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91.
92.
A directional passive air sampler for monitoring polycyclic aromatic hydrocarbons (PAHs) in air mass
Tao S Liu YN Lang C Wang WT Yuan HS Zhang DY Qiu WX Liu JM Liu ZG Liu SZ Yi R Ji M Liu XX 《Environmental pollution (Barking, Essex : 1987)》2008,156(2):435-441
A passive air sampler was developed for collecting polycyclic aromatic hydrocarbons (PAHs) in air mass from various directions. The airflow velocity within the sampler was assessed for its responses to ambient wind speed and direction. The sampler was examined for trapped particles, evaluated quantitatively for influence of airflow velocity and temperature on PAH uptake, examined for PAH uptake kinetics, calibrated against active sampling, and finally tested in the field. The airflow volume passing the sampler was linearly proportional to ambient wind speed and sensitive to wind direction. The uptake rate for an individual PAH was a function of airflow velocity, temperature and the octanol-air partitioning coefficient of the PAH. For all PAHs with more than two rings, the passive sampler operated in a linear uptake phase for three weeks. Different PAH concentrations were obtained in air masses from different directions in the field test. 相似文献
93.
94.
Temporal and spatial distributions of sediment total organic carbon in an estuary river 总被引:1,自引:0,他引:1
Understanding temporal and spatial distributions of naturally occurring total organic carbon (TOC) in sediments is critical because TOC is an important feature of surface water quality. This study investigated temporal and spatial distributions of sediment TOC and its relationships to sediment contaminants in the Cedar and Ortega Rivers, Florida, USA, using three-dimensional kriging analysis and field measurement. Analysis of field data showed that large temporal changes in sediment TOC concentrations occurred in the rivers, which reflected changes in the characteristics and magnitude of inputs into the rivers during approximately the last 100 yr. The average concentration of TOC in sediments from the Cedar and Ortega Rivers was 12.7% with a maximum of 22.6% and a minimum of 2.3%. In general, more TOC accumulated at the upper 1.0 m of the sediment in the southern part of the Ortega River although the TOC sedimentation varied with locations and depths. In contrast, high concentrations of sediment contaminants, that is, total polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), were found in sediments from the Cedar River. There was no correlation between TOC and PAHs or PCBs in these river sediments. This finding is in contradiction to some other studies which reported that the sorption of hydrocarbons is highly related to the organic matter content of sediments. This discrepancy occurred because of the differences in TOC and hydrocarbon source input locations. It was found that more TOC loaded into the southern part of the Ortega River, while almost all of the hydrocarbons entered into the Cedar River. This study suggested that the locations of their input sources as well as the land use patterns should also be considered when relating hydrocarbons to sediment TOC. 相似文献
95.
96.
Zhang W 《Environmental monitoring and assessment》2007,130(1-3):415-422
Self-organizing neural networks can be used to mimic non-linear systems. The main objective of this study is to make pattern classification and recognition on sampling information using two self-organizing neural network models. Invertebrate functional groups sampled in the irrigated rice field were classified and recognized using one-dimensional self-organizing map and self-organizing competitive learning neural networks. Comparisons between neural network models, distance (similarity) measures, and number of neurons were conducted. The results showed that self-organizing map and self-organizing competitive learning neural network models were effective in pattern classification and recognition of sampling information. Overall the performance of one-dimensional self-organizing map neural network was better than self-organizing competitive learning neural network. The number of neurons could determine the number of classes in the classification. Different neural network models with various distance (similarity) measures yielded similar classifications. Some differences, dependent upon the specific network structure, would be found. The pattern of an unrecognized functional group was recognized with the self-organizing neural network. A relative consistent classification indicated that the following invertebrate functional groups, terrestrial blood sucker; terrestrial flyer; tourist (nonpredatory species with no known functional role other than as prey in ecosystem); gall former; collector (gather, deposit feeder); predator and parasitoid; leaf miner; idiobiont (acarine ectoparasitoid), were classified into the same group, and the following invertebrate functional groups, external plant feeder; terrestrial crawler, walker, jumper or hunter; neustonic (water surface) swimmer (semi-aquatic), were classified into another group. It was concluded that reliable conclusions could be drawn from comparisons of different neural network models that use different distance (similarity) measures. Results with the larger consistency will be more reliable. 相似文献
97.
研究了压力式接触氧化法的脱氮性能,分析了容积负荷、溶解氧和停留时间等因素对反应器脱氮效果的影响.研究表明,压力式接触氧化法具有明显的同步硝化反硝化现象,当HRT=1.8 h时,DO高达5.4 mg/L,可获得90%以上的反硝化率.当HRT=1.8 h,溶解氧4~5 mg/L,容积负荷为10~12 kg COD/(m3·d)时,氨氮去除率80%左右,总氮去除率达70%~80%. 相似文献
98.
99.
Hai Zhao Dexiang Zhang Fangfang Wang Tingting Wu Jinsheng Gao 《Process Safety and Environmental Protection》2008,86(6):448-454
Fe–Mn oxide and Ce-doped Fe–Mn oxide sorbents were studied on the structural and desulfurization behavior in COS removal from syngas. The effects of cerium oxide on the Fe–Mn oxides have been investigated by XRD, BET, TPR, XPS and TEM methods. Analysis data show that the Ce-doped sorbent has larger specific surface area and better particles’ dispersion compared with non-modified Fe–Mn sorbent. The addition of Ce improves the reduction performance of Fe–Mn species. The desulfurization experiments show that the desulfurization activity of sorbent can be increased because of the promotion of the structural and redox properties by ceria doped. The Ce-doped sorbent can reduce COS from 15,000 ppmv to less than 0.1 ppmv at 325 °C and a space velocity of 1000 h−1. 相似文献
100.
利用透射电子显微镜观察分析白腐真菌(黄孢原毛平革菌)在处理染料废水活性艳红X-3B过程中,染料和盐度对黄孢原毛平革菌的细胞结构产生的毒性作用.结果表明:活性艳红X-3B染料对黄孢原毛平革菌产生生物毒性作用,且随着染料浓度的增加,细胞受损伤程度不断加深.加入100 mg/L的染料活性艳红X-3B后,黄孢原毛平革菌菌丝细胞形态发生变化,出现质壁分离现象;染料浓度进一步加大,菌丝细胞超微结构受到损伤逐渐严重.染料废水中的盐度对黄孢原毛平革菌细胞也会造成损伤,且损伤程度随盐度增大而增大.NaCl浓度为3 g/L时,菌丝细胞发生质壁分离;而当NaCl加入量高于8 g/L时,细胞膜受损,线粒体、细胞核呈现空泡化,表现为受到不可逆的损伤.染料和盐双因子对黄孢原毛平革菌细胞的损伤效应表现为其损伤程度与单因子作用一致,且染料的影响作用占主导. 相似文献