The impact of slurry application technique on nitrous oxide emission from agricultural soils

Direct nitrous oxide (N₂O) emissions from fertilized soils are generally estimated using emission factors. However, the emission factors for N₂O emission of applied slurry are not well quantified. The effect of slurry application technique on N₂O emission was quantified in field experiments in the Netherlands in order to derive N₂O emission factors for (shallow) injected and surface-applied cattle and pig slurries. Fluxes of N₂O were measured using a closed flux chamber technique and a photo-acoustic infra-red gasmonitor. Fluxes of N₂O were measured 64–83 times on grassland on sandy and clay soils and maize land on sandy soil, in the period 2007–2009. There were large differences in total N₂O emission between the years, and differences between treatments were not consistent over the years and sites. The average emission factor of all treatments and years (n = 35) was 0.9% of the N applied, which is close to the default IPCC emission factor of 1%. However, the range in emission was large, i.e. from ?0.2% to 7.0%. The average emission factor for grassland was 1.7% of the N applied for calcium ammonium nitrate (CAN), 0.4% for shallow injected cattle slurry, and 0.1% for surface-applied cattle slurry. For maize land, the average emission factor for CAN was 0.1% of the N applied, for injected cattle slurry 0.9% and for surface-applied cattle slurry 0.4%. The emission factors for pig slurry applied to maize land were higher than for cattle slurry; 3.6% for injected pig slurry and 0.9% for surface-applied pig slurry. Increasing the N application rate on maize land resulted in higher emission factors for CAN, injected cattle slurry, and injected pig slurry. Concluding, on both grassland and maize land (shallow) injection of slurry increased the average emission factor of N₂O in comparison to surface application. Differentiation of N₂O emission factors which takes specific factors into account, such as N type and rate and application technique, can improve the quantification of N₂O emission from agricultural soils and is needed to derive most efficient options for mitigation.     

Leachate characterization in semi-aerobic and anaerobic sanitary landfills: A comparative study

This study analyzes and compares the results of leachate composition at the semi-aerobic Pulau Burung Landfill Site (PBLS) (unaerated pond and intermittently aerated pond) and the anaerobic Kulim Sanitary Landfill in the northern region of Malaysia. The raw samples were collected and analyzed for twenty parameters. The average values of the parameters such as phenols (1.2, 6.7, and 2.6 mg/L), total nitrogen (448, 1200, and 300 mg/L N-TN), ammonia-N (542, 1568, and 538 mg/L NH₃-N), nitrite (91, 49, and 52 mg/L NO₂^?-N), total phosphorus (21, 17, and 19 mg/L), BOD₅ (83, 243, and 326 mg/L), COD (935, 2345, and 1892 mg/L), BOD₅/COD (0.096,0.1124,0.205%), pH (8.20, 8.28, and 7.76), turbidity (1546, 180, and 1936 Formazin attenuation units (FAU)), and color (3334, 3347, and 4041 Pt Co) for leachate at the semi-aerobic PBLS (unaerated and intermittently aerated) and the anaerobic Kulim Sanitary Landfill were recorded, respectively. The obtained results were compared with previously published data and data from the Malaysia Environmental Quality Act 1974. The results indicated that Pulau Burung leachate was more stabilized compared with Kulim leachate. Furthermore, the aeration process in PBLS has a considerable effect on reducing the concentration of several pollutants. The studied leachate requires treatment to minimize the pollutants to an acceptable level prior to discharge into water courses.     

Using penalty functions to evaluate aggregation models for environmental indices

The purpose of indices is to summarize a large volume of information into a single number that is easy to understand and interpret. Environmental indices provide a composite picture of an environmental condition derived from a series of observed measurements and parameters. They are used as communication tools by regulatory agencies to characterize the state of a specific environmental system (air, water, and sediments) and to study the impact of regulatory policies on various environmental management practices. In the development of environmental indices, a few issues and problems have been encountered arising as a result of the abstraction of information and data. These problems are referred to as characteristic properties that include ambiguity, eclipsing, compensation and rigidity. These characteristic properties have long been identified and interpreted in Boolean (e.g., Yes/No) or qualitative (e.g., low, medium, high) terms. In this paper, we propose a new approach to describe the above stated characteristic properties on a continuous scale to evaluate and compare the behavior of various aggregation models. Our approach is based on developing penalty functions for each characteristic property. A water quality index example by Swamee and Tyagi (2000) is used to explain our approach. A detailed case study for a developing microbial risk index is also provided to show how the proposed approach can be extended to complex hierarchical systems. Results show that it is possible to improve aggregation models for index development. Future research directions to improve index development are also discussed.     

A device for sampling the mud‐water interface in eutrophic lakes and bogs for residue analysis

Abstract

A tubular device has been developed making it possible to obtain layered samples of loosely aggregated, flocculent material from bogs or eutrophic lakes. The samples are up to 50 cm long and 15 cm in diameter. The sampler is free from protuberances and intact, layered samples can be taken. The tubular part of the sampler is about 85 em long, the walls of the lower 25‐cm portion harbouring a pneumatic closing mechanism which is controlled from above the water surface. An extendible handle for manipulating the sampler and for guiding it into place, is fastened to the upper end of the sampling tube. The performance and the operation of the sampler in the field are described.     

Educating the next generation of atmospheric scientists within a European Network of Excellence

In order to promote the next generation of atmospheric scientists, the task Training and Education (T&E) in ACCENT, the European Network of Excellence in Atmospheric Composition Change (www.accent-network.org) has developed and implemented an Integrated Learning Environment (ILE). For school teachers and their students, the Internet-based “Global Change Magazine” provides up-to-date and freely accessible scientific material in English and five other languages. Additionally, T&E has produced online teaching material for early-career scientists. These e-learning modules are now being used in University Master's courses across Europe. T&E also organised training events for early-career scientists, combining scientific content with development in transferable skills, to focus on interdisciplinary collaboration, interaction with senior scientists, communication with stakeholders, and dissemination to the general public. Evaluation based on participant feedback evidences the effectiveness of these events, e.g., in terms of motivation to remain in the field. Methodologies and materials from T&E are being published in a Handbook on Best Practice, intended for both educators and scientists around the globe who are involved in education in the field of air quality and climate change science.     

Validation studies of turbulence closure schemes for high resolutions in mesoscale meteorological models – A case of gas dispersion at the local scale

This work is a contribution to a large project, aimed at the development of an advanced environmental assessment modelling system to be used in Japan. The modelling system here considered consisted of the RAMS and HYPACT coupled models. The RAMS code was modified to properly simulate local scale phenomena using a fine mesh size of 250 m. In this direction, the main aim here was to investigate the effect of the choice of the turbulence closure scheme on the dispersion of pollutants. Our modified version of the RAMS/HYPACT model chain was validated using field experiments which were carried out by the Japan Atomic Energy Research Institute (JAERI) in the area of Mt. Tsukuba (Japan). The mean flow, turbulence and concentration fields obtained using two alternative turbulence closure schemes are compared. A discussion on the different performances of the turbulence closures is presented and the influence of the closure schemes over the plume dispersion is investigated.     

Penetration of submicron amino-functionalized graphene quantum dots in plant stomata,implication for the depollution of atmospheric soot particles

Environmental Chemistry Letters - Plants remove efficiently atmospheric pollution by soot particles, yet the mechanisms used by leaves to capture soot particles are unclear. Here, we studied the...