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31.
A sensitive spectrophotometric method has been developed for determination of ametryn in agricultural samples. The proposed
method was based on reaction with pyridine and further coupling with sulfanilic acid to form a colored product. The absorbance
was measured at 400 nm with a molar absorptivity of 2.1 × 105 L mol−1 cm−1. The method shows a linear range from 0.2–20 μg mL−1 with limit of detection and limit of quantification 0.16 and 0.54 μg mL−1, respectively. The method has been successfully applied to the determination of ametryn in sugarcane juice and commercial
formulations after separation of ametryn from triazine herbicides based on solvent extraction. Recovery values were found
to be in the range of 96.0 ± 0.2% to 98.4 ± 0.1%. 相似文献
32.
de Araújo MC Chaves AP Espinosa DC Tenório JA 《Waste management (New York, N.Y.)》2008,28(11):2177-2182
Every year, the number of discarded electro-electronic products is increasing. For this reason recycling is needed, to avoid wasting non-renewable natural resources. The objective of this work is to study the recycling of materials from parallel wire cable through unit operations of mineral processing. Parallel wire cables are basically composed of polymer and copper. The following unit operations were tested: grinding, size classification, dense medium separation, electrostatic separation, scrubbing, panning, and elutriation. It was observed that the operations used obtained copper and PVC concentrates with a low degree of cross contamination. It was concluded that total liberation of the materials was accomplished after grinding to less than 3 mm, using a cage mill. Separation using panning and elutriation presented the best results in terms of recovery and cross contamination. 相似文献
33.
Photocatalytic degradation of formaldehyde containing wastewater from veterinarian laboratories 总被引:1,自引:0,他引:1
Araña J Martínez Nieto JL Herrera Melián JA Doña Rodríguez JM González Díaz O Pérez Peña J Bergasa O Alvarez C Méndez J 《Chemosphere》2004,55(6):893-904
The photocatalytic destruction of methanol, formaline (mixture of formaldehyde, methanol and water) and formaline wastes from the preservation of vertinarian physiologic samples has been attempted by two different processes, at high concentrations of reagents and by dossification of reagents, varying pH in both. Experiment evolution has been monitored by measuring the organic matter such as TOC and formaldehyde concentrations [H2CO]. Also, methanol and methanol-formaldehyde interactions with the TiO2 surface have been analysed by FTIR spectroscopy. Results indicate that at high concentrations the catalyst surfacial alterations given by methoxy, formates or carbonates, according to the pH of the sample can profoundly affect catalyst behaviour. It has been established that reagent dossification is advantageous for enhancing photonic efficiency as it minimizes the adsorbate presence that hampers the photocatalytic process. 相似文献
34.
Shanaz Jahan Yatimah Binti Alias Ahmad Farid Bin Abu Bakar Ismail Bin Yusoff 《环境科学学报(英文版)》2018,30(10):140-152
The toxicity and kinetic uptake potential of zinc oxide(Zn O) and titanium dioxide(TiO_2)nanomaterials into the red bean(Vigna angularis) plant were investigated. The results obtained revealed that Zn O, due to its high dissolution and strong binding capacity, readily accumulated in the root tissues and significantly inhibited the physiological activity of the plant. However, TiO_2 had a positive effect on plant physiology, resulting in promoted growth. The results of biochemical experiments implied that Zn O, through the generation of oxidative stress, significantly reduced the chlorophyll content, carotenoids and activity of stress-controlling enzymes. On the contrary, no negative biochemical impact was observed in plants treated with TiO_2. For the kinetic uptake and transport study, we designed two exposure systems in which Zn O and TiO_2 were exposed to red bean seedlings individually or in a mixture approach. The results showed that in single metal oxide treatments, the uptake and transport increased with increasing exposure period from one week to three weeks.However, in the metal oxide co-exposure treatment, due to complexation and competition among the particles, the uptake and transport were remarkably decreased. This suggested that the kinetic transport pattern of the metal oxide mixtures varied compared to those of its individual constituents. 相似文献
35.
