in oral mucosa cells of users.     

Experimental testing of an annular denuder and filter system to measure gas–particle partitioning of semivolatile bifunctional carbonyls in the atmosphere

An annular denuder and filter-pack system was tested in combination with the use of the in-tube and on-fiber O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA)-derivatization technique to simultaneously sample and measure gaseous and particulate concentrations of semivolatile bifunctional carbonyl compounds in the atmosphere. Ozone was denuded from the sampling air to avoid oxidation and PFBHA was used as the sorbent by coating the sampling denuders and impregnating the filters. The collection efficiency of the system was evaluated under different conditions in photochemical smog chamber experiments and in field samplings of urban and suburban atmospheres. The effects of concentration level, temperature, and humidity on the collection efficiency were assessed. The system showed average collection efficiencies in one denuder from 81% for pyruvic acid and 82% for glyoxylic acid to 87% for hydroxyacetone and dihydroxyacetone. The capacity of the filters to collect the gaseous fraction that cannot be collected in the denuders was also evaluated, and the system allows a correction for this artifact. The application of this method to chamber experiments and field samplings offers an easy-to-apply technique with good results that can be used to evaluate the partition mechanisms of these compounds in the atmosphere.     

Development of the concept of spatial–temporal mask for testing effects of discharge from well-drilling activities on biological communities

This paper describes the use of Bayesian spatial models to develop the concept of a spatial–temporal mask for the purpose of identifying regions in which before and after drilling effects are most clearly defined and from which the consequences of exposure of macrofauna and meiofauna to the release of drilling discharges can be evaluated over time. To determine the effects of drilling fluids and drill-cuttings on the marine benthic community, it is essential to know not only where discharged materials ended up within the possible impact area, but also the chemical concentrations to which biota were exposed during and after drilling. Barium and light hydrocarbons were used as chemical tracers for water-based and non-aqueous-based fluids in a shallow water site in the Campos Basin, off the coast of Brazil. Since the site showed evidence of exposure to waste material from earlier drilling, the analysis needed to take into account the background concentrations of these compounds. Using the Bayesian models, concentrations at unsampled sites were predicted and regions altered and previously contaminated were identified.