Estimating Nitrogen Loading to Ground Water and Assessing Vulnerability to Nitrate Contamination in a Large Karstic Springs Basin,Florida1

Abstract: A nitrogen (N) mass‐balance budget was developed to assess the sources of N affecting increasing ground‐water nitrate concentrations in the 960‐km² karstic Ichetucknee Springs basin. This budget included direct measurements of N species in rainfall, ground water, and spring waters, along with estimates of N loading from fertilizers, septic tanks, animal wastes, and the land application of treated municipal wastewater and residual solids. Based on a range of N leaching estimates, N loads to ground water ranged from 262,000 to 1.3 million kg/year; and were similar to N export from the basin in spring waters (266,000 kg/year) when 80‐90% N losses were assumed. Fertilizers applied to cropland, lawns, and pine stands contributed about 51% of the estimated total annual N load to ground water in the basin. Other sources contributed the following percentages of total N load to ground water: animal wastes, 27%; septic tanks, 12%; atmospheric deposition, 8%; and the land application of treated wastewater and biosolids, 2%. Due to below normal rainfall (97.3 cm) during the 12‐month rainfall collection period, N inputs from rainfall likely were about 30% lower than estimates for normal annual rainfall (136 cm). Low N‐isotope values for six spring waters (δ¹⁵N‐NO₃ = 3.3 to 6.3‰) and elevated potassium concentrations in ground water and spring waters were consistent with the large N contribution from fertilizers. Given ground‐water residence times on the order of decades for spring waters, possible sinks for excess N inputs to the basin include N storage in the unsaturated zone and parts of the aquifer with relatively sluggish ground‐water movement and denitrification. A geographical‐based model of spatial loading from fertilizers indicated that areas most vulnerable to nitrate contamination were located in closed depressions containing sinkholes and other dissolution features in the southern half of the basin.     

Simultaneous E. coli inactivation and NOM degradation in river water via photo-Fenton process at natural pH in solar CPC reactor. A new way for enhancing solar disinfection of natural water

Bacteria inactivation and natural organic matter oxidation in river water was simultaneously conducted via photo-Fenton reaction at “natural” pH (6.5) containing 0.6 mg L⁻¹ of Fe³⁺ and 10 mg L⁻¹ of H₂O₂. The experiments were carried out by using a solar compound parabolic collector on river water previously filtered by a slow sand filtration system and voluntarily spiked with Escherichia coli. Fifty five percent of 5.3 mg L⁻¹ of dissolved organic carbon was mineralized whereas total disinfection was observed without re-growth after 24 h in the dark.     

Development of a simple, accurate SPME-based method for assay of VOCs in column breakthrough experiments

Solid-phase microextraction (SPME) with gas chromatography is to be used for assay of effluent liquid samples from soil column experiments associated with VOC fate/transport studies. One goal of the fate/transport studies is to develop accurate, highly reproducible column breakthrough curves for 1,2-cis-dichloroethylene (cis-DCE) and trichloroethylene (TCE) to better understand interactions with selected natural solid phases. For SPME, the influences of the sample equilibration time, extraction temperature and the ratio of volume of sample bottle to that of the liquid sample (V(T)/V(w)) are the critical factors that could influence accuracy and precision of the measured results. Equilibrium between the gas phase and liquid phase was attained after 200 min of equilibration time. The temperature must be carefully controlled due to variation of both the Henry's constant (K(h)) and the fibre/gas phase distribution coefficient (K(fg)). K(h) decreases with decreasing temperature while K(fg) increases. Low V(T)/V(w) yields better sensitivity but results in analyte losses and negative bias of the resultant assay. High V(T)/V(w) ratio yields reduced sensitivity but analyte losses were found to be minimal, leading to better accuracy and reproducibility. A fast SPME method was achieved, 5 min for SPME extraction and 3.10 min for GC analysis. A linear calibration function in the gas phase was developed to analyse the breakthrough curve data, linear between a range of 0.9-236 microgl(-1), and a detection limit lower than 5 microgl(-1).     

Tourists‘ and Locals‘ Preferences Toward Ecotourism Development in the Maya Biosphere Reserve,Guatemala

Ecotourism has been identified as a low impact means to provide income generating opportunities that are complementary to nature conservation as well as the welfare of the local population. The Maya Biosphere Reserve in Peten, Guatemala is one of Central America's largest and most isolated protected areas. And although the area is contains a well-visited archeological site, it has not been developed for ecotourism. In this study choice experiments are used to analyze the preferences toward alternative scenarios of ecotourism of two important stakeholder groups: foreign tourists and educated local residents. Results demonstrate that these two populations of have unequal but similar preference orderings, especially toward: improved national park management and the presence of guides for wildlife viewing. These stakeholder groups had different opinions toward paved access roads and the presence of illegal colonists within the protected area. Both populations favored an entrance fee toward the absence of an entrance fee. These preferences were generally consistent across other socioeconomic indicators. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Sustainable Land Use Requires Attention to Ecological Signals

This case study details the difficulties of landscape management, highlighting the challenges inherent in managing natural resources when multiple agencies are involved, when the land users have no incentive for conservation, and when government agencies have too few resources for effective management. Pumping of groundwater from the aquifer of La Costa de Hermosillo in the state of Sonora, Mexico, began in 1945 and developed so quickly that by the late 1950s salinity intrusion from the Gulf of California was occurring in the wells. In the 1970s, the irrigatable land in La Costa peaked at 132,516 ha and the extracted volume of water from the aquifer peaked at around 1.14 billion cubic meters annually. By the 1980s, 105 wells of the total of 498 were contaminated with seawater and, therefore, identified for closure. At present La Costa de Hermosillo still represents 15% of the total harvested land, 16% of the total annual production, and 23% of the gross agricultural production of the state of Sonora. However, there are approximately 80,000 ha of abandoned fields due to salt water intension, lack of water and/or lack of credit available to individual farmers. This unstable situation resulted from the interplay of water management policies and practices, and farm-land policies and practices. While government agencies have been able to enforce better water use for agricultural production, there remains a significant area that requires restoration from its degraded state. For this piece of the ecosystem management puzzle, government agencies have thus far been unable to affect a solution.     

