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101.
Size distribution, characteristics and sources of heavy metals in haze episod in Beijing 总被引:3,自引:0,他引:3
Size segragated samples were collected during high polluted winter haze days in 2006 in Beijing, China. Twenty nine elements and 9 water soluble ions were determined. Heavy metals of Zn, Pb, Mn, Cu, As, Cr, Ni, V and Cd were deeply studied considering their toxic effect on human being. Among these heavy metals, the levels of Mn, As and Cd exceeded the reference values of National Ambient Air Quality Standard (GB3095-2012) and guidelines of World Health Organization. By estimation, high percentage of atmospheric heavy metals in PM2.5 indicates it is an effective way to control atmospheric heavy metals by PM2.5 controlling. Pb, Cd, and Zn show mostly in accumulation mode, V, Mn and Cu exist mostly in both coarse and accumulation modes, and Ni and Cr exist in all of the three modes. Considering the health effect, the breakthrough rates of atmospheric heavy metals into pulmonary alveoli are: Pb (62.1%) 〉 As (58.1%) 〉 Cd (57.9%) 〉 Zn (57.7%) 〉 Cu (55.8%) 〉 Ni (53.5%) 〉 Cr (52.2%) 〉 Mn (49.2%) 〉 V (43.5%). Positive matrix factorization method was applied for source apportionment of studied heavy metals combined with some marker elements and ions such as K, As, SO42- etc., and four factors (dust, vehicle, aged and transportation, unknown) are identified and the size distribution contribution of them to atmospheric heavy metals are discussed. 相似文献
102.
Pedological characteristics of Mn mine tailings and metal accumulation by native plants 总被引:3,自引:0,他引:3
In southern China revegetation and ecological restoration of many abandoned Mn tailings has become a major concern. To determine the major constraints for plant establishment and evaluate the feasibility of remediation, a comparative study was conducted on Mn tailings and rhizosphere soils at the boundary of the tailings pond. Both tailings and rhizosphere soils had neutral to slightly alkaline pH and normal electrical conductivity. They were both enriched with organic matter (6.8-9.2%), total N (1.77-5.94 g kg(-1)), available P (41.78-73.83 mg kg(-1)) and K (146.7-906.9 mg kg(-1)), suggesting the tailings were a nutrient rich substrate for revegetation. Mn tailings were clay textured, while rhizosphere soils were silty loam or clay loam. The compaction and anoxic nature of Mn tailings were considered to be the major constraints for plant establishment. Total Mn (31903 mg kg(-1)), Cd (119 mg kg(-1)), Cu (126 mg kg(-1)) and Zn (2490 mg kg(-1)) in tailings were all at phytotoxic levels, but did not differ significantly from those in rhizosphere soils. In both tailings and rhizosphere soils, percentages of water- and DTPA-extractable metals were less than 1% and 2% of the total metal pools, respectively. Sequential extraction revealed that the majority of Mn, Cu and Zn were associated with the residual fraction, while the majority of Cd occurred as Fe-Mn oxides. The natural succession of plants around Mn tailings formed a distinctive metal-tolerant plant community, mainly comprising nine species such as Cynodon dactylon and Humulus scandens and so on. All species studied could be good candidates for revegetation of Mn tailings. 相似文献
103.
The application of bioflocculant for the removal of humic acids from stabilized landfill leachates 总被引:24,自引:0,他引:24
The evaluation of bioflocculant, in comparison with traditional inorganic coagulants, for the removal of humic acids from landfill leachates stabilized by biological treatment, was performed using conventional jar-test coagulation experiments. The optimized conditions (pH and coagulant dosage) were identified for the treatment of synthetic solutions as well as for biologically pre-treated landfill leachates. It was found that the application of bioflocculant was quite efficient in the removal of humic acids from synthetic solutions as well as in the reduction of COD content from real landfill leachates. The optimal pH value was found to be between 7 and 7.5, while a 20 mg/l bioflocculant dosage was sufficient in providing more than 85% humic acid removal. The results were comparable with those obtained by the application of conventional coagulants such as alum or polyaluminum chloride; therefore, bioflocculant can be considered as a viable alternative in the treatment of landfill leachates applying coagulation. 相似文献
104.
东川市土地退化(荒漠化)及其防治 总被引:5,自引:0,他引:5
分析了东川市土地退化现状:土地退化以水蚀为主,退化土地面积占总土地面积38.5%。土地退化类型主要有土壤退化、土地沙石化、土地石质化和侵蚀劣地。文章还探讨了东川市土地退化的原因,提出了土地退化防治对策。 相似文献
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109.
昆明市东川区农业旱灾风险区识别研究 总被引:3,自引:0,他引:3
昆明市东川区是云南省农业旱灾危害较为严重的区域之一。利用2000-2007年东川区各乡镇历史灾情等数据资料,应用风险分析理论、效用理论、因子-成份分析方法等理论方法,在分别研究致灾风险度、承灾体易损性及地域人群对农业旱灾心理反响等基础上,构建了东川区农业旱灾风险评价模型。初步揭示出东川区农业旱灾风险度呈现出自南向北、自西向东逐渐增强的空间态势;识别出极高风险区、高风险区、中风险区和低风险区等4个农业旱灾风险区;发现东川区各地农业旱灾综合风险度、致灾风险度、承灾体易损度以及地域人群对旱灾的心理响应值等指数之间普遍存在着明显的正相关。 相似文献
110.
Chai X Jia J Sun T Wang Y Liao L 《Journal of environmental science and health. Part. B》2007,42(6):629-634
A novel and simple analytical procedure using cold activated carbon fiber-solid phase microextraction (CACF-SPME) was applied to determine organochlorine pesticides (OCs) in soil samples. The pesticides in this study consist of alpha -, beta -, gamma -, and delta -hexachlorocyclohexane (HCH). By heating the sample while cooling the fiber, the developed method not only provides better performance in terms of sensitivity, linearity and recovery but also offers shorter adsorption procedure than that of traditional headspace-solid phase microextraction (HS-SPME). The experimental conditions such as the amount of water, adsorption time and adsorption temperature were optimized. Matrix effects were investigated with different types of soils. We concluded that using the standard addition method was required for quantification purposes. The limits of detection obtained using the proposed method range from 0.01 to 0.05 ng/g, and the recoveries for CACF-SPME are in the range of 80.01% to 89.68% with relative standard deviation (RSDs) better than 8.60%. The proposed method was further applied to determine OCs in real agricultural soil. The results are in good agreement with those obtained using traditional ultrasonic extraction. The research demonstrates the suitability of the CACF-SPME for the analysis of OCs in soil. 相似文献