全文获取类型
收费全文 | 101篇 |
免费 | 14篇 |
国内免费 | 82篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 7篇 |
环保管理 | 4篇 |
综合类 | 104篇 |
基础理论 | 10篇 |
污染及防治 | 44篇 |
评价与监测 | 14篇 |
社会与环境 | 2篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 9篇 |
2020年 | 2篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2015年 | 10篇 |
2014年 | 8篇 |
2013年 | 8篇 |
2012年 | 11篇 |
2011年 | 15篇 |
2010年 | 3篇 |
2009年 | 11篇 |
2008年 | 10篇 |
2007年 | 11篇 |
2006年 | 10篇 |
2005年 | 12篇 |
2004年 | 9篇 |
2003年 | 15篇 |
2002年 | 8篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1994年 | 3篇 |
1990年 | 1篇 |
排序方式: 共有197条查询结果,搜索用时 31 毫秒
41.
OH自由基降解二英OCDD的反应机理及动力学研究 总被引:1,自引:0,他引:1
采用量子化学计算研究了OH自由基降解八氯代二苯并对-二英(OCDD)的微观反应机理,计算分析了微观反应进程,结果表明该反应存在两条途径:①α-氯取代:1,4,6,9位置氯取代,该路径反应活化能较高,反应难以进行,并以中间产物积聚,无法使OCDD的毒性消失;②β-氯取代:2,3,7,8位置氯取代,该路径的反应能相对较低,且能使OCDD的毒性消失,是有效降解OCDD的主要途径.结合过渡态理论,计算获得动力学参数:反应活化能为8.32 kJ·mol-1(B3LYP/6-311G++(d,g)//B3LYP/6-31G(d)),阿仑尼乌斯表达式为k=1.29×1014exp(-1049.6/T)(cm3·mole-1·s-1).这与文献实验结果取得了很好的吻合,说明本文对OH自由基降解OCDD的反应机理及动力学研究是合理且可靠的.本文的计算结果可为催化氧化降解二英的进一步研究提供理论参考. 相似文献
42.
Li Ying Cen Hongyi Chiu Yung-ho Lin Tai-Yu 《Journal of Material Cycles and Waste Management》2021,23(3):922-936
Journal of Material Cycles and Waste Management - As resident awareness of environmental issues has grown, waste disposal has become an important part of urban environmental governance. Most... 相似文献
43.
Qinfeng Guo Xiaoyu Cen Ruiyan Song Michael L. McKinney Deli Wang 《Conservation biology》2021,35(2):711-721
Non-native species have invaded most parts of the world, and the invasion process is expected to continue and accelerate. Because many invading non-native species are likely to become permanent inhabitants, future consideration of species-area relationships (SARs) should account for non-native species, either separately or jointly with native species. If non-native species occupy unused niches and space in invaded areas and extinction rate of native species remains low (especially for plants), the resultant SARs (with both native and non-native species) will likely be stronger. We used published and newly compiled data (35 data sets worldwide) to examine how species invasions affect SARs across selected taxonomic groups and diverse ecosystems around the world. We first examined the SARs for native, non-native, and all species. We then investigated with linear regression analyses and paired or unpaired t tests how degree of invasion (proportion of non-native species) affected postinvasion SARs. Postinvasion SARs for all species (native plus non-native) became significantly stronger as degree of invasion increased (r2 = 0.31, p = 0.0006), thus, reshaping SARs worldwide. Overall, native species still showed stronger and less variable SARs. Also, slopes for native species were steeper than for non-native species (0.298 vs. 0.153). There were some differences among non-native taxonomic groups in filling new niches (especially for birds) and between islands and mainland ecosystems. We also found evidence that invasions may increase equilibrial diversity. Study of such changing species–area curves may help determine the probability of future invasions and have practical implications for conservation. 相似文献
44.
45.
46.
47.
48.
49.
城市生活垃圾典型组分的热解动力学模型研究 总被引:26,自引:1,他引:26
对城市生活垃圾中的典型组分进行热重特性试验,根据热失重曲线得出了反应力学参数及反应速率控制方程,进而提出了一个通用的反应速率函数式,提出热解指数这个指标来表征垃圾的热解特性。结果表明:1.垃圾组分中,塑料、橡胶、植物类厨余热解符合三段模型,其余组分符合二段热解模型,在不同的温度范围内,热解的反应机理是不同的,且反应动力学参数也不相同。2.同一种组分,影响其反应速率的主要因素是反应动力学常数,升温速 相似文献
50.
Kuang C Neumann T Norra S Stüben D 《Environmental science and pollution research international》2004,11(2):73-83
BACKGROUND: More than 10 million people are currently living in Beijing. This city faces severe anthropogenic air pollution caused by an intense vehicle increase (11% per year in China), coal combusting power plants, heavy industry, huge numbers of household and restaurant cookers, and domestic heating stoves. Additionally, each year dust storms are carrying particulate matter from the deserts of Gobi and Takla Makan towards Beijing, especially in spring. Other geogenic sources of particulate matter which contribute to the air pollution are bare soils, coal heaps and construction sites occurring in and around Beijing. Streets function as receptor surfaces for atmospheric dusts. Thus, street sediments consist of particles of different chemical compositions from many different sources, such as traffic, road side soils and industry. METHODS: Distributions and concentrations of various chemical elements in street sediments were investigated along a rural-urban transect in Beijing, China. Chemical elements were determined with X-ray fluorescence analysis. Factor analysis was used to extract most important element sources contributing to particulate pollution along a main arterial route of the Chinese capital. RESULTS AND DISCUSSION: The statistical evaluation of the data by factor analysis identifies three main anthropogenic sources responsible for the contamination of Beijing street sediments. The first source is a steel factory in the western part of Beijing. From this source, Mn, Fe, and Ti were emitted into the atmosphere through chimneys and by wind from coal heaps used as the primary energy source for the factory. The second source is a combination of traffic, domestic heating and some small factories in the center of Beijing discharging Cu, Pb, Zn and Sn. Calcium and Cr characterize a third anthropogenic element source of construction materials such as concrete and mortar. Beside the anthropogenic contamination, some elements like Y, Zr, Nb, Ce, and Rb are mainly derived from natural soils and from the deserts. This is supported by mineral phase analysis, which showed a clear imprint of material in road dusts coming from the West-China deserts. CONCLUSIONS: Our results clearly show that the chemical composition of urban road dusts can be used to identify distinct sources responsible for their contamination. The study demonstrates that the chemistry of road dusts is an important monitor to assess the contamination in the urban environment. Chemical composition of street sediments in Beijing comprises the information of different sources of atmospheric particles. RECOMMENDATIONS AND OUTLOOK: This study is only a small contribution to the understanding of substance fluxes related to Beijing's dust. More effort is required to assess Beijing's dust fluxes, since the dust harms the living quality of the inhabitants. Especially the measurable superimposing of long scale transported dust from dry regions with the anthropogenic polluted urban dust makes investigations of Beijing's dust scientifically valuable. 相似文献