Measures of ozone concentrations using passive sampling in forests of South Western Europe

Ambient ozone concentrations were measured with passive samplers in the framework of the EU and UN/ECE Level II forest monitoring programme. Data from France, Italy, Luxembourg, Spain and Switzerland are reported for 2000-2002, covering the period from April to September. The number of plots increased from 67 in 2000 to 83 in 2002. The year 2001 experienced the highest ozone concentrations, reflecting more stable summer meteorological conditions. Average 6-month ozone concentrations above 45 ppb were measured this year in 40.3% of the plots, in contrast with the less than 21% measured in the other 2 years. Gradients of increasing ozone levels were observed from North to South and with altitude. Comments are made on the regional trends and on the time frame of the higher ozone episodes. Also, some recommendations enabling a better comparison between plots are provided.     

The development and application of remote sensing to monitor sand dune habitats

Sand dunes are complex systems that contain several habitats, often as mosaics or transitions between types. Several of these habitats are afforded protection under European Legislation and in the UK nationally within Special Areas of Conservation (SAC) and Sites of Special Scientific Interest (SSSI). Natural England has a statutory duty to report to Europe on the conservation status and condition of sand dunes; and is required to report to the UK Government on designated sites. To achieve this we have sought ways of capturing, analysing and interpreting data on the extent and location of sand dune habitats. This requires an ability to be able to obtain data over large areas of coastline in an efficient way. Natural England and Environment Agency Geomatics have worked collaboratively for over 16 years, sharing data and ecological knowledge. In 2012 work started to evaluate the use of remote sensing to map UK BAP and Annex I sand dune habitats. A methodology has now been developed and tested to map sand dune habitats. The key objective was to provide an operational tool that will help to map these habitats and understand change on sites around England. This has been achieved through analysis of LIDAR and Compact Airborne Spectrographic Imager (CASI) data using Object Orientated Image Analysis. Quality Control (QC) and accuracy assessments have shown this approach to be successful and 11 sites have been mapped to date. These techniques are providing a new approach to monitoring change in coastal vegetation communities and informing management of protected sites.     

Measurement of machinery safety level in the European market: A real case based on market surveillance data

This article aims to highlight the current status of compliance to Machinery Directive 98/37/EC (transposed to Spanish regulation as RD 56/1995, of 20th January) (a new directive numbered as 2006/42/EC [Directive 2006/42/EC of the European Parliament and of the Council of 17 may 2006 on machinery, and amending Directive 95/16/EC (recast). OJ L157/24-86, 9.6.2006.], that recasts and replaced 98/37/ED directive and its amendments, came into force on 29 June 2006; it will not be applied until 29th December 2009. European Member States have a lead-time of two years to adopt and publish the national laws and regulations transposing the provisions of the new Directive into national law. Latest 10th October, Spain transposed Machinery Directive 2006/42/EC to national regulation as Real Decreto 1644/2008 [Real Decreto 1644/2008, de 10 de octubre, por el que se establecen las normas para la comercialización y puesta en servicio de las máquinas. BOE 246/2008, de 11 octubre 2008. Páginas 40995–41030]) of a particular family of machinery (hand-held, medium and small-size, deeply introduced in the market, of low-medium cost), that any user, professional or non-professional, can acquire as first-hand in any of the sales points (whether or not experts in these kind of products).At the same time, it emphasises the most significant shortcomings and non-conformities found, after analyzing the results of five consecutive Campaigns of Control of Industrial Products performed by one of the labs (placed in Spain) involved in the market surveillance European Program.     

Microwave and Fenton's reagent oxidation of wastewater

We compared two H₂O₂ oxidation methods for the treatment of industrial wastewater: oxidation using Fenton's reagent [H₂O₂/Fe(II)] and microwave irradiation. Both methods were applied to the treatment of synthetic phenol solutions (100 mg L⁻¹) and of an industrial effluent containing a mixture of ionic and non-ionic surfactants at high load (20 g L⁻¹ of COD). The effects of initial pH, initial H₂O₂ concentration, Fenton catalyst amount and irradiation time were assessed. According to the oxidation of phenol, it has been found that the oxidation by Fenton's reagent is dependent on the pH, contrary to the microwave system, which is not influenced by this parameter. For both systems, a limiting amount of oxidant has been found; above this point the oxidation of phenol is not improved by a further addition of peroxide. The oxidation of the industrial surfactant effluent has only been successful with the Fenton's reagent. In this case, large amounts of ferrous ions are necessary for the precipitation of the ionic surfactants of the effluent, followed by the oxidation of the non-ionic constituents of the solution. Electronic Publication     

Response of native plants of northeastern United States and southern Spain to ozone exposures; determining exposure/response relationships

Tropospheric ozone has been identified as the most important regional scale air pollutant across much of eastern United States of America and many areas of Mediterranean climes in southern Europe. Recent field surveys in the northeastern USA and in southeastern Spain have revealed many additional plant species that exhibit symptoms typical of ozone-induced injuries. Objectives of this study were to confirm ozone as the cause of the observed foliar symptoms, determine ozone induced exposure/response relationships, and identify possible bio-indicator species. Thirteen native species of northeastern USA and 27 native species of southeastern Spain were selected for study. Plant species were exposed to ozone within 16 CSTR chambers in a greenhouse during the summer seasons of 2000 and 2001; ozone exposures of 30, 60, 90, and 120 ppb were delivered for 7 h/day, 5 days/week. Results have confirmed that with few exceptions, symptoms observed in the field were induced by exposures to ambient ozone. Species differed significantly in terms of the exposures required for the initiation of visible symptoms and subsequent injury progression.     

Spatial pattern of ozone injury in Aleppo pine related to air pollution dynamics in a coastal-mountain region of eastern Spain

In eastern Spain, studies combining the tracking and meso-scale circulations of air pollutants with the evaluation of their effects on plants have been undertaken since 1994. Meso-scale processes are very important from the point of view of how and where forest ecosystems are affected by point sources and regional air pollution in the Mediterranean area. The first results of these field surveys show that in 1994, 1995 and 1996, the distribution pattern of ozone visual injury (chlorotic mottle) in Pinus halepensis correlated with the penetration of pollutants transported by the sea-breeze into coastal valleys of Castellón (eastern Spain). In this tree species, longer needles are associated with higher chlorotic mottle, and ozone injury seems to be among the factors affecting needle retention and crown transparency.