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121.
Stefano Salvestrini Silvana Canzano Pasquale Iovino Vincenzo Leone Sante Capasso 《Journal of environmental science and health. Part. B》2013,48(8):578-590
The sorption kinetics of simazine (6-chloro-N,N′-diethyl-1,3,5-triazine-2,4-diamine), imidacloprid (1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine), and boscalid (2-chloro-N-(4′-chlorobiphenyl-2-yl)nicotinamide), three pesticides of wide use in agriculture, was determined in five different water/soil systems over a time interval from the initial few seconds to about 1 month. In all the experiments, sorption kinetics showed a biphasic pattern characterized by an initial, relatively short phase with a high sorption rate and a later phase with much a lower sorption rate. Initial sorption capacity increased with soil organic carbon content and with sorbate hydrophobicity. We postulate that the first phase of the process involves a fast second-order sorption reaction on superficial sites of soil particles, whereas the second phase depends on diffusion-controlled migration to internal binding sites. A kinetic equation based on this hybrid model accurately fitted all data sets. Less satisfactory results were obtained employing the pseudo-first order, pseudo-second order, Elovich, two site non-equilibrium, or Weber-Morris equation. The superior performance of the hybrid model for describing boscalid sorption probably reflects the high hydrophobic character and consequent low diffusion rates of this compound. The accuracy of modelling was in any case strongly dependent on the time interval considered. 相似文献
122.
Adriano Sofo Antonio Scopa Stefano Dumontet Angelo Mazzatura Vincenzo Pasquale 《Journal of environmental science and health. Part. B》2013,48(7):653-659
The effect of four triazinyl-sulfonylurea herbicides (cinosulfuron, prosulfuron, thifensulfuron methyl, triasulfuron) on soil microbial biomass, soil respiration, metabolic activity, metabolic quotient, and some enzymatic activities (acid and alkaline phosphatase, β-glucosidase, arylsulphatase, and fluorescein diacetate hydrolysis) were monitored under controlled conditions over 30 days. The herbicides were applied at the normal field dose (FD) and at ten-fold (10 FD) the field dose, in order to mimic a long term toxic effect. The measured soil microbial parameters showed that the FD had slight effects on soil microflora, while at 10 FD the tested herbicides exerted a stronger detrimental effect on soil microbial biomass and its biochemical activities. 相似文献
123.
Cuoco Emilio Viaroli Stefano Paolucci Vittorio Mazza Roberto Tedesco Dario 《Environmental geochemistry and health》2022,44(7):2065-2082
Environmental Geochemistry and Health - A theoretical pattern for Fe and As co-precipitation was tested directly in a groundwater natural system. Several monitoring wells were sampled to identify... 相似文献
124.
Manzo Sonia Parrella Luisa Schiavo Simona Spaziani Fabio Chiavarini Salvatore Tebano Carlo De Maio Lucio Capone Stefano Siciliano Anna Valeria Armiento Giovanna 《Environmental science and pollution research international》2022,29(55):83291-83303
Environmental Science and Pollution Research - In this study we propose, a multi-step strategy of selection and characterization of long-term dataset of contaminant concentrations in different... 相似文献
125.
In this work we present the results of an experimental study on the abatement of polychlorinated biphenyl (PCBs) in contaminated soil using a high energy milling technique, that promotes a reaction only by impact between milling bodies. A sample of soil from a controlled landfill was treated with powdered NaBH(4) using two different hydride/soil ratios (5 and 2.5% w/w). The efficiency of the dehalogenation/hydrogenation reaction was studied as a function of the milling time (3.5 up to 30 h). After each run, the total PCBs content and the production of inorganic chloride were measured. The complete abatement was obtained with a starting PCBs concentration of about 2600 mg/kg. The residual PCBs concentration resulted to be <0.2 mg/kg. The final products of the treatment were biphenyl and NaCl. Other toxic or hazardous organic by-products were not generated. Boron was found as boric acid. 相似文献
126.
Iannotta N Noce ME Ripa V Scalercio S Vizzarri V 《Journal of environmental science and health. Part. B》2007,42(7):789-793
Within the framework of research concerning the application of techniques alternative to chemical pesticides for control of parasites, the C.R.A. Experimental Institute for Olive Growing for many years has been performing a large investigation in order to detect sources of genetic resistance in olive germplasm. In the present study we observed the behavior related to the olive fly (Bactrocera oleae) infestation and Camarosporium dalmaticum infection of ten olive cultivars farmed under the same agronomic and climatic conditions in Calabria, Southern Italy. The sampling and the data collecting were carried out in three different ripening times.The drupe amount of oleuropein and cyanidine was detected by laboratory analyses in order to verify a possible correlation between these molecules and the level of infestation/infection of the above-mentioned parasites. The obtained data were submitted to analysis of variance. In relation to the fungal infection the results displayed that cvs Tonda nera dolce showed the lowest susceptibility, while the cv Giarraffa turned out to be the most susceptible. The less susceptible cultivars to the phytophagous were Tonda nera dolce and Bhardi Tirana. Since the less susceptible cultivar to olive fly attacks are the same observed in relation to the susceptibility to olive fruit rot, it is suggested a relation between the olive fly infestation and the fungal infection. It suggests the utility to achieve these results both to transfer directly to the farmers' world and to emphasize ecosystem health and biodiversity conservation. 相似文献
127.
