The impact of implementation of the requirements of Standard No. OHSAS 18001:2007 to reduce the number of injuries at work and financial costs in the Republic of Croatia

This article contains the results of research into the impact of implementation of the requirements mentioned in Standard No. OHSAS 18001:2007 to reduce the number of injuries at work and the financial costs incurred in this way. The study was conducted on a determined sample by a written questionnaire survey method in the Republic of Croatia. The objective of the empirical research is to determine the impact of implementation of the requirements of Standard No. OHSAS 18001:2007 to reduce the number of injuries at work and financial costs in Croatia in business organizations that implement these requirements. To provide a broader picture, the research included the collection and analysis of data on the impact of the Standard No. OHSAS 18001:2007 on accidents and fatalities at work. Research findings are based on the analysis of performed statistical data where correlation and regression analysis has been applied.     

Resource availability,planning rigidity and Realpolitik in Lithuanian forest utilization

As tensions among diverse forest‐use interests in Lithuania are on the rise, this study examines the actual resource availability, the underlying planning approaches and the pertinent policy arena. Two 5‐year cycles of sampling‐based forest inventory provide accurate data showing that the overall timber harvest/increment ratio (or utilization intensity) is 61%. Utilization intensity is similar in state and private forests. It could potentially be raised to 70‐80%, with due account for environmental values. Such an increase is inhibited by rigid routines of forest management planning, involving inflexible rotation ages and cutting norms. Age‐class analysis indicates that the current planning practice counters its underlying aim of achieving a long‐term even flow of timber. According to a survey of key forest stakeholders, those who directly benefit from forest utilization have a weak position in the policy arena, the dominant powers being vested in the national forestry authorities. State forest enterprises have to follow restrictive plans from above, private forest owners are constrained by stern regulations and suffer from the bad image caused by the persistent myth of overuse in private forests. More rational management of Lithuanian forests is hardly possible without major shifts in the institutional set‐up accompanied by transformation of the professional ideology.     

Multiple kinetic Langmuir modeling to predict the environmental behaviour of As(v) in soils

A soil with a relatively high Fe content (2.82% [w/w]) was loaded for up to one year with As(v) by equilibrating it with a solution containing 1000 mg l(-1) As(v) at a soil mass-to-solution ratio of 0.1 kg l(-1). The incorporation of As(v) into the soil and its distribution over the soil phases were monitored by sampling at strategic time intervals using an operationally defined five-step sequential extraction procedure (Wenzel et al., Anal. Chim. Acta, 2001, 436, 309) and subsequent As measurement. A multiple kinetic Langmuir model was developed to retrieve the dynamic parameters (adsorption and desorption rate constants, capacities and Langmuir equilibrium constants) for each of the soil phases by numerical fitting of the experimental adsorption data to the model. Under the equilibration conditions used the adsorption rate constants for all five operationally defined soil phases were very similar but the desorption rate constants decreased by a factor of ca. 150 from soil phase 1 (non-specifically sorbed As) to 5 (residual phases). This implies that As(v) incorporation "deeper" into the soil leads to stronger binding which is associated with the Langmuir equilibrium constants (adsorption rate constants/desorption rate constants). Equilibration of the soil with As(v) was complete in ca. 10 days with As(v) predominantly bound to soil phase 2 (specifically sorbed As) and soil phase 3 (amorphous and poorly crystalline hydrous oxides). X-Ray absorption spectroscopy techniques revealed that these binding characteristics may be related to adsorption of As(v) on Si- and/or Al-containing structures and natural hydrous iron oxide (HFO) surface sites, respectively. Since the model is independent of the initial As(v) concentration in the solution and the soil mass-to-solution ratio, the behaviour of the thus characterized soil-As(v) system can be predicted for a range of conditions. Simulations showed that in an accidental As(v) spill the soil studied would actively scavenge As(v) by instantaneous adsorption onto all soil phases followed by redistribution of As(v) from weaker binding sites to stronger ones over time.     

Modelling of a Capillary Rise Height of Biochar by Modified Lucas–Washburn Equation

Environmental Modeling & Assessment - Lucas–Washburn equation is a fundamental expression which is used to describe capillary rise in porous materials according to average pore radius,...     

How do larvae attach to a solid in a laminar flow?

A hydrodynamic model explaining the mechanism of contact of marine larvae in vertical flows is presented. Two hydrodynamic factors—flow vorticity and larval self-propulsion—are the key components in the mathematical model. It is shown that flow vorticity causes a larva to rotate and change the direction of self-thrust, thus leading to its migration across the mean flow. The latter motion is of an oscillatory nature. Contact will be enabled only for sufficiently large amplitudes of oscillations. Simple expressions for the probability of initial contact are obtained for two-dimensional Couette and Poiseuille flows. The three-dimensional motion of a larva in a tube is studied using the Monte-Carlo simulations. It is shown that contact probability depends mainly on the ratio of the characteristic flow velocity and the larva’s swimming speed. The theoretical results compare favorably with available experimental data. Possible applications of the method and results presented here to the classical problem of larval attachment to bodies of general geometry are briefly discussed in the concluding section.     

