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991.
Mutual effects of cadmium and phosphate on their adsorption and desorption by goethite 总被引:4,自引:0,他引:4
Adsorption of cadmium (Cd) and phosphate by oxides or soils has been extensively studied, but the adsorption/desorption kinetics and mutual effects of these two species in co-existing systems has received little attention. In this study, a batch equilibration method was used to investigate the effect of phosphate and its application time on Cd adsorption and desorption on goethite. The influence of Cd and its application time on phosphate sorption and desorption kinetics was also determined. For Cd adsorption, phosphate was introduced into the system by two sequences: pre-treating goethite at 40 (degrees)C for 1 week, and applying with Cd simultaneously. Similarly, for phosphate sorption, Cd was applied by pre-treating goethite at 40 (degrees)C for 1 week or simultaneous addition with phosphate. Results demonstrated that phosphate added to goethite enhanced Cd adsorption, and facilitated Cd release as compared to untreated goethite. Cadmium had slightly higher adsorption, but a significantly faster desorption rate from the goethite simultaneously treated with phosphate and Cd, as compared to phosphate-pretreated goethite. Cadmium and its application time had little impact on phosphate sorption by goethite. However, phosphate desorption kinetics was affected by Cd application time. When the sorption time was short (15 min), phosphate desorption was faster from the goethite that was simultaneously treated with phosphate and Cd, as compared to Cd pretreated or untreated goethite. In contrast, a longer sorption time (4 weeks) resulted in a higher desorption rate of phosphate from Cd pretreated goethite than simultaneously phosphate-Cd treated goethite. This study provided useful information on adsorption/desorption kinetics in complicated Cd-phosphate-goethite systems. 相似文献
992.
Yuan Jie Ding Shuang Li Huijin 《Journal of Material Cycles and Waste Management》2022,24(6):2608-2619
Journal of Material Cycles and Waste Management - Spent cathode carbon (SCC), with high recycling potential of carbon, is an unavoidable solid waste in the aluminum electrolysis industry. In this... 相似文献
993.
Guo Ting Bulin Chaoke Zhang Bangwen Ma Zeyu Xing Ruiguang Ge Xin Zhang Yanghuan Li Bo 《Journal of Polymers and the Environment》2022,30(2):569-584
Journal of Polymers and the Environment - Heavy metal pollution stems from the modern industry is a severe environmental problem. In this work, a highly efficient adsorbent based on starch-graphene... 相似文献
994.
Zhenming Zhou Canyang Lin Shuwen Li Shupo Liu Fei Li Baoling Yuan 《Frontiers of Environmental Science & Engineering》2022,16(3):29
995.
Yuwei Guo Xian Xiao Yuan Zhao Jianguo Liu Jizhong Zhou Bo Sun Yuting Liang 《Frontiers of Environmental Science & Engineering》2022,16(7):91
996.
Lei Li Shijie Yuan Chen Cai Xiaohu Dai 《Frontiers of Environmental Science & Engineering》2022,16(6):74
Methanogenesis is the last step in anaerobic digestion, which is usually a rate-limiting step in the biological treatment of organic waste. The low methanogenesis efficiency (low methane production rate, low methane yield, low methane content) substantially limits the development of anaerobic digestion technology. Traditional pretreatment methods and bio-stimulation strategies have impacts on the entire anaerobic system and cannot directly enhance methanogenesis in a targeted manner, which was defined as “broad-acting” strategies in this perspective. Further, we discussed our opinion of methanogenesis process with insights from the electron transfer system of syntrophic partners and provided potential targeted enhancing strategy for high-efficiency electron transfer system. These “precise-acting” strategies are expected to achieve an efficient methanogenesis process and enhance the bio-energy recovery of organic waste. 相似文献
997.
998.
Chen Xing Daihui Yang Yan Zhang Tian Sun Junfei Duan Hussein A.Younus Shiguo Zhang 《绿色能源与环境(英文)》2022,7(1):43-52
Heteroatom-doped meso/micro-porous carbon materials are conventionally produced by harsh carbonization under an inert atmosphere involving specific precursors, hard/soft templates, and heteroatom-containing agents. Herein, we report a facile synthesis of N and O co-doped meso/micro-porous carbon (NOMC) by template-free carbonization of a small-molecule precursor in a semi-closed system. The semi-closed carbonizaiton process yields hydrophilic NOMCs with large surface area in a high yield. The porous structure as well as the elemental composition of NOMCs can be modulated by changing the holding time at a particular temperature. NOMCs as metal-free heterogeneous catalysts can selectively oxidize benzyl alcohol and its derivatives into aldehydes/ketones with>85%conversion in aqueous solution, which is much higher than that of the control sample obtained in tube furnace (21%conversion), mainly due to their high N content, high percentage of pyridinic N, and large surface area. The presence of O-containing moieties also helps to improve the hydrophilicity and dispersion ability of catalysts and thus facilitates the mass transfer process during aqueous oxidation. The NOMC catalysts also dispayed excellent activity for a wide range of substrates with a selectivity of>99%. 相似文献
999.
Jin Baichuan Lin Zuhong Liu Weiyi Xiao Yong Meng Yuan Yao Xiaolong Zhang Tingting 《Environmental science and pollution research international》2022,29(14):20517-20529
Environmental Science and Pollution Research - The amount of dissolved organic matter (DOM) in a multi-source watershed is important for complete management and assessing the river basin’s... 相似文献
1000.
Du Wenbo Ma Xiaozhi Yuan Hongping Zhu Yue 《Environmental science and pollution research international》2022,29(39):58648-58663
Environmental Science and Pollution Research - The problems of data leakage and unreliable information transfer in the management process make sustainability management an inevitable need for... 相似文献