Environmental Security: A Geographic Information System Analysis Approach—The Case of Kenya 总被引:2,自引:0,他引:2
Studies into the relationships between environmental factors and violence or conflicts constitute a very debated research
field called environmental security. Several authors think that environmental scarcity, which is scarcity of renewable resources,
can contribute to generate violence or social unrest, particularly within states scarcely endowed with technical know-how
and social structures, such as developing countries. In this work, we referred to the theoretical model developed by the Environmental
Change and Acute Conflict Project. Our goal was to use easily available spatial databases to map the various sources of environmental
scarcity through geographic information systems, in order to locate the areas apparently most at risk of suffering negative
social effects and their consequences in terms of internal security. The analysis was carried out at a subnational level and
applied to the case of Kenya. A first phase of the work included a careful selection of databases relative to renewable resources.
Spatial operations among these data allowed us to obtain new information on the availability of renewable resources (cropland,
forests, water), on the present and foreseen demographic pressure, as well as on the social and technical ingenuity. The results
made it possible to identify areas suffering from scarcity of one or more renewable resources, indicating different levels
of gravity. Accounts from Kenya seem to confirm our results, reporting clashes between tribal groups over the access to scarce
resources in areas that our work showed to be at high risk. 相似文献
128.
The results of recent studies by our group have suggested that in social wasps of the genus Polistes the Dufour’s gland is involved in kin recognition. In fact, the same hydrocarbons occurring on the cuticle are found in the
gland secretion, and in P. dominulus the composition of the glandular secretion is more similar in foundresses belonging to the same colonies than in heterocolonial
foundresses. In this study, P. dominulus colonies were experimentally presented with previously treated dead conspecific females. These lures had been deprived of
their epicuticular lipids and coated with epicuticular or Dufour’s gland secretion extracts from females hetero- or homocolonial
with respect to the tested colonies. The behaviour of the colonies towards these lures indicates that, like the epicuticular
lipids, the Dufour’s gland secretion is involved in nestmate recognition.
Received: 14 August 1995/Accepted after revision: 5 November 1995 相似文献
129.
Biomonitoring aquatic environmental quality in a marine protected area: a biomarker approach 总被引:1,自引:0,他引:1
The main aims of the present study, conducted in the framework of the MONIQUA-Egadi Scientific Project, were twofold: first, to make the first step in the development and validation of an ecotoxicological approach for the assessment of marine pollution in coastal environments on the basis of a set of biomarker responses in new sentinel species; and second, to obtain preliminary information on environmental quality in an Italian marine protected area, the Egadi Islands (Sicily). Several cytochrome P450-dependent mixed-function oxidase activities were measured in the following sentinel species: rainbow wrasse Coris julis, gastropod limpet Patella caerulea, and sea urchin Paracentrotus lividus. The results suggest that specimens from the Favignana Harbor may be exposed to P450 inducers, whereas most of the other sites seem to share similar environmental quality. The proposed approach has potential for assessment of environmental quality in marine protected areas. 相似文献
130.
Tsunami Survey Expedition: Preliminary Investigation of Maldivian Coral Reefs Two Weeks After the Event 总被引:1,自引:0,他引:1
On December 26th 2004, a earthquake west of Sumatra generated a devastating tsunami. Hundreds of thousands of people fell
victim. Economic losses were greatest in those countries dependant on tourism. The impact in the Maldives on persons and things
was modest. Immediately following the event and notwithstanding the lack of scientific data, the mass media gave catastrophic
reports on the state of coral reefs in the area. This paper reports on the first survey on coral reefs in the Maldives after
the Tsunami. Ocean walls, passes, inner reefs, and shoals in the North and South Malé atolls, were surveyed two weeks after
the event. Significant damage was recorded in the passes in the South Malé atoll. Our observations showed that the damage
was more or less extensive depending on latitude and topography. Sri Lanka may have broken the wave’s rush, reducing the extent
of the impact on northern atolls. The water’s acceleration inside the passes was so intense as to cause reef collapses. The
observed damage represents a minimum fraction of the entire coral reef system. Tourist perception of the area seems unchanged.
These data may be used to disseminate correct information about the state of Maldives coral reefs, which would be useful in
relaunching local economy. 相似文献