Nitrate, ammonium and dissolved organic nitrogen (DON) concentrations were measured in the lower reaches of the River Test in Hampshire to assess the impact of two effluent point sources. An 18-month survey from July 2001 to December 2002 was carried out at locations above and below fish farm inputs and a sewage effluent outfall. The concentration of nitrate exceeded 400 M at the four sites on all sample dates. A consistent increase in ammonium concentration was measured downstream of the fish farm, but not the sewage effluent input. DON samples collected downstream of the fish farm did not show a consistent increase in concentration, compared with the upstream sampling location, whereas the sewage effluent input at Romsey was a point source of DON to the River Test with a mean increase of 15 M. Nitrate was the major component of dissolved nitrogen in this aquifer-fed chalk-bed river system, with up to 10% being DON and ammonium comprising <1%. 相似文献
A review is presented detailing the development of ion chromatography (IC) as a selective analytical tool for the determination of toxic metals and their organic species in many environmental sample matrices. A brief outline of ion chromatographic principles, together with an overview of the stationary phases used to separate metals, namely ion exchangers, modified ion pair sorbents and chelating ion exchangers, and the methods for detecting metal ions including hyphenation with spectroscopy and sample preparation schemes are also given, prior to a critical examination of developed methods for various metals including arsenic, chromium, cadmium, lead, mercury, beryllium, aluminium and uranium since 1990. 相似文献
ABSTRACT: For many years, a commonly used strategy for source water protection in Taiwan has been setting up arbitrary, fixed‐width buffer zones near sensitive waters, such as water‐supply reservoirs, and prohibiting any development in their watersheds. However, such regulations are now often viewed as infringing by the government on landowners' property rights, a situation that has led to citizen protests. This paper describes a proposed strategy that is water‐quality based and uses a quantitative zoning approach. A reservoir's watershed is divided into several zones beginning from the normal water line to the divide. Different levels of best management practices (BMPs) are required for controlling runoff pollution in different zones. The layout of the management zones is based on a number of factors such as reservoir classification, water quality conditions, and physical characteristics of the watershed. The goal of promoting such an approach is to try to balance the needs of watershed development and water quality protection. A case study using the Tapu Reservoir Watershed in Northern Taiwan as an example for illustrating the proposed zoning approach is presented. 相似文献
A dry deposition model (RDM) for operational application has beenevaluated and modified in the present study. Field measurements of friction velocity and dry deposition velocity of SO2 andO3 over a mixed forest have been used to evaluate RDM. It was found that RDM predicts friction velocities very close to measurements and thus it can predict reasonable aerodynamic resistance. RDM overestimated O3 deposition during dry nighttime conditions and underestimated both O3 andSO2deposition for early morning hours. It could not predict the mean diurnal variation in deposition velocity for either O3 or SO2 deposition under wet surface conditions. Modifications have been made for O3 and SO2 dry deposition based on the comparison of results and based upon additional published data. Compared to an earlier version of RDM, the modified versionpredicts better results for O3 and SO2 dry deposition,especially under rain and dew conditions. 相似文献
In a wide variety of species, male reproductive success is determined by contest for access to females. Among multi-male primate
groups, however, factors in addition to male competitive ability may also influence paternity outcome, although their exact
nature and force is still largely unclear. Here, we have investigated in a group of free-ranging Barbary macaques whether
paternity is determined on the pre- or postcopulatory level and how male competitive ability and female direct mate choice
during the female fertile phase are related to male reproductive success. Behavioural observations were combined with faecal
hormone analysis for timing of the fertile phase (13 cycles, 8 females) and genetic paternity analysis (n = 12). During the fertile phase, complete monopolisation of females did not occur. Females were consorted for only 49% of
observation time, and all females had ejaculatory copulations with several males. Thus, in all cases, paternity was determined
on the postcopulatory level. More than 80% of infants were sired by high-ranking males, and this reproductive skew was related
to both, male competitive ability and female direct mate choice as high-ranking males spent more time in consort with females
than low-ranking males, and females solicited copulations mainly from dominant males. As most ejaculatory copulations were
female-initiated, female direct mate choice appeared to have the highest impact on male reproductive success. However, female
preference was not directly translated into paternity, as fathers were not preferred over non-fathers in terms of solicitation,
consortship and mating behaviour. Collectively, our data show that in the Barbary macaque, both sexes significantly influence
male mating success, but that sperm of several males generally compete within the female reproductive tract and that therefore
paternity is determined by mechanisms operating at the postcopulatory level. 相似文献
Addressing one of the most vulnerable coastal communities in Bangladesh, this paper explores people’s perception and vulnerabilities
to coastal hazards. At the same time, it investigates the methods that communities apply to cope with different coastal hazards.
Findings revealed that people perceived an increase in both the intensity of hazards and their vulnerabilities. In spite of
having a number of socio-economic and locational factors enhancing their vulnerabilities, the community is creating their
own ways to cope with these hazards. For different aspects of life like shelter, employment, water supply, and health, communities
apply different coping methods that vary with the types of hazard. Efforts have also been made by governments and NGOs to
manage coastal hazards. By highlighting both community-coping methods and efforts of development organizations, this paper
attempts to devise an integrated approach for managing the coastal hazards that occur in Bangladesh. 相似文献
One of the key challenges in the total maximum daily load (TMDL) development process is how to define the critical condition for a receiving waterbody. The main concern in using a continuous simulation approach is the absence of any guarantee that the most critical condition will be captured during the selected representative hydrologic period, given the scarcity of long-term continuous data. The objectives of this paper are to clearly address the critical condition in the TMDL development process and to compare continuous and event-based approaches in defining critical condition during TMDL development for a waterbody impacted by both point and nonpoint source pollution. A practical, event-based critical flow-storm (CFS) approach was developed to explicitly addresses the critical condition as a combination of a low stream flow and a storm event of a selected magnitude, both having certain frequencies of occurrence. This paper illustrated the CFS concept and provided its theoretical basis using a derived analytical conceptual model. The CFS approach clearly defined a critical condition, obtained reasonable results and could be considered as an alternative method in TMDL development. 相似文献
Lignocellulosic biomass offers the most abundant renewable resource in replacing traditional fossil resources. However, it is still a major challenge to directly convert the lignin component into value-added materials. The availability of plentiful hydroxyl groups in lignin macromolecules and its unique three-dimensional structure make it an ideal precursor for mesoporous biosorbents. In this work, we reported an environmentally friendly and economically feasible method for the fabrication of mesoporous lignin-based biosorbent (MLBB) from lignocellulosic biomass through a SO3 micro-thermal-explosion process, as a byproduct of microcrystalline cellulose. BET analysis reveal the average pore-size distribution of 5.50 nm, the average pore value of 0.35 cm3/g, and the specific surface area of 186 m2/g. The physicochemical properties of MLBB were studied by fourier transform infrared spectroscopy (FTIR), attenuated-total-reflection fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and element analysis. These results showed that there are large amounts of sulfonic functional groups existing on the surface of this biosorbent. Pb(II) was used as a model heavy-metal-ion to demonstrate the technical feasibility for heavy-metal-ion removal. Considering that lignocellulosic biomass is a naturally abundant and renewable resource and SO3 micro-thermal-explosion is a proven technique, this biosorbent can be easily produced at large scale and become a sustainable and reliable resource for wastewater treatment. 相似文献