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101.
102.
Photocatalytic ozonation of phenol and oxalic acid (OA) was conducted with a Ag^+/TiO2 catalyst and different pathways were found for the degradation of different compounds. Ag^+ greatly promoted the photocatalytic degradation of contaminants due to its role as an electron scavenger. It also accelerated the removal rate of OA in ozonation and the simultaneous process for its complex reaction with oxalate. Phenol could be degraded both in direct ozonation and photolysis, but the TOC removal rates were much higher in the simultaneous processes due to the oxidation of hydroxyl radicals resulting from synergetic effects. The sequence of photo-illumination and ozone exposure in the combined process showed quite different effects in phenol degradation and TOC removal. The synergetic effects in different combined processes were found to be highly related to the properties of the target pollutants. The color change of the solution and TEM result confirmed that Ag+ was easily reduced and deposited on the surface of Tit2 under photo-illumination, and dissolved again into solution in the presence of ozone. This simple cycle of enrichment and distribution of Ag^+ can greatly benefit the design of advanced oxidation processes, in which the sequences of ozone and photo-illumination can be varied according to the needs for catalyst recycling and the different properties of pollutants. 相似文献
103.
Experimental study on filtration and continuous regeneration of a particulate filter system for heavy-duty diesel engines 总被引:1,自引:0,他引:1
This study investigated the filtration and continuous regeneration of a particulate filter system on an engine test bench, consisting of a diesel oxidation catalyst(DOC) and a catalyzed diesel particulate filter(CDPF). Both the DOC and the CDPF led to a high conversion of NO to NO2 for continuous regeneration. The filtration efficiency on solid particle number(SPN) was close to100%. The post-CDPF particles were mainly in accumulation mode. The downstream SPN was sensitively influenced by the variation of the soot loading. This phenomenon provides a method for determining the balance point temperature by measuring the trend of SPN concentration. 相似文献
104.
Taste and odor (T/O) in drinking water often cause consumer complaints and are thus regulated in many countries. However, people in different regions may exhibit different sensitivities toward WO. This study proposed a method to determine the regional drinking water odorant regulation goals (ORGs) based on the odor sensitivity distribution of the local population. The distribution of odor sensitivity to 2-methylisobomeol (2-MIB) by the local population in Beijing, China was revealed by using a normal distribution function/model to describe the odor complaint response to a 2-MIB episode in 2005, and a 2-MIB concentration of 12.9 ng/L and FPA (flavor profile analysis) intensity of 2.5 was found to be the critical point to cause odor complaints. Thus the Beijing ORG for 2-MIB was determined to be 12.9 ng/L. Based on the assumption that the local FPA panel can represent the local population in terms of sensitivity to odor, and that the critical FPA intensity causing odor complaints was 2.5, this study tried to determine the ORGs for seven other cities of China by performing FPA tests using an FPA panel from the corresponding city. ORG values between 12.9 and 31.6 ng/L were determined, showing that a unified ORG may not be suitable for drinking water odor regulations. This study presents a novel approach for setting drinking water odor regulations. 相似文献
105.
106.
四川省西充河为严重污染河流,选取溶解氧(DO)、氨氮(NH+4-N)、五日生化需氧量(BOD5)、总氮(TN)、总磷(TP)5项指标年平均值,采用综合水质标识指数法,研究了西充河近10年水质状况随时间变化趋势及水污染特征。2003年至2010年水质级别为劣V类,2011年和2012年水质级别为Ⅳ类,水质标识指数Iwq从2003年的12.459逐渐降低到2012年的4.431。西充河近10年水质状况整体呈好转趋势,但未达到国家规定的Ⅲ级水质标准,水质标识指数Iwq结果表明该好转的速度较慢,西充河水质状况有较大的上升潜力和空间。总氮(TN)和氨氮(NH+4-N)为河流主要污染物,为了达到国家Ⅲ级水质标准,西充河的治理已刻不容缓。 相似文献
107.
