Flame Temperature in Oil-Fired Fuel-Burning Equipment and its Relationship to Carbonaceous Particulate Emissions

Field tests were conducted on 82 fuel-burning installations ranging from 50 to 500 hp, fired with residual fuel oils. A flame pyrometer was used to measure peak flame temperatures. Coarse particulates were measured by impingement on adhesive paper strips inserted at right angles to the gas flow and fine particulates by filtration of the gas sample through filter paper. Both were evaluated using a standard Bacharach Scale. The tests clearly established that both coarse and fine particulate matter invariably occurred with low flame temperatures but decreased appreciably when peak flame temperatures reached approximately 2650°F; Minimum values were observed at temperatures somewhere between 2750 and 2850°F. This research was conducted as a result of the problem of acid smut and carbonaceous (ceno-sphere) fallout which appears to have increased with the advent of modern high-efficiency low-temperature heating installations and taller, cooler operating chimneys; sudden deluges of particles from the chimney serving large oil-burning plants soil clothing, pit car finishes, and damage nylon stockings and other materials.     

Analysis for Exhaust Gas Hydrocarbons—Nondispersive Infrared Versus Flame-lonizaticn

An investigation has been made of the suitability of a nondispersive infrared analyzer and two flame-ionization analyzers for measuring the total hydrocarbon concentrations of automobile exhaust gas. The investigation consisted of measuring relative responses of various hydrocarbons, checking for possible exhaust gas interferences and finally comparing exhaust hydrocarbon concentrations indicated by the flame-ionization analyzer to those indicated by the infrared analyzer. The infrared analyzer has high relative responses for parraffins and low responses for olefins, acetylenes, and aromatics. Also, the infrared indicated hydrocarbon concentrations must be corrected for exhaust water vapor interference. When the flameionization analyzers are operated at conditions that result in approximately uniform response to hydrocarbons and low oxygen interference, the exhaust hydrocarbon concentrations indicated by either flameionization analyzer are better approximations of the total hydrocarbon concentration than those indicated by the infrared analyzer.     

Determining the Costs of Air Pollution Control

A general procedure has been described that can be followed for estimating the cost of reducing air pollution emissions within a metropolitan region. The six step procedure examines emission inventories, regional trends, control trends, alternate control schemes, control costs, and optimum cost-effectiveness. The procedure is illustrated for one emission source in the Delaware Valley. By application of “feasible controls,” automobile emissions were shown to be reduced from 4.5 billion pounds per year in the Region during 1968 to 1.5 billion pounds in the year 2000. Annual control costs during the same period will increase from $30 million to over $300 million per year. This represents a cost increase from $15 per registered vehicle in 1968 to about $58 per vehicle per year in 2000. A method was illustrated for determining minimum cost to achieve any desired degree of emission reduction where alternate feasible control schemes are available. This method is especially useful where the allocation of scarce resources is involved. The general procedure is applicable to any number of pollutants and emission sources, and may be useful for calculations in any metropolitan area. The objectives of the present study are to apply this method to other sources within the Delaware Valley and to determine total regional costs for various levels of emission reduction. As one example of a practical application for this type of analysis, the economic impact of regulatory schemes can be evaluated on a cost-effectiveness basis     

Estrogen receptor mediated activity in bankside groundwater, with flood suspended particulate matter and floodplain soil - an approach combining tracer substance, bioassay and target analysis

Bankside groundwater is widely used as drinking water resource and, therefore, contamination has to be avoided. In the European Union groundwater protection is explicit subject to Water Framework Directive. While groundwater pollution may originate from different sources, this study investigated on impacts via flood events.Groundwater was sampled with increasing distance to the river Rhine near Karlsruhe, Germany. Samples were HPLC-MS-MS analyzed for the river contaminant carbamazepine to indicate river water infiltration, giving permanent presence in 250 m distance to the river (14-47 μg L⁻¹). Following a flood event, concentrations of about 16-20 μg L⁻¹ could also be detected in a distance of 750 m to the river. Furthermore, estrogenic activity as determined with the Yeast Estrogen Screen assay was determined to increase up to a 17β-ethinylestradiol equivalent concentration (E-EQ) = 2.9 ng L⁻¹ near the river, while activity was initially measured following the flood with up to E-EQ = 2.6 ng L⁻¹ in 750 m distance. Detections were delayed with increasing distance to the river indicating river water expansion into the aquifer.Flood suspended matter and floodplain soil were fractionated and analyzed for estrogenic activity in parallel giving up to 1.4 ng g⁻¹ and up to 0.7 ng g⁻¹, respectively. Target analysis focusing on known estrogenic active substances only explained <1% of measured activities.Nevertheless, river water infiltration was shown deep into bankside groundwater, thus, impacting groundwater quality. Therefore, flood events have to be in the focus when aiming for groundwater and drinking water protection as well as for implementation of Water Framework Directive.     

