熟料造纸清洁生产量化评价—以承德兴业造纸项目为例

运用专家调查打分法，以具体的承德兴业造纸项目为例，初步探讨了清滞生产量化评价方法，程序以及清洁生产评价指标的应用。     

Occurrence, source diagnosis, and biological effect assessment of DDT and its metabolites in various environmental compartments of the Pearl River Delta, South China: A review

This review summarizes and analyzes available data in the literature (mostly after 2000) on the occurrence of dichlorodiphenyltrichloroethane (DDT) and its main metabolites, dichlorodiphenyldichloroethane (DDD) and chlorodiphenyldichloroethylene (DDE), in the environment of the Pearl River Delta (PRD), South China. Generally, the concentration levels of the sum of DDT, DDD, and DDE, designated as DDTs thereafter, have not significantly declined since 1983. However, the composition of DDTs residues has changed with time. DDTs in soil, freshwater sediment and freshwater fish species were mainly residues from chronological use. There is evidence that new point sources, such as dicofol and anti-fouling paint, may have contributed DDTs to various environmental compartments. Risk assessment against existing criteria indicated that the levels of DDTs in water and some fish species may pose adverse effects to humans or wildlife, and those in sediment/soil may also cause negative impacts to the eco-environment of the PRD.     

混凝法深度处理印染废水中试研究

采用"高效混凝沉淀-过滤"深度处理工艺处理印染废水二级生化出水,并将混凝沉淀污泥回流.实验结果表明,混凝剂聚合氯化铝加入量为160 mg/L时,COD去除率平均可达34.6%,TP去除率平均达到87.9%,平均出水TP为0.3 mg/L.气相色谱-质谱分析和元素分析结果表明混凝沉淀工艺对有机物和TP的去除效果良好.     

China's grazed temperate grasslands are a net source of atmospheric methane

A budget for the methane (CH₄) cycle in the Xilin River basin of Inner Mongolia is presented. The annual CH₄ budget in this region depends primarily on the sum of atmospheric CH₄ uptake by upland soils, emission from small wetlands, and emission from grazing ruminants (sheep, goats, and cattle). Flux rates for these processes were averaged over multiple years with differing summer rainfall. Although uplands constitute the vast majority of land area, they consume much less CH₄ per unit area than is emitted by wetlands and ruminants. Atmospheric CH₄ uptake by upland soils was ?3.3 and ?4.8 kg CH₄ ha^?1 y^?1 in grazed and ungrazed areas, respectively. Average CH₄ emission was 791.0 kg CH₄ ha^?1 y^?1 from wetlands and 8.6 kg CH₄ ha^?1 y^?1 from ruminants. The basin area-weighted average of all three processes was 6.8 kg CH₄ ha^?1 y^?1, indicating that ruminant production has converted this basin to a net source of atmospheric CH₄. The total CH₄ emission from the Xilin River basin was 7.29 Gg CH₄ y^?1. The current grazing intensity is about eightfold higher than that which would result in a net zero CH₄ flux. Since grazing intensity has increased throughout western China, it is likely that ruminant production has converted China's grazed temperate grasslands to a net source of atmospheric CH₄ overall.     

Incorporating layer- and local-scale heterogeneities in numerical simulation of unsaturated flow and tracer transport

This study characterizes layer- and local-scale heterogeneities in hydraulic parameters (i.e., matrix permeability and porosity) and investigates the relative effect of layer- and local-scale heterogeneities on the uncertainty assessment of unsaturated flow and tracer transport in the unsaturated zone of Yucca Mountain, USA. The layer-scale heterogeneity is specific to hydrogeologic layers with layerwise properties, while the local-scale heterogeneity refers to the spatial variation of hydraulic properties within a layer. A Monte Carlo method is used to estimate mean, variance, and 5th, and 95th percentiles for the quantities of interest (e.g., matrix saturation and normalized cumulative mass arrival). Model simulations of unsaturated flow are evaluated by comparing the simulated and observed matrix saturations. Local-scale heterogeneity is examined by comparing the results of this study with those of the previous study that only considers layer-scale heterogeneity. We find that local-scale heterogeneity significantly increases predictive uncertainty in the percolation fluxes and tracer plumes, whereas the mean predictions are only slightly affected by the local-scale heterogeneity. The mean travel time of the conservative and reactive tracers to the water table in the early stage increases significantly due to the local-scale heterogeneity, while the influence of local-scale heterogeneity on travel time gradually decreases over time. Layer-scale heterogeneity is more important than local-scale heterogeneity for simulating overall tracer travel time, suggesting that it would be more cost-effective to reduce the layer-scale parameter uncertainty in order to reduce predictive uncertainty in tracer transport.     