Ionic composition of TSP and PM2.5 during dust storms and air pollution episodes at Xi'an,China 总被引:1,自引:0,他引:1
Zhenxing Shen Junji Cao Richard Arimoto Zhiwei Han Renjian Zhang Yuemei Han Suixin Liu Tomoaki Okuda Shunsuke Nakao Shigeru Tanaka 《Atmospheric environment (Oxford, England : 1994)》2009,43(18):2911-2918
TSP and PM2.5 samples were collected at Xi'an, China during dust storms (DSs) and several types of pollution events, including haze, biomass burning, and firework displays. Aerosol mass concentrations were up to 2 times higher during the particulate matter (PM) events than on normal days (NDs), and all types of PM led to decreased visibility. Water-soluble ions (Na+, NH4+, K+, Mg2+, Ca2+, F?, Cl?, NO3?, and SO42?). were major aerosol components during the pollution episodes, but their concentrations were lower during DSs. NH4+, K+, F?, Cl?, NO3?, and SO42? were more abundant in PM2.5 than TSP but the opposite was true for Mg2+ and Ca2+. PM collected on hazy days was enriched with secondary species (NH4+, NO3?, and SO42) while PM from straw combustion showed high K+ and Cl?. Firework displays caused increases in K+ and also enrichments of NO3? relative to SO42?. During DSs, the concentrations of secondary aerosol components were low, but Ca2+ was abundant. Ion balance calculations indicate that PM from haze and straw combustion was acidic while the DSs samples were alkaline and the fireworks' PM was close to neutral. Ion ratios (SO42?/K+, NO3?/SO42?, and Cl?/K+) proved effective as indicators for different pollution episodes. 相似文献
108.
Lifeng Cao Weihua Sun Yuting Zhang Shimin Feng Jinyun Dong Yongming Zhang Bruce E. Rittmann 《Frontiers of Environmental Science & Engineering》2017,11(6):14
It is common that 2,4,6-trichlorophenol (TCP) coexists with nitrate or nitrite in industrial wastewaters. In this work, simultaneous reductive dechlorination of TCP and denitrification of nitrate or nitrite competed for electron donor, which led to their mutual inhibition. All inhibitions could be relieved to a certain degree by augmenting an organic electron donor, but the impact of the added electron donor was strongest for TCP. For simultaneous reduction of TCP together with nitrate, TCP’s removal rate value increased 75% and 150%, respectively, when added glucose was increased from 0.4 mmol?L–1 to 0.5 mmol?L–1 and to 0.76 mmol?L–1. For comparison, the removal rate for nitrate increased by only 25% and 114% for the same added glucose. The relationship between their initial biodegradation rates versus their initial concentrations could be represented well with the Monod model, which quantified their half-maximum-rate concentration (K S value), and K S values for TCP, nitrate, and nitrite were larger with simultaneous reduction than independent reduction. The increases in K S are further evidence that competition for the electron donor led to mutual inhibition. For bioremediation of wastewater containing TCP and oxidized nitrogen, both reduction reactions should proceed more rapidly if the oxidized nitrogen is nitrite instead of nitrate and if readily biodegradable electron acceptor is augmented. 相似文献
109.
Cheng-fang Li Zhi-kui Kou Jin-hua Yang Ming-li Cai Jin-ping Wang Cou-gui Cao 《Atmospheric environment (Oxford, England : 1994)》2010,44(23):2696-2704
Agricultural practices affect the production and emission of carbon dioxide (CO2) from paddy soils. It is crucial to understand the effects of tillage and N fertilization on soil CO2 flux and its influencing factors for a better comprehension of carbon dynamics in subtropical paddy ecosystems. A 2-yr field study was conducted to assess the effects of tillage (conventional tillage [CT] and no-tillage [NT]) and N fertilization (0 and 210 kg N ha?1) on soil CO2 fluxes during the 2008 and 2009 rice growing seasons in central China. Treatments were established following a split-plot design of a randomized complete block with tillage practices as the main plot and N fertilizer level as the split-plot treatment. The soil CO2 fluxes were measured 24 times in 2008 and 17 times in 2009. N fertilization did not affect soil CO2 emissions while tillage affected soil CO2 emissions, where NT had similar soil CO2 emissions to CT in 2008, but in 2009, NT significantly increased soil CO2 emissions. Cumulative CO2 emissions were 2079–2245 kg CO2–C ha?1 from NT treatments, and 2084–2141 kg CO2–C ha?1 from CT treatments in 2008, and were 1257–1401 kg CO2–C ha?1 from NT treatments, and 1003–1034 kg CO2–C ha?1 from CT treatments in 2009, respectively. Cumulative CO2 emissions were significantly related to aboveground biomass and soil organic C. Before drainage of paddy fields, soil CO2 fluxes were significantly related to soil temperature with correlation coefficients (R) of 0.67–0.87 in 2008 and 0.69–0.85 in 2009; moreover, the Q10 values ranged from 1.28 to 1.55 and from 2.10 to 5.21 in 2009, respectively. Our results suggested that NT rice production system appeared to be ineffective in decreasing carbon emission, which suggested that CO2 emissions from integrated rice-based system should be taken into account to assess effects of tillage. 相似文献
110.
对杭州市环保系统的人才总量、学历结构、专业结构、职称结构和年龄结构等方面作了较详细的分析;针对杭州市环保系统存在的人才总量不足、结构分布不合理和高层次人才匮乏等问题,提出了引进高层次人才、加强教育培训、壮大基层队伍等对策。 相似文献