Optimization and treatment of wastewater of crude oil desalting unit and prediction of scale formation

In this article, one of Iran’s southwest oil fields that produces 3200 barrels per day (bbl/d) of wastewater from oil and gas processing was investigated. Experimental analysis of oil reservoir water and desalting wastewater disposal of crude oil desalting unit was performed. First, water was treated with a reverse osmosis membrane. As a result, the purified water, with lower total dissolved solids (TDS) and pH, was a suitable candidate for injection into the adjacent wells of the crude oil desalting unit. The effectiveness and compatibility of this wastewater to the formation water of the oil field wells were simulated. Finally, we studied and identified the formation, the amount, and the type of mineral scale deposits. These are the most important problems during water injection into the wells. The analysis shows that the refined water from the reverse osmosis (RO) process was a suitable and low-cost economical option for injection in onshore and offshore fields, due to the low amount of salts, the concentration of susceptible ions in scaling formation, and the appropriate pH. This oil field, which is in the second half of life, requires enhanced oil recovery methods (EOR) for the maintenance of pressure and an increase in oil recovery.

     

A fuzzy multi-stakeholder multi-criteria methodology for water allocation and reuse in metropolitan areas

In this paper, a fuzzy decision making methodology is proposed to find a socially optimal scenario for allocating effluent of wastewater treatment plants and urban and suburban runoffs to agricultural regions and recharging aquifers. The presented methodology named modified fuzzy social choice (MFSC) considers multi-stakeholder multi-criteria problems under uncertainties inherent in a decision making process utilizing a fuzzy ranking method and the fuzzy social choice (FSC) theory. A set of water and wastewater allocation scenarios are proposed for water quantity and quality management of the study area, while six main stakeholders with conflicting utilities and different negotiation powers are involved. The proposed methodology is applied to Tehran metropolitan area, the capital city of Iran with the population of about 8 million people, to examine its applicability and effectiveness. The results shows that using fuzzy multi-stakeholder multi-criteria decision making method considering equal and different negotiation powers can lead to different outcomes. Based on the results, the MFSC method, which considers a number of decision makers having different negotiation powers, degrees of importance of decision making criteria, and some important uncertainties, performs more promising in real water resources management problems.     

Tolerance of juvenile barnacles (Amphibalanus improvisus) to warming and elevated pCO2

We investigated the impacts of warming and elevated pCO₂ on newly settled Amphibalanus improvisus from Kiel Fjord, an estuarine ecosystem characterized by significant natural pCO₂ variability. In two experiments, juvenile barnacles were maintained at two temperature and three pCO₂ levels (20/24 °C, 700–2,140 μatm) for 8 weeks in a batch culture and at four pCO₂ levels (20 °C, 620–2,870 μatm) for 12 weeks in a water flow-through system. Warming as well as elevated pCO₂ hardly affected growth or the condition index of barnacles, although some factor combinations led to temporal significances in enhanced or reduced growth with an increase in pCO₂. While warming increased the shell strength of A. improvisus individuals, elevated pCO₂ had only weak effects. We demonstrate a strong tolerance of juvenile A. improvisus to mean acidification levels of about 1,000 μatm pCO₂ as is already naturally experienced by the investigated barnacle population.     

Atrazine and mancozeb induce excitotoxicity and cytotoxicity in primary cultures of mouse cerebellar cortex

This work aimed to determine the neurotoxicity of atrazine and mancozeb by high performance liquid chromatography (HPLC) evaluation of neurotransmitters, and morphologically by flow cytometry and ultrastructural analysis using transmission electron microscopy of primary cultures of mouse cerebellar cortex. The latter revealed mitochondrial damage, synaptic alterations, and neuroinflammation, while neurochemical results showed augmented release of excitatory neurotransmitters with a consequent increase in excitation/inhibition ratio of atrazine- and mancozeb-treated cultures. This study shows that atrazine and mancozeb exposure may lead to neuronal damage associated with excitotoxicity and cytotoxicity.     

Regional convergence of energy-environmental efficiency: from the perspective of environmental constraints

Environmental Science and Pollution Research - This paper conducts a convergence analysis on the energy-environmental efficiency to explore the differences between regions that reflect the...     

Release behavior of metals from tin-lined copper cookware into food simulants during cooking and cold storage

Environmental Science and Pollution Research - The copper pots with an inner coating layer of tin have been remarkably used in many countries for a long time. In this study, leaching of some metals...     