Jayara D.C. Silva Tamara T.B. Leal Ademir S.F. Araújo Raul M. Araujo Regina L.F. Gomes Wanderley J. Melo Rajeev P. Singh 《Waste management (New York, N.Y.)》2010,30(10):1976-1980
Composting has been recognized as one of the most cost effective and environmentally sound alternatives for organic wastes recycling from long and composted wastes have a potential to substitute inorganic fertilizers. We investigated the potential of composted tannery sludge for ornamental purposes and to examine the effects of two different composts and concentrations on ornamental Capsicum growth. The two composts were produced with tannery sludge and the composition of each compost was: compost1 of tannery sludge (C1TS) – tannery sludge + sugarcane straw and cattle manure mixed in the ratio 1:3:1 (v:v:v); compost2 of tannery sludge (C2TS) – tannery sludge + “carnauba” straw and cattle manure in the ratio 1:3:1 (v:v:v). Each compost was amended with soil at rates (% v:v) of 0%, 25%, 50%, 75% and 100% (designation hereafter as T1–T5, respectively). The number of leaves and fruits were counted, and the stem length was also measured. Chlorophyll content was recorded on three leaves of each harvested plant prior to harvest. Number of leaves and fruits, stem length, dry weight of shoot and roots did not vary significantly between the plants grown in two tannery composts. All the treatments with composted tannery sludge application (T2–T5) significantly increased the number of leaves and fruits, stem length and chlorophyll content compared with the control (T1). The chlorophyll content was higher in plants growing in the C1TS compared to C2TS. The results of the present study further suggest that Capsicum may be a good option to be grown on composted tannery amended soil. 相似文献
36.
37.
Jasmin Shah M. Rasul Jan Farhat-un-nisa Shehzad Behisht Ara 《Environmental Chemistry Letters》2010,8(3):253-259
A simple spectrophotometric method was developed for determination of trifluralin in commercial formulation and food samples.
The method was based on the hydrolysis of trifluralin with sodium hydroxide to form 2,6-dinitro-4-trifluoromethylaniline.
The resultant aniline group was diazotized with nitrate in acidic media and the diazotized product was coupled with β-naphthol
to form red colored product having λmax 550 nm. The reaction conditions were optimized for hydrolysis as well as for the diazotization reaction. The Beer’s law was obeyed over the range of 0.2–17 μg mL−1 with molar absorptivity of 1.5 × 104 L mol−1 cm−1. The relative standard deviation was found to be 3.6%. A two level factorial design of 23 was used for optimization of all parameters. The influence of different factors and their interactions on the final azo dye
formation were also studied from these factorial designs. The method has been applied successfully for the analysis of commercial
formulations and agricultural samples. The recovery for the determination of trifluralin was found to be in the range 95–97%. 相似文献
38.
Tolerance to iron accumulation and its effects on mineral composition and growth of two grass species 总被引:1,自引:0,他引:1
Talita Oliveira de Araújo Larisse de Freitas-Silva Brenda Vila Nova Santana Kacilda Naomi Kuki Eduardo Gusmão Pereira Aristéa Alves Azevedo Luzimar Campos da Silva 《Environmental science and pollution research international》2014,21(4):2777-2784
This study aimed to assess the influence of excess iron on the capacity of accumulation of this heavy metal, mineral composition, and growth of Setaria parviflora and Paspalum urvillei. Seedlings were submitted to 0.009; 1; 2; 4; and 7 mM of Fe-EDTA. In both species there was an increase in the concentration of Fe, Zn, P, and Ca and a decrease in Mn, K, and Mg in the iron plaque. Both species accumulated more iron in roots. In the shoots, S. parviflora showed higher iron content, except at 7 mM. Iron altered the contents of Fe, Cu, K, and Mg in roots, and of Fe, Mn, Zn, N, P, K, Ca, and Mg in shoots. The two species tolerated high iron concentrations and accumulated high content of this element in both shoots and roots. The iron did not reduce their growth. Both species are indicated for studies aiming restoration of iron-contaminated areas. 相似文献
39.
Shubo Tatsuo Maranhão Adriana Ferreira Fernando César Fumian Tulio Machado Pimenta Márcia Maria Araújo do Rosário Vaz Morgado Cláudia Toze Simon Ahmed Warish Sidhu Jatinder Miagostovich Marize Pereira 《Food and environmental virology》2021,13(3):412-420
Food and Environmental Virology - Roof-harvested rainwater (RHRW) is considered relatively clean water, even though the possible presence of pathogens in the water may pose human health risks. In... 相似文献
40.
Coastal hazards and community-coping methods in Bangladesh 总被引:1,自引:0,他引:1
Addressing one of the most vulnerable coastal communities in Bangladesh, this paper explores people’s perception and vulnerabilities
to coastal hazards. At the same time, it investigates the methods that communities apply to cope with different coastal hazards.
Findings revealed that people perceived an increase in both the intensity of hazards and their vulnerabilities. In spite of
having a number of socio-economic and locational factors enhancing their vulnerabilities, the community is creating their
own ways to cope with these hazards. For different aspects of life like shelter, employment, water supply, and health, communities
apply different coping methods that vary with the types of hazard. Efforts have also been made by governments and NGOs to
manage coastal hazards. By highlighting both community-coping methods and efforts of development organizations, this paper
attempts to devise an integrated approach for managing the coastal hazards that occur in Bangladesh. 相似文献