Soil washing treatability tests for pesticide-contaminated soil

The 1987 Sand Creek Operable Unit 5 record of decision (ROD) identified soil washing as the selected technology to remediate soils contaminated with high levels of organochlorine pesticides, herbicides, and metals. Initial treatability tests conducted to assess the applicability of soil washing technology did not effectively evaluate the removal of the elevated contaminant concentrations that were found. To further evaluate the applicability of soil washing at this industrial site, a second more comprehensive pilot-scale treatability test was conducted. Twenty-three test runs were conducted over a two-week period in late September 1992, using a pilot-scale soil washing device called the volume reduction unit (VRU). The experimental design evaluated the effects of two wash temperatures, two pH levels, three surfactants, four surfactant concentrations, and two liquid-to-soil ratios on the contaminant removal efficiency of the soil washing process. Site soils from layers at three different depths were used in the study. Results from the pilot-scale treatability test indicated that the VRU could achieve contaminant reduction efficiencies of 97 percent for heptachlor and greater than 91 percent for dieldrin in the uppermost contaminated soils (surface to 1-ft. depth). Residual concentrations of heptachlor and dieldrin in the treated soil ranged from 50 ppm to less than 1.6 ppm, and 6.8 ppm to less than 1.6 ppm, respectively. However, the analytical method detection limit of 1.6 ppm was not low enough to provide residual concentration data at the risk-based action levels of 0.55 ppm for heptachlor and 0.15 ppm for dieldrin.     

Agricultural land evaluation and site assessment in the United States: An introduction

The US Soil Conservation Service has developed an agricultural land evaluation and site assessment (LESA) system. The LESA system is being used by the US Department of Agriculture and other federal agencies to implement the Farmland Protection Policy Act of 1981. The LESA system and three case studies from the Pacific North-west are introduced in this article.Scientific Paper no. 7166, College of Agriculture and Home Economics Research Paper. Washington State University, Pullman, Washington. Project no. 0010.     

Configuration of a functional department: A study of contextual and structural variables

This study investigates whether departments performing the same functions in different firms incur similar changes in structural configuration in response to industry-wide stimuli. Based on the proposition that the context of functional departments is similar across firms, changes in differentiation, integration, and perspective are hypothesized. Managers' perceptions of the validity of a series of statements to conditions five to 10 years ago and to present conditions are contrasted and show statistically significant shifts in these structural configurations. This change is confirmed by the analysis of responses of other managers in different departments within the same firms. Correlation analysis shows significant agreement among alternative measures of the same aspects of structure, and significant comovement among different structural dimensions. The later result supports the quantum theory of organizations.     

Structure-biodegradation relationships of polymeric materials. 1. Effect of degree of oxidation on biodegradability of carbohydrate polymers

The biodegradability of oxidized starch and inulin has been studied in relation to the degree of periodate oxidation to dialdehyde derivatives, by measuring oxygen consumption and mineralization to carbon dioxide. A higher degree of oxidation of dialdehyde starch and dialdchyde inulin results in a lower rate at which the polymers are biodegraded. It is demonstrated that the biodegradation rate of dialdehyde inulin derivatives decreases more than that of equivalent starch derivatives. The differences in biodegradation behavior between dialdehyde starch and dialdehyde inulin, resulting from comparable modifications, are discussed in terms of conformational structure.     

Integrated economic-ecological analysis and evaluation of management strategies on nutrient abatement in the Rhine basin

Management of river basins involves the making of informed choices about the desired levels of economic activities and ecosystem functioning in the catchment. Information on the economic and ecological effects of measures as well as their spatial distribution is therefore needed. This paper proposes the following instruments to support decision-making in river basins: (1) the linking of models and indicators to describe the economic and ecological effects of management actions and their spatial distribution and (2) an extended evaluation framework that aims to evaluate management actions on three objectives for sustainable river management. These are cost-effectiveness, spatial equity, and environmental quality. This paper illustrates the potential of these instruments for river basin management by a case-study on nutrient management in the Rhine basin. In this case-study four nutrient abatement strategies are formulated, based on policies of the International Commission for the Protection of the Rhine and the North Sea Commission. These strategies are analysed and evaluated on their contribution to the three management objectives. Results show that none of these strategies score highest on cost-effectiveness, spatial equity and environmental quality simultaneously. It appears that cost-effectiveness is in conflict with environmental quality, whereas spatial equity and cost-effectiveness show quite close correspondence. This means that a trade-off has to be made between costs and spatial equity on the one hand, and environmental standards on the other hand. This paper offers a framework to make these trade-offs more explicit and provides quantitative information on cause-effect relationships, economic and environmental effects and the spatial distribution of these effects for various management strategies. This information can be particularly useful in the development of compromises required to establish international agreement and co-operation.     