Investigation on the role of traffic volume in accidents on urban highways

Introduction

Roadway safety is a major concern for the general public and public agencies, as roadway crashes claim many lives and cause substantial economic loss each year. In Iran, a large number of vehicles are involved in road accidents each year, which cause many deaths and extensive property damage; such accidents are among the major causes of death and disability in the country. Method: To reduce roadway accidents, the factors that affect the occurrence and severity of accidents should be scrutinized to prevent or reduce their effect. The method that many researchers have adopted to determine the effective parameters surrounding road accidents in recent years is through statistical modeling of accidents. In this article, the role of different kinds of vehicles in traffic flow are investigated separately in terms of the likelihood of crashes on urban highways, and the vehicles are divided into three groups: passenger cars, heavy vehicles, and light non-passenger car vehicles. Poisson and negative binomial (NB) regression models were applied to model the accidents in this research, which were categorized into two groups: no injury (property damage only) accidents and more severe (injury and fatal) accidents. Results: Ultimately, we conclude that light non-passenger car vehicles (i.e., taxis and motorcycles) play the largest role in the occurrence of crashes on urban highways for both types of accidents.     

Contact toxicities of anuran skin alkaloids against the fire ant (Solenopsis invicta)

Nearly 500 alkaloids, representing over 20 structural classes, have been identified from the skin of neotropical poison frogs (Dendrobatidae). These cutaneous compounds, which are derived from arthropod prey of the frogs, generally are believed to deter predators. We tested the red imported fire ant (Solenopsis invicta) for toxicosis following contact with 20 alkaloids (12 structural classes) identified from dendrobatids or other anurans. Individual ants forced to contact the dried residues of 13 compounds exhibited convulsions and/or reduced ambulation. We estimated the cutaneous concentrations of several compounds based on their reported recoveries from skin extracts of free-ranging frogs and our measurements of the skin surface areas of museum specimens. Pumiliotoxin 251D exhibited contact toxicity below its estimated cutaneous concentration in the Ecuadorian frog, Epipedobates anthonyi, an observation consistent with the hypothesized role of this compound in anuran chemical defense. Our results and those of a previous study of mosquitoes indicate that some anuran skin compounds function defensively as contact toxins against arthropods, permeating their exoskeleton.     

On the feasibility of producing polymer–metal composites via novel variant of friction stir processing

In this study a novel variant of friction stir processing was developed for producing of polymer metal surface or bulk composites in order to enhance the mechanical, electrical and thermal properties. For this purpose, a novel tooling system was designed consists of a rotating pin, a stationary shoulder and a heating system located inside the shoulder. In present paper, for preliminary study high-density polyethylene and copper powder was selected as polymeric matrix and metallic additive, respectively. Surface quality, microstructure, ultimate tensile strength and the modulus of elasticity were determined for each prepared sample. From experimental tests, it was found that this approach is an efficient method for producing of polymer–metal composites.     

DBP formation from degradation of DEET and ibuprofen by UV/chlorine process and subsequent post-chlorination

The formation of disinfection by-products(DBPs) from the degradation of N,N-diethyl-3-methyl benzoyl amide(DEET) and ibuprofen(IBP) by the ultraviolet irradiation(UV)/chlorine process and subsequent post-chlorination was investigated and compared with the UV/H_2O_2 process.The pseudo first-order rate constants of the degradation of DEET and IBP by the UV/chlorine process were 2 and 3.1 times higher than those by the UV/H_2O_2 process, respectively, under the tested conditions. This was due to the significant contributions of both reactive chlorine species U(RCS) and hydroxyl radicals(HO) in the UV/chlorine process. Trichloromethane, 1,1,1-trichloro-2-propanone and dichloroacetic acid were the major known DBPs formed after 90% of both DEET and IBP that were degraded by the UV/chlorine process. Their yields increased by over 50%after subsequent 1-day post-chlorination. The detected DBPs after the degradation of DEET and IBP comprised 13.5% and 19.8% of total organic chlorine(TOCl), respectively, and the proportions increased to 19.8% and 33.9% after subsequent chlorination, respectively. In comparison to the UV/H_2O_2 process accompanied with post-chlorination, the formation of DBPs and TOCl in the UV/chlorine process together with post-chlorination was 5%–63% higher,Ulikely due to the generation of more DBP precursors from the attack of RCS, in addition to HO.