热脱附-气相色谱法测定空气中的总挥发性有机化合物研究

建立了热脱附-毛细管气相色谱法测定空气中苯、甲苯、乙酸丁酯、乙苯、对/间二甲苯、邻二甲苯、苯乙烯和十一烷等挥发性有机物的检测方法。九种挥发性有机物在一定浓度范围内标准曲线线性良好,相关系数均在0.997~0.999之间。检出限在0.002~0.005 mg/m3(采样体积1.0 L计)。用该方法检测了企业产生的有机废气及厂区周边环境空气,实验结果表明该方法灵敏度高、操作简单、重现性好、准确可靠,能够满足对实际样品的分析要求。     

生态环境变化遥感评价指数的应用研究——以敖江流域为例

利用1994年5月12日与2009年6月6日的Landsat TM和2001年5月23日的Landsat ETM＋卫星影像,选用遥感生态指数（RSEI）,结合流域的植被覆盖度状况,定量评价了15年间敖江流域的生态环境变化与植被覆盖度变化情况,并对二者的关系进行了简要分析.结果表明：15年间,敖江流域生态等级为优所占的面积比例从13.48％上升到24.90％,增加了304.29 km2;植被覆盖度等级为极高的面积增加比例为29.31％.总体看来,敖江流域生态环境状况和植被覆盖状况均有明显的提高,两者具有较好的对应关系.     

内蒙古省级层面碳汇总量评估必要性与框架初探

结合国内外最新研究进展，制定适合内蒙古区域特点的碳汇测算方法和评估体系框架，科学估算碳汇状况，系统分析我区不同陆地生态系统类型的碳汇大小及其机制，可提供关于我区陆地生态系统碳汇功能可信、翔实和正确的估算结果；新时期省级层面上开展陆地生态系统碳汇总量评估十分重要。     

集中供热工程实施前后大气环境影响对比分析研究

采暖期的大气环境质量与供热方式息息相关,集中供热是提高我国环境空气质量的一种可行办法。以定西市临洮县集中供热项目为例,结合拟建项目的建设特点,利用环评软件——AERMOD预测模式分析实施集中供热工程前后以大气为主的环境影响的差异,用以说明集中供热工程的实施具有巨大的环境效益。分析表明:集中供热减少了SO2、NO X烟尘的排放量,对环境的改善将起到良好的作用。     

Dissipation and residue behavior of mepiquat on wheat and potato field application

A modified LC-MS method for the analysis of mepiquat residue in wheat, potato, and soil was developed and validated. A hydrophilic interaction liquid chromatographic column has been successfully used to retain and separate the mepiquat. Mepiquat residue dynamics and final residues in supervised field trials at Good Agricultural Practice (GAP) conditions in wheat, potato, and soil were studied. The limits of quantification for mepiquat in all samples were all 0.007 mg kg^?1, which were lower than their maximum residue limits. At fortification levels of 0.04, 0.2, and 2 mg kg^?1 in all samples, recoveries ranged from 77.5 to 116.4 % with relative standard deviations of 0.4–7.9 % (n?=?5). The dissipation half-lives (T _1/2) of mepiquat in soil (wheat), wheat plants, soil (potato), and potato plants were 4.5–6.3, 3.0–5.6, 2.2–4.6, and 2.4–3.2 days, respectively. The final residues of mepiquat were below 0.153 mg kg^?1 in soil (wheat), 0.052–1.900 mg kg^?1 in wheat, below 0.072 mg kg^?1 in soil (potato), and below 1.173 mg kg^?1 in potato at harvest time. Moreover, pesticide risk assessment for all the detected residues was conducted. A maximum 0.0012 % of acceptable daily intake (150 mg kg^?1) for national estimated daily intake indicated low dietary risk of these products.     

Aquatic photolysis of hydroxylated polybromodiphenyl ethers under direct UV irradiation: a case study of 2′-HO-BDE-68

Environmental Science and Pollution Research - Hydroxylated polyhalodiphenyl ethers (HO-PXDEs) have attracted considerable scientific interest as examples of emerging aquatic pollutants. However, a...     

Even sampling designs generation by charges repulsion simulation

Evenly distributed sampling design is generally considered as an efficient sampling design. It is widely used in sampling for the environmental survey. In this paper, we present a novel method for generating N evenly distributed samples within a given irregular polygon via simulating the movements of some ideal homogeneous point charges. Initially, charges are randomly put into the sampling region; then, they are freed and held orderly; and after enough runs, the charges will finally reach a stable state with all of them having a zero resultant force and velocity; and so they distribute evenly within the region. Their layout can thus be considered as an evenly distributed sampling design. The main advantages of this method are: (1) it is easy to understand and implement; (2) it is efficient in both running and generating better designs. Analysis and experimental results indicate that this method is an efficient and robust method for generating even sampling designs for 2D polygonal sampling region.     

Increase in biodegradation of dimethyl phthalate by Closterium lunula using inorganic carbon

The effect and mechanism of inorganic carbon (IC) on the biodegradation of dimethyl phthalate (DMP) by a green microalga Closterium lunula was investigated. The growth of this microalga and the biodegradation of DMP were significantly enhanced when the initial IC was increased. An intermediate product of DMP biodegradation was identified as phthalic acid (PA) that was accumulated and caused a sharp decrease in pH of microalgal culture medium, which inhibited both the growth of microalga and the biodegradation of DMP. A suggested second-order kinetic equation of organic pollutant biodegradation by microalgae (-dC/dt = kNr) fitted well with the experimental data. The increase of IC caused a decline in biodegradation rate constant for organic carbon (k) and an increase in growth (N) by supplying a favorite carbon source and mitigating the decrease of pH. As the net effect, the overall biodegradation rate of DMP was promoted as IC increased, which was dominated by the increase of microalgal growth.     

Rapid degradation of butachlor in wheat rhizosphere soil

The degradative characteristics of butachlor in non-rhizosphere, wheat rhizosphere, and inoculated rhizosphere soils were measured. The rate constants for the degradation of butachlor in non-rhizosphere, rhizosphere, and inoculated rhizosphere soils were measured to be 0.0385, 0.0902, 0.1091 at 1 mg/kg, 0.0348, 0.0629, 0.2355 at 10 mg/kg, and 0.0299, 0.0386, 0.0642 at 100 mg/kg, respectively. The corresponding half-lives for butachlor in the soils were calculated to be 18.0, 7.7, 6.3 days at 1 mg/kg, 19.9, 11.0, 2.9 days at 10 mg/kg, and 23.2, 18.0, 10.8 days at 100 mg/kg, respectively. The experimental results show that the degradation of butachlor can be enhanced greatly in wheat rhizosphere, and especially in the rhizosphere inoculated with the bacterial community designated HD which is capable of degrading butachlor. It could be concluded that rhizosphere soil inoculated with microorganisms-degrading target herbicides is a useful pathway to achieve rapid degradation of the herbicides in soil.