Mo-N-TiO2光催化剂的制备、表征及其活性提高机制

以钼酸铵和氨水分别为钼源和氮源,采用溶胶-凝胶法制备了Mo-N-TiO2光催化剂,并对其进行了XRD、XPS和UV-visDRS表征。XRD结果表明,Mo、N共掺杂有效抑制了TiO2晶粒的生长,提高了TiO2由锐钛矿向金红石相的转变温度。UV-vis表明,Mo-N-TiO2光催化剂可见光吸收能力增强,吸收带边明显"红移",且钼酸铵添加量(相对TiO2)为0.5%的样品"红移"程度最大,最大吸收带边为550 nm。XPS分析结果表明,Mo取代了TiO2晶格中的部分Ti4+,以Mo6+形式存在的,而N以Ti—N及N—Ti—O形式存在。以罗丹明B为模型污染物,重点考察了钼酸铵添加量与焙烧温度对Mo-N-TiO2光催剂性能的影响。结果表明,400℃焙烧下、钼酸铵添加量为0.5%的样品催化活性最好。模拟太阳光下光照120min对罗丹明B的降解率达到96.8%,是纯TiO2的2.42倍。     

长江上游曲麻莱至玉树段春秋季浮游植物群落结构及多样性评价

于2012年春季（4月）和秋季（10月）对长江上游曲麻莱至玉树段的浮游植物进行初步研究。结果显示：浮游植物共3门62种（属），以硅藻门最多，42种（属），占678%，其次是绿藻门11种（属），占177%，蓝藻门9种（属），占145%。浮游植物优势种为普通等片藻（Diatoma vulgare）、长等片藻（Diatoma elongatum）、尖针杆藻（Synedra acus）、曲壳藻（Achnanthes sp）、舟形藻（Navicula sp）、桥弯藻（Cymbella sp）、脆杆藻（Fragilaria sp）、直链藻（Melosira sp）、异极藻（Gomphonem sp）、菱形藻（Hantzchia sp）、小环藻（Cyclotella sp）、小颤藻（Oscillatoria tenuis）、席藻（Phormidium sp）和小球藻（Chlorella sp）14种，其中硅藻门12种（属），占优势种类的786%。浮游植物种类组成的季节变化不明显，春季（4月）和秋季（10月）均以硅藻为优势种群。浮游植物平均数量3487×104 cells/L，平均生物量0138 8 mg/L，硅藻数量和生物量分别占8786%和9668%,为优势种群。浮游植物现存量表现为春季高于秋季，支流高于干流。Shannon Wiener指数平均值251，Pielou指数平均值070，Marggalef指数平均值089，Shannon Wiener指数、Pielou指数和Marggalef指数是秋季高于春季。结合浮游植物各项评价指标，得出长江上游曲麻莱至玉树段浮游植物群落结构比较稳定，种类分布较为均匀，水体属贫营养型，水域生态环境良好     

The Relationship between the Quantity of Heavy Metal and PAHs in Fly Ash

ABSTRACT

Heavy metal and polycyclic aromatic hydrocarbons (PAHs) in flue gas have received considerable attention in recent years due to their mutagenic or carcinogenic properties. The present study is carried out to investigate the influence of the quantity of heavy metals on PAHs formation in fly ash.

A fluidized bed incinerator was used in this experiment to obtain fly ash of chemical similarity by incinerating various compositions of waste. The obtained fly ash, both with and without heavy metal, were used to adsorb the PAHs in the flue gas and to investigate the formation of PAHs in fly ash. The results indicate that carbon and heavy metals most greatly influence the formation of PAHs in the fly ash. Carbon is absorptive; heavy metals encourage not only absorption of PAHs but also catalyze PAHs formation.     

CDM Project Activities in China＇s Iron and Steel Industry：Current Status,Barriers and Development Strategies

China is now facing huge pressure from both the domestic concern of energy security and the global community's call for emission reduction commitment. As one of the major energy consumers and greenhouse gas emitters, China's iron and steel industry has a huge clean development mechanism (CDM) potential. This article both quantitatively and qualitatively analyzes the current status of CDM project activities in the iron and steel industry in China, including characteristics of approved project types, applicable methodologies, and potential technology fields. From the perspective of project implementation, the article summarizes development barriers such as high investment risk, difficulty in project identification, strict requirements on PPDs, long registration waiting time, and etc. Policy suggestions are also put forwarded to help better promote the development of CDM projects in the iron and steel industry.     

大坝下游定点区域溶解氧饱和度预测

大坝通过坝身泄流时，巨大的洪水卷吸空气中的大量气体直泻到下游河床，造成下游河道特别是近坝区域气体含量过饱和，给下游水生生物带来不利影响，其中鱼类气泡病就是水体气体过饱和造成的典型病症。为探明大坝泄流对坝下河道溶解氧饱和度的影响，以三峡 葛洲坝区域坝下近坝区定点区域的溶解氧实测资料为基础，建立溶解氧饱和度的BP网络预测模型，对大坝不同运行工况进行下游溶解氧饱和度的预测仿真计算，并将仿真预测值与实测及数值模拟结果进行比较分析。结果得出BP网络模型能很好地逼近坝下近坝区指定区域的溶解氧饱和度，可根据大坝运行工况对下游水体溶解氧饱和度进行快速预测，为有效控制坝下水体溶解氧饱和度提供借鉴