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排序方式: 共有358条查询结果,搜索用时 15 毫秒
81.
82.
83.
Carlos Costa Javier Rodríguez M. Carmen Márquez 《Environmental Modeling and Assessment》2009,14(6):739-747
A simplified dynamic model for the activated sludge process with high-strength wastewaters is presented. The model is based
on activated sludge models and predicts effluent chemical oxygen demand concentration using only four parameters. Experimental
data for testing the model were obtained in an activated sludge plant using flax retting wastewater. The proposal of the model
is described: mass balance to the system, selection of variables and behaviour of the theoretical values versus experimental
results. 相似文献
84.
Sue Ellen C. Bottrel Camila C. Amorim Mônica M.D. Leão Elizângela P. Costa Igor A. Lacerda 《Journal of environmental science and health. Part. B》2013,48(4):263-270
In this study, photocatalytic (photo-Fenton and H2O2/UV) and dark Fenton processes were used to remove ethylenethiourea (ETU) from water. The experiments were conducted in a photo-reactor with an 80 W mercury vapor lamp. The mineralization of ETU was determined by total organic carbon analysis, and ETU degradation was qualitatively monitored by the reduction of UV absorbance at 232 nm. A higher mineralization efficiency was obtained by using the photo-peroxidation process (UV/H2O2). Approximately 77% of ETU was mineralized within 120 min of the reaction using [H2O2]0 = 400 mg L?1. The photo-Fenton process mineralized 70% of the ETU with [H2O2]0 = 800 mg L?1 and [Fe2+] = 400 mg L?1, and there is evidence that hydrogen peroxide was the limiting reagent in the reaction because it was rapidly consumed. Moreover, increasing the concentration of H2O2 from 800 mg L?1 to 1200 mg L?1 did not enhance the degradation of ETU. Kinetics studies revealed that the pseudo-second-order model best fit the experimental conditions. The k values for the UV/H2O2 and photo-Fenton processes were determined to be 6.2 × 10?4 mg L?1 min?1 and 7.7 × 10?4 mg L?1 min?1, respectively. The mineralization of ETU in the absence of hydrogen peroxide has led to the conclusion that ETU transformation products are susceptible to photolysis by UV light. These are promising results for further research. The processes that were investigated can be used to remove pesticide metabolites from drinking water sources and wastewater in developing countries. 相似文献
85.
Evaluation of the effectiveness of phosphate treatment for the remediation of mine waste soils contaminated with Cd, Cu, Pb, and Zn 总被引:14,自引:0,他引:14
The effectiveness of phosphate treatment for Cd, Cu, Pb, and Zn immobilization in mine waste soils was examined using batch conditions. Application of synthetic hydroxyapatite (HA) and natural phosphate rock (FAP) effectively reduced the heavy metal water solubility generally by about 84-99%. The results showed that HA was slightly superior to FAP for immobilizing heavy metals. The possible mechanisms for heavy metal immobilization in the soil involve both surface complexation of the metal ions on the phosphate grains and partial dissolution of the phosphate amendments and precipitation of heavy metal-containing phosphates. HA and FAP could significantly reduce Cd, Cu, Pb, and Zn availability in terms of water solubility in contaminated soils while minimizing soil acidification and potential risk of eutrophication associated with the application of highly soluble phosphate sources. 相似文献
86.
Deng Y Besse-Hoggan P Husson P Sancelme M Delort AM Stepnowski P Paszkiewicz M Gołębiowski M Costa Gomes MF 《Chemosphere》2012,89(3):327-333
Several physico-chemical properties relevant to determine the environmental impact of ionic liquids - aqueous solubility, octanol/water partition coefficient, chromatographically derived lipophilicity and infinite dilution diffusion coefficients in water - were measured in ionic liquids based on pyridinium, ammonium and pyrrolidinium cations with bis(trifluoromethylsulfonyl)imide anions. The influence of the presence of hydroxyl or ester groups in the physico-chemical properties of these liquids was checked. It appeared that the presence of functional oxygenated moieties reduces the lipophilicity of ionic liquids and so decreases the risk of bioaccumulation in environment. 相似文献
87.
Cristani M Naccari C Nostro A Pizzimenti A Trombetta D Pizzimenti F 《Environmental science and pollution research international》2012,19(1):161-168
Background, aim and scope
Metal pollution is a serious problem for environmental safety and programmes of monitoring and bioremediation are needed. Among the processes of bioremediation, the use of microbes to remove and degrade contaminants is considered a biotechnological approach to clean up polluted environments. 相似文献88.
Pires-Marques Élia Chaves Cristina Pinto Lígia M. Costa 《Environment, Development and Sustainability》2021,23(8):11382-11405
Environment, Development and Sustainability - Even though ecosystem services have a significant contribution to human well-being, their value is not always recognized. Despite difficulties, the... 相似文献
89.
Ramsdorf WA Ferraro MV Oliveira-Ribeiro CA Costa JR Cestari MM 《Environmental monitoring and assessment》2009,158(1-4):77-85
Different genetic biomarkers have been used to evaluate the pollution effects of mutagenic agents such as metals and also a great variety of chemicals delivered on the environment by human activities. This way, the aim of the present report was to evaluate the effects of inorganic lead in fishes through the frequency of piscine micronuclei and nuclear morphological alterations in peripheral cells, chromosomal aberration frequency and comet assays in blood and kidney cells. Specimens of Hoplias malabaricus received different doses of lead by intra-peritoneal injections at time of 96 h. There was not a significant difference between control and treated groups for the piscine micronucleus and chromosomal aberration assays. In the comet assays there was a significant difference between control and contaminated groups. However, a significant difference between the applied doses was not observed. The results obtained with the comet assays also show that blood presented a higher sensibility than the kidney tissue, possibly due to the acute contamination. Although the results showed the genotoxic potential of lead at the 21 and 63 microg Pb(2 + )/g doses for both tissues, the lowest dose is considered more appropriate for future bioassays. 相似文献
90.
da Costa AO Silva PF Sabará MG da Costa EF 《Environmental monitoring and assessment》2009,155(1-4):527-538
This paper reports the using of neural networks for water quality analysis in a tropical urban stream before (2002) and after sewerage building and the completion of point-source control-based sanitation program (2003). Mathematical modeling divided water quality data in two categories: (a) input of some in situ water quality variables (temperature, pH, O2 concentration, O2 saturation and electrical conductivity) and (b) water chemical composition (N-NO2(-); N-NO3(-); N-NH4(+) Total-N; P-PO4(3-); K+; Ca2+; Mg+2; Cu2+; Zn2+ and Fe+3) as the output from tested models. Stream water data come from fortnightly sampling in five points along the Ipanema stream (Southeast Brazil, Minas Gerais state) plus two points downstream and upstream Ipanema discharge into Doce River. Once the best models are consistent with variables behavior we suggest that neural networking shows potential as a methodology to enhance guidelines for urban streams restoration, conservation and management. 相似文献