Simulating soil organic matter with CQESTR (v. 2.0): Model description and validation against long-term experiments across North America

Soil carbon (C) models are important tools for examining complex interactions between climate, crop and soil management practices, and to evaluate the long-term effects of management practices on C-storage potential in soils. CQESTR is a process-based carbon balance model that relates crop residue additions and crop and soil management to soil organic matter (SOM) accretion or loss. This model was developed for national use in U.S and calibrated initially in the Pacific Northwest. Our objectives were: (i) to revise the model, making it more applicable for wider geographic areas including potential international application, by modifying the thermal effect and incorporating soil texture and drainage effects, and (ii) to recalibrate and validate it for an extended range of soil properties and climate conditions. The current version of CQESTR (v. 2.0) is presented with the algorithms necessary to simulate SOM at field scale. Input data for SOM calculation include crop rotation, aboveground and belowground biomass additions, tillage, weather, and the nitrogen content of crop residues and any organic amendments. The model was validated with long-term data from across North America. Regression analysis of 306 pairs of predicted and measured SOM data under diverse climate, soil texture and drainage classes, and agronomic practices at 13 agricultural sites having a range of SOM (7.3–57.9 g SOM kg⁻¹), resulted in a linear relationship with an r² of 0.95 (P < 0.0001) and a 95% confidence interval of 4.3 g SOM kg⁻¹. Using the same data the version 1.0 of CQESTR had an r² of 0.71 with a 95% confidence interval of 5.5 g SOM kg⁻¹. The model can be used as a tool to predict and evaluate SOM changes from various management practices and offers the potential to estimate C accretion required for C credits.     

The pattern of species turnover resulting from stochastic population dynamics: The model and field data

The model of random population dynamics in a sampling site returns geometric distribution of longevities of continuous presence (=persistence) and Poisson distribution of the presence–absence transitions. This discrete-time stochastic process describes the presence–absence pattern observed in the beetles surveyed 6 years on Mount Carmel, Israel. Homogeneous pools of species mostly on the Families rank, exhibit the predicted by the model patterns. Conformity to an ergodic hypothesis is the criterion of ecological homogeneity. This criterion assumes the equivalence of short-term behavior of entire pool and long-term behavior of any species from this pool. The pool of all 801 species of Order Coleoptera does not match the model. Thus a taxon of an arbitrary rank may not be considered a priory as a unit of ecological study. Determined from field data parameters of the model are biased and magnitude of the bias depends on longevity of the survey. Parameter of distribution depends also on species tolerance, which is the level adaptation of given species to given environment in given time interval. Random process of species turnover may be considered as a game of species to gain their presence against deteriorative fluctuations of environmental conditions.     

Active biomonitoring with wet and dry moss: a case study in an urban area

Active biomonitoring of the air quality in Belgrade, Serbia, was performed using the moss Sphagnum girgensohnii. Moss bags were exposed in parallel with and without irrigation for 3 and 6 months, respectively, at three different sites. Twenty-nine elements were determined in the exposed moss samples by INAA. For all exposure periods, higher uptake in the irrigated moss bags was evident for Al, Cr, Fe, Zn and Sr. Elements such as Cl, K, Rb and Cs were depleted in the moss tissue during the time of exposure. For most of the elements the accumulation after 6 months exceeded that observed after 3 months.     

Spatially explicit modeling of overstory manipulations in young forests: Effects on stand structure and light

Young forests can be manipulated in diverse ways to enhance their ecological values. We used stem maps from two dense, second-growth stands in western Washington and a spatially explicit light model (tRAYci) to simulate effects of five silvicultural manipulations on diameter distribution, species composition, spatial patterning, and light availability. Each treatment removed 30% of the basal area, but differed in how trees were selected for removal. Three primary treatments were thin from below (removing the smallest trees), random thin (removing trees randomly), and gap creation (removing all trees in circles ∼1 tree height in diameter). Two additional treatments combined elements of these approaches: random ecological thin (a mixture of thin from below and random thin) and structured ecological thin (a mixture of thin from below and gap creation).     

Medical geochemistry research in Spišsko-Gemerské rudohorie Mts., Slovakia

This study presents an assessment of the potential impact of geological contamination of the environment on the health of the population in Spišsko-Gemerské rudohorie Mts. (SGR Mts.). The concentration levels of potentially toxic elements (mainly As, Cd, Cu, Hg, Pb, Sb, and Zn) were determined in soils, groundwater, surface water, and stream sediments as well as in the food chain (locally grown vegetables). A medical study included some 30 health indicators for all 98 municipalities of the study area. The As and Sb contents in human fluids and tissues were analyzed in one municipality identified to be at the highest risk. Based on element content, environmental and health risks were calculated for respective municipalities. Out of 98 municipalities 14 were characterized with extremely high environmental risk and 10 were characterized with very high carcinogenic risk from arsenic (groundwater). Extensive statistical analysis of geochemical data (element contents in soils, groundwater, surface water, and stream sediments) and health indicators was performed. Significant correlations between element contents in the geological environment and health indicators, mainly cancer and cardiovascular diseases, were identified. Biological monitoring has confirmed the transfer of elements from the geological environment to human fluids and tissues as well as to the local food chain.