“Food Metaphors and Ethics: Towards More Attention for Bodily Experience”

Official Dutch food information apparently tries to avoid images but is implicitly shaped by the metaphor that food is fuel. The image of food as fuel and its accompanying view of the body as a machine are not maximally helpful for integrating two important human desires: health and pleasure. At the basis of the split between health and pleasure is the traditional mind–body dichotomy, in which the body is an important source of evil and bodily pleasure is sinful and dangerous. In the search for alternatives, new metaphors are proposed that integrate mind and body as well as pleasure and health. The relevance of metaphors for ethics is at least twofold. (1) Moral thought and theory are at least partly shaped by metaphors. In the light of this growing recognition, the analysis of morality needs innovation. (2) With regard to food, new metaphors, such as slow food, or the image of enjoyment as an art, enable a new search for morally responsible forms of hedonism, based on more love and respect for human as well as animal bodies. But new metaphors are specific and selective, just like old ones. I argue that a search for the best overall metaphor would be misguided, but that more diverse forms of attention to bodily aspects of life, including experiences related to food, will result in richer vocabularies of the body, the mind, and body–mind relations. This holds a promise of moral progress.     

WEST AFRICA: VOLTA DISCHARGE DATA QUALITY ASSESSMENT AND USE1

ABSTRACT: Water resource management in West Africa is often a complicated process due to inadequate resources, climatic extremes, and insufficient hydrological information. Insufficient data hinder sustainable watershed management practices, one of the top priorities in the Volta River Basin. This research properly fills in missing data by modeling the hydrological distribution in the Volta River Basin. On average, discharge gages across the basin are missing 20 percent of their monthly data over 20 years. Two methods were used to supplement missing data: a statistically linear model and a conceptual hydrological model. A linear equation, developed from the regression of precipitation and runoff, was used to evaluate the quality of existing data. The hydrological model separates the system into root and groundwater zones. Measured values were used to calibrate the hydrological model and to validate the statistical model. The quality of existing data was analyzed and organized for usability. Accuracy of the hydrological model was also evaluated for its effectiveness using R² and standard error. It was found that the hydrological model was an improvement from the linear model on a monthly basis; R² values improved by as much as 0.5 and monthly error decreased. Monthly predictions of the hydrological model were used to fill gaps of measured data sets.     

Gender aspects in the management of water

Water resources increasingly need to meet the demands and needs of different sectors and to be protected against deteriorating quantity and quality. This paper discusses the different interests of men and women in the use of water resources, and what effects the neglect of female interests in particular, has on development. The authors stress that besides class and ethnic differences, the different interests of men and women also play a role in the cross-sectoral management of water resources. Water pricing, property rights and management structures are three key aspects where a gender approach is required. In the management of water resources in smaller catchment areas, several instruments for a gender approach have been developed. Discussed are gender specific participatory research, planning and tools, gender in management organizations and task divisions and involvement of multidisciplinary teams with a gender orientation.     

Effect of cobalt sorption on metal fractionation in anaerobic granular sludge

A sequential extraction procedure was applied to two anaerobic methanogenic sludges (Eerbeek and Nedalco) to examine the speciation of micro- and macronutrients in the sludges after cobalt sorption by exposing the sludge to a 1 mM Co solution for 4 d at pH 7 and 30 degrees C. The effect of different physicochemical conditions on cobalt sorption was studied as well: effect of pH (6-8), effect of competition by a second trace element (Ni or Fe), modification of the granular matrix by glutaraldehyde or heat treatment, and EDTA (ethylenediaminetetraacetic acid) addition. Sorbed Co was found to distribute between the carbonates, organic matter + sulfides, and residual fractions. Cobalt adsorption resulted in an antagonistic interaction with other metals present in the granular matrix, evidenced by the solubilization of other trace elements (e.g., Ni, Cu, and Zn) as well as macronutrients (especially Ca and Fe). Modification of the sludge matrix by glutaraldehyde or heat treatment, or exposure to EDTA, led to serious modifications of the Co sorption capacity and strong interactions with multivalent cations (i.e., Ca(2+) and Fe(2+)).