内蒙古煤化工废水零排放中浓盐废水处理技术及存在的问题讨论

内蒙古自治区煤炭储量位居全国首位,同时又属于严重缺水地区,煤化工、盐化工等化工废水零排放为成了热点话题。浓盐水的处理成为制约化工废水零排放的关键技术。介绍了浓盐水的处理技术及存在的问题同时对主要处理技术的投资行进了比较分析。     

深圳陆源入海排污口现状及污染防治对策研究

深圳全市共有直入海河道82条,陆源主要入海排污口(包括受污染的入海河流、入海人工渠道及重点企业排污口)53个.根据2013年上半年对深圳市主要入海排污口进行实地勘查结果和对应水质监测数据,分析了深圳陆源入海排污口现状,针对排污口排污超标情况严重问题,提出了开展综合治理工程对重点河流进行整治、加快污水收集处理系统建设等措施,为近岸海域入海排污口污染物总量控制和海洋环境污染整治提供科学支撑.     

离子色谱法测定钻井废水中的S~(2-)

川东气田生产过程中产生的废水含有硫化物,且色度深、浊度大。为测定废水中的Ｓ２－含量,实验探索了将Ｓ２－氧化成ＳＯ２－４后用离子色谱测定的方法。进行了Ｓ２－的转化率实验,结果表明：Ｓ２－含量在０～２．７ｍｇ／Ｌ范围内可以被完全氧化成ＳＯ２－４,转化率为９８．８％～１０８．０％。同时进行了该方法的精密度和准确度实验,并与碘量法进行了对比,对同一标样和实际样品的测定两种方法的结果吻合较好,该方法测定钻井废水中的Ｓ２－含量,可以避免色度、浊度的干扰,且简便、灵敏、准确     

沈阳市冬季一次典型大气污染过程特征和成因分析

2013年11月18日~25日沈阳地区出现一次典型空气污染过程。采用单颗粒气溶胶质谱仪(SPAMS),并结合气象条件分析了该次污染的成因和细颗粒物的污染特征。结果表明,不利于污染物扩散的气象条件是重污染发生的主要原因,低空排放的积累可能是造成这次污染的又一重要原因。从细颗粒物成分上看,污染过程中有机碳颗粒占比明显增加,有机物污染较为严重,颗粒物间混合加剧;从来源上看,机动车尾气、工业排放和燃煤的占比较高。     

污水土地处理技术研究的最新进展

本文以地下渗滤系统、慢速渗滤系统为例 ,介绍了污水土地处理技术研究的最新进展 ,指出加速污水土地处理技术产业化的进程必将大大促进我国的环境保护与生态建设工作 ,并带来巨大的环境、经济与社会效益。     

双台子河口国家自然保护区红海滩景观退化机制研究

双台子河口国家自然保护区的红海滩景观由生长在潮间带的天然翅碱篷(Suaeda heteroptera)群落形成,是世界上数量最大的黑嘴鸥(Larus saundersi)的觅食和繁殖场所.近年来,由于翅碱篷群落大面积萎缩,黑嘴鸥数量急剧减少.通过现场监测和实验模拟,对潮间带翅碱蓬群落的生态学特性和红海滩景观退化机制进行了研究.潮间带翅碱篷是一种非常特殊的植物群落,只生长在特定标高的有周期性潮汐作用的滩涂上,过高或过低均不能生长.潮汐是保证翅碱篷在高盐度潮间带正常生长的重要自然力,可以及时洗脱翅碱篷排出体外的大量盐分,避免盐分结晶形成盐鞘使植物受害死亡.研究发现,潮间带翅碱篷群落退化的原因是由于滩涂因泥沙沉积抬升,潮位降低造成的,而拦海坝的修筑是导致滩涂快速升高的直接原因.采取必要的工程措施,翅碱篷群落是可以人工恢复的.     

Correlations between fine particulate matter (PM2.5) and meteorological variables in the United States: Implications for the sensitivity of PM2.5 to climate change

We applied a multiple linear regression (MLR) model to study the correlations of total PM_2.5 and its components with meteorological variables using an 11-year (1998–2008) observational record over the contiguous US. The data were deseasonalized and detrended to focus on synoptic-scale correlations. We find that daily variation in meteorology as described by the MLR can explain up to 50% of PM_2.5 variability with temperature, relative humidity (RH), precipitation, and circulation all being important predictors. Temperature is positively correlated with sulfate, organic carbon (OC) and elemental carbon (EC) almost everywhere. The correlation of nitrate with temperature is negative in the Southeast but positive in California and the Great Plains. RH is positively correlated with sulfate and nitrate, but negatively with OC and EC. Precipitation is strongly negatively correlated with all PM_2.5 components. We find that PM_2.5 concentrations are on average 2.6 μg m^?3 higher on stagnant vs. non-stagnant days. Our observed correlations provide a test for chemical transport models used to simulate the sensitivity of PM_2.5 to climate change. They point to the importance of adequately representing the temperature dependence of agricultural, biogenic and wildfire emissions in these models.     

Characterization of cadmium (Cd) distribution and accumulation in Tagetes erecta L. seedlings: Effect of split-root and of remove-xylem/phloem

Tagetes erecta has a high potential for cadmium (Cd) phytoremediation. Through several hydroponic experiments, characteristics of ¹⁰⁸Cd distribution and accumulation were investigated in T. erecta with split -roots or removed xylem/phloem. The results showed that ¹⁰⁸Cd transport from roots to aboveground tissues showed the homolateral transport phenomenon in split-root seedlings. ¹⁰⁸Cd content of leaves on the +¹⁰⁸Cd side and the −¹⁰⁸Cd side was not significantly different, which implied that there was horizontal transport of ¹⁰⁸Cd from the +¹⁰⁸Cd side to the −¹⁰⁸Cd side in cut-root seedlings. Like ¹⁰⁸Cd transport, the transport of ⁷⁰Zn was homolateral. Reduction of water consumption in the removed xylem treatment significantly decreased ¹⁰⁸Cd accumulation; whereas, the removed phloem treatment had no significant effect on water consumption, but did decrease ¹⁰⁸Cd accumulation in leaves of the seedlings. The removal of phloem significantly reduced distal leaf ¹⁰⁸Cd content, which was significantly lower than that in the basal leaves in both the split-root and unsplit-root seedlings. Overall, the results presented in this study revealed that the root to aboveground cadmium translocation via phloem is as an important and common physiological process as xylem determination of the cadmium accumulation in stems and leaves of marigold seedlings.     

Surface-enhanced Raman spectroscopic analysis of N6-benzylaminopurine residue quantity in sprouts with gold nanoparticles

ABSTRACT

A rapid and quantitative method for the determination of N⁶-Benzylademine (N⁶-BA) was established through the application of surface-enhanced Raman spectroscopy (SERS). The Raman peak intensities of N⁶-BA at 1002 cm^?1 positively correlated to N⁶-BA concentrations in sprout extracts. The R² reached 0.99, and RSDs calculated below 10% at the concentration range of 0.1 ～5μg mL^?1. The average recoveries were 80.0% ～ 98.2% for blank samples intentionally contaminated at differing levels of 0.04, 0.4, and 1 μg g^?1. The whole procedure, including sample preparation and SERS detection, did not exceed 30 min for a set of 6 samples. This study indicates that SERS is a promising technique for rapid tracing analysis and on-site testing of N⁶-BA.