Life cycle assessment of solar photo-Fenton and solar photoelectro-Fenton processes used for the degradation of aqueous α-methylphenylglycine

A comparative Life Cycle Assessment (LCA) of solar photo-Fenton and solar photoelectro-Fenton, two solar-driven advanced oxidation processes (AOPs) devoted to the removal of non-biodegradable pollutants in water, is performed. The study is based on the removal, at laboratory scale, of the amino acid α-methylphenylglycine, a good example of soluble and non-biodegradable target pollutant. The system under study includes chemicals, electricity, transport of all raw materials to the plant site, and the generation of emissions, but it does not take into account the impact of the infrastructure needed to build a hypothetical solar plant. Nine environmental impact categories are included in the LCA: global warming potential, ozone depletion potential, aquatic eutrophication potential, acidification potential, human toxicity potential, photochemical ozone formation potential, fresh water aquatic ecotoxicity potential, marine aquatic ecotoxicity potential, and terrestrial ecotoxicity potential and abiotic resource depletion potential. Although previous experimental results show that both AOPs are able to efficiently degrade the pollutant, the LCA indicates that solar-driven photo-Fenton is the most environmentally friendly alternative, mainly because the use of electricity in solar photoelectro-Fenton experiments involves high environmental impacts.     

Photoelectro-Fenton treatment of pesticide triclopyr at neutral pH using Fe(III)–EDDS under UVA light or sunlight

Environmental Science and Pollution Research - One of the main challenges of electrochemical Fenton-based processes is the treatment of organic pollutants at near-neutral pH. As a potential...     

Levels of hexachlorobenzene and other organochlorine compounds in cord blood: exposure across placenta

Hexachlorobenzene (HCB) is an organochlorine compound widespread in the environment, highly lipophilic, that accumulates in biological systems. It has been suggested that it should be classified as a dioxin-like compound. Newborns are exposed to organochlorine compounds across the placenta and through breastfeeding. Although HCB is one of the most common organochlorine compounds, the transplacental transference of HCB from mother to fetus during pregnancy has been scarcely documented. This study reports the levels of HCB, dichlorodiphenyl trichloroethane (DDT) and its metabolite p,p'DDE, polychlorinated biphenyls (PCBs), and beta-hexachlorocyclohexane (beta-HCH) in 72 maternal blood samples at delivery and in 69 cord blood samples, from which 62 corresponded to mother infant pairs born between May 1997 and September 1999 in a rural area highly exposed to HCB. Results show that all newborns presented detectable levels of HCB, PCBs, and p,p'DDE, and, to a lesser extent, of beta-HCH, the HCB levels being the highest. The geometric mean of HCB was 1.1 ng/ml, ranging from 0.3 to 5.7 ng/ml. Concentrations of HCB levels in cord blood (log ng/ml) were positively associated with concentrations in maternal blood (log ng/ml) (coefficient = 0.45, P < 0.01). Gestational age was not associated with the transplacental transfer of HCB. Maternal p,p'DDE and beta-HCH levels were also associated with newborn levels, but levels of PCBs were not. We conclude that HCB, similar to other organochlorinated compounds, has a transplacental transfer.     

Correction to: Human behavior and Homo-mammal interactions at the first European peopling: new evidence from the Pirro Nord site (Apricena,Southern Italy)

The Science of Nature - Female-only colour polymorphism is rare in birds, but occurs in brood parasitic cuckoos (Cuculidae). Obligate brood parasites leave incubation and parental care to other...     

Effects of diver frequentation on Mediterranean sublittoral populations of the bryozoan Pentapora fascialis

The erect, foliaceous bryozoan Pentapora fascialis was selected as an indicator of the abrasive effects of heavy diving activity in Mediterranean coralligenous communities. A comparative survey of bryozoan populations at diver-frequented and unfrequented sites was undertaken in the Medes Islands Protected Area (NW Mediterranean) in 1992. Density, colony diameter, and colony height of P. fascialis populations were significantly lower and colony position was more cryptic at frequented sites than at unfrequented sites. Human frequentation may affect not only the structure of P. fascialis populations, but also that of the coralligenous community as a whole.     

Water consumption in Barcelona and its regional environmental imprint: a long-term history (1717–2008)

We present the evolution of urban water withdrawal and consumption of Barcelona from the eighteenth to the twenty-first centuries. The boundaries of the urban system have been set into the limits of the current municipality, adjusting the data of earlier periods to include the estimated consumption in former municipalities aggregated to the city. Different sorts of water flows have been either recorded or estimated from scant and indirect information, such as local groundwater extractions obtained from a hydrological model calibrated with historical data on variations in the water table. The changes experienced in catching infrastructures, the regional ecological imprint of the domestic or industrial water consumed together with the rates of growth in population, economic activity and water intensity have been taken into account as driving forces. The series obtained reveal an overall increase in accessibility to safe freshwater, and a corresponding extension of water terrestrial imprints of Barcelona over the Catalan river basins, up to the peak reached in 1967?C1970 both for per capita and total water withdrawn. The subsequent downward trend, mainly driven by a lesser water intensity of the local economy, a halt in population growth, and a recently link to the emergence of a New Sustainable Water Culture in Catalan society, stands out against the alleged need for new transfers from farthest basins such as the Ebro or Roine rivers.