Autotrophic denitrification using hydrogen oxidizing bacteria in continuous flow biofilm reactor

Autotrophic denitrification was investigated in five bench‐scale upflow attached growth reactors using hydrogen oxidizing bacteria under anoxic conditions. The performance of sand, granular activated carbon (GAC), crushed pumice, crushed volcanic rock, and plastic media were evaluated as the support material. The reactors were inoculated with acclimated cultures obtained from domestic sewage treatment plant. A synthetic solution containing nitrate was used as the influent. The reactor performance was evaluated by measuring influent and effluent nitrate concentration. The design parameters demonstrated that the effectiveness of autotrophic denitrification is comparable to that of the heterotrophic process and may be utilized economically for drinking water treatment either as the main process or as a supplemental process for ion exchange regenerant treatment.     

Hunting Effects on Favourable Conservation Status of Highly Inbred Swedish Wolves

The wolf (Canis lupus) is classified as endangered in Sweden by the Swedish Species Information Centre, which is the official authority for threat classification. The present population, which was founded in the early 1980s, descends from 5 individuals. It is isolated and highly inbred, and on average individuals are more related than siblings. Hunts have been used by Swedish authorities during 2010 and 2011 to reduce the population size to its upper tolerable level of 210 wolves. European Union (EU) biodiversity legislation requires all member states to promote a concept called “favourable conservation status” (FCS) for a series of species including the wolf. Swedish national policy stipulates maintenance of viable populations with sufficient levels of genetic variation of all naturally occurring species. Hunting to reduce wolf numbers in Sweden is currently not in line with national and EU policy agreements and will make genetically based FCS criteria less achievable for this species. We suggest that to reach FCS for the wolf in Sweden the following criteria need to be met: (1) a well‐connected, large, subdivided wolf population over Scandinavia, Finland, and the Russian Karelia‐Kola region should be reestablished, (2) genetically effective size (N_e) of this population is in the minimum range of N_e = 500–1000, (3) Sweden harbors a part of this total population that substantially contributes to the total N_e and that is large enough to not be classified as threatened genetically or according to IUCN criteria, and (4) average inbreeding levels in the Swedish population are <0.1. Efectos de la Cacería sobre el Estatus de Conservación Favorable de Lobos Suecos con Endogamia Alta     

A Portable,Battery-Operated,Immediate-Readout Dust-Particle Analyzer

A portable, battery-operated, electro-optical dust analyzer operating on the principle of light scattering from individual dust particles in air drawn through a high-intensity light field has been developed for monitoring dust levels where external power may be unavailable. The instrument counts and size-discriminates airborne particles over two size ranges upwards of 0.3 microns with immediate readout. A dilution mechanism permits analysis of particulate concentrations as high as 2400 particles/cm³ on each channel. The self-contained Ni-Cd batteries are rechargeable. Total weight, including batteries and all components, is approximately 14 Ib. Total power used, mainly for pumping a filtered air sheath at 300 cm/sec and for the light source, is less than 34 watts. Another unique feature is the flow system designed for turbulence suppression.

Electronic calibration in terms of number of particles/cm³ for each size range is accomplished in the laboratory by means of a pulse generator with respect to which the readout indicator is calibrated for count. The input voltages to the pulse-height discriminators are appropriately attenuated for various pulse amplitudes simulating the output of the light-sensitive pickup, a photomultiplier tube.Pulse height as a function of particle size was measured for polystyrene latex beads ranging from 0.3 to 2 microns in diameter. Good correlation is obtained with results from commercial analyzers.

Field surveys have been undertaken with the CAES prototype analyzer at various sites in central Pennsylvania and at numerous sampling points within the cities of Pittsburgh and Philadelphia. Particulate concentrations as high as 1400 particles/ cm³ have been measured at a coal cleaning plant.