Use of life cycle assessment as decision-support tool for water reuse and handling of residues at a Danish industrial laundry.

This analysis presents the results of a life cycle assessment (LCA) carried out on six alternative options for the recycling of water at a Danish industrial laundry for workwear. The study focuses on the handling and disposal of the wet residues generated when wastewater is treated for recycling, and in accounting for long-term potential toxicity impacts. The analysed options are a combination of two water-upgrading technologies: biofilter and ultrafiltration, and three residue disposal alternatives: biogas followed by incineration of sludge at local wastewater treatment plant, thermal vitrification treatment for production of vitrified sand, and mineralization in a sludge bed. It is concluded from the results that with the current Danish environmental policy priorities, the environmental impacts of highest priority are the toxicity effects derived from the presence of heavy metals in the residues. Heavy metals originate from the dirt in the workwear that is washed in the laundry. It is further concluded that the studied water treatment technologies satisfy both the need of clean water for recycling and simultaneously help controlling a safe disposal of pollutants by concentration of the residues. The results of the study also confirm the potential of LCA as a decision-support tool for assisting water recycling initiatives and for residue handling management. The handling of residues has been identified as a stage of the water recycling strategy that bears important environmental impacts. This holistic perspective provided by LCA can be used as input for the definition of environmental management strategies at an industrial laundry, and the prioritization of investments to the environmental profile of laundry processes. In this case-study, the results of the LCA are made operational by, for example, selecting the water treatment technology which is associated wih a safe disposal of the wet residue. It is important to bear in mind that such prioritization depends on national boundary conditions. In the case study analysed, the boundary conditions steer the weighing of the environmental impacts, following the current Danish environmental policy priorities.     

FLOODPLAIN STORAGE AND LAND USE ANALYSIS AT THE WOODLANDS,TEXAS1

ABSTRACT: The Woodlands, a totally planned community north of Houston, Texas, was studied in detail in an effort to develop a master drainage plan which minimizes adverse impact on the 100-year floodplain. A total of 40 HEC-1 and HEC-2 computer runs were made to evaluate various development, channelization, and reservoir storage options.     

Ecological Impacts of Chile's Neoliberal Policies, with Special Emphasis on Agroecosystems

Although Chile has been touted for developing a broad market liberalization and opening to the international economy, evidence is emerging that such neoliberal economic policies are dramatically impacting biodiversity and the natural resource base. This paper examines the evidence on the plundering of forestry and fishery resources and the damming and pollution of aquatic ecosystems. Although it may be argued that economic liberalization policies have been effective in reallocating agricultural resources toward more competitive activities, the ecological toll imposed by the expansion of export-led modern agriculture has been heavy. An effective agricultural development strategy in Chile should confront such ecological costs and should promote alternatives to high input agriculture.     

Reducing public participation in a formal procedure: Limits of public meetings concerning the installation of the dams of the Madeira River (Brazilian Amazon)

This article examines and discusses problems faced by proposals to increase participation by members of the public in the public debate process related to environmental policies. The analysis is based on an examination of the processes followed to develop several public meetings, which were ostensibly aimed at democratizing the process of implementing hydroelectric installations in the Madeira River in the Brazilian Amazon at the beginning of the twenty‐first century. The analysis concluded that the invitation to the public to participate in discussions regarding the construction of the dams was a mere formality. Not only did members of the public not have access to information that could have helped them understand the real social and environmental impacts of this large‐scale economic development project, but the public was restricted from interfering in its construction. As a consequence, the region is today dealing with a number of difficulties which could have been avoided if the voice of the community had been heard in the public meetings.     

Modeling and Measurement of Structural Changes at a Landscape Scale in Dryland Areas

We present a technique to quantify and model the intensity of structural changes produced by management of dry grazing lands at a landscape scale. The technique is illustrated with the analysis of digitized black–white (b/w) imagery and an application to the study of changes induced by grazing gradients. Structural changes in patchy vegetation canopies were studied in the Patagonian Monte (Chubut, Argentina) at two resolution scales by means of linear transects in the field (50 m) and others drawn on aerial b/w photographs (2–5 km) of grazed paddocks. Spatial series of plant cover values along transects in the field and on photographs were analyzed with standard techniques of spectral analyses, including auto-correlation spectra and Fourier transforms. In order to test the internal consistency of the techniques used, synthetic plant canopies with patches of varying cover and size were generated by means of a stochastic model of plant growth under different stocking rates or after varying periods of recovery. The behavior of the simulation model is consistent with the observed dynamics of plant canopies in semiarid environments. There is a consistent relation between the number and geometric properties of plant patches (patch number, patch size, patch connectivity) and the signal/noise ratios of the Fourier decomposition describing plant density data. Signal/noise ratios corresponding to plant cover data in paddocks with different grazing treatment are consistent with the assumptions derived from modeled canopies, as well as those estimated from optical density of b/w aerial photographs of paddocks. We tested the hypotheses that patch arrangements as quantified by the signal/noise ratios vary in accordance with grazing gradients in paddocks with a permanent corner-located watering point. The use of digitized b/w images allows inspecting permanent changes over time periods when other types of images were not yet available.