Recycling of synthetic waste wig fiber in the production of cement-adobe for building envelope: physio-hydric properties

Environmental Science and Pollution Research - Waste wigs are often disposed off in their volume on landfills, thus constituting a nuisance to the environment. Recycling these wigs in masonry...     

Simultaneous measurement of ventilation using tracer gas techniques and VOC concentrations in homes, garages and vehicles

Air exchange rates and interzonal flows are critical ventilation parameters that affect thermal comfort, air migration, and contaminant exposure in buildings and other environments. This paper presents the development of an updated approach to measure these parameters using perfluorocarbon tracer (PFT) gases, the constant injection rate method, and adsorbent-based sampling of PFT concentrations. The design of miniature PFT sources using hexafluorotoluene and octafluorobenzene tracers, and the development and validation of an analytical GC/MS method for these tracers are described. We show that simultaneous deployment of sources and passive samplers, which is logistically advantageous, will not cause significant errors over multiday measurement periods in building, or over shorter periods in rapidly ventilated spaces like vehicle cabins. Measurement of the tracers over periods of hours to a week may be accomplished using active or passive samplers, and low method detection limits (<0.025 microg m(-3)) and high precisions (<10%) are easily achieved. The method obtains the effective air exchange rate (AER), which is relevant to characterizing long-term exposures, especially when ventilation rates are time-varying. In addition to measuring the PFT tracers, concentrations of other volatile organic compounds (VOCs) are simultaneously determined. Pilot tests in three environments (residence, garage, and vehicle cabin) demonstrate the utility of the method. The 4 day effective AER in the house was 0.20 h(-1), the 4 day AER in the attached garage was 0.80 h(-1), and 16% of the ventilation in the house migrated from the garage. The 5 h AER in a vehicle traveling at 100 km h(-1) under a low-to-medium vent condition was 92 h(-1), and this represents the highest speed test found in the literature. The method is attractive in that it simultaneously determines AERs, interzonal flows, and VOC concentrations over long and representative test periods. These measurements are practical, cost-effective, and helpful in indoor air quality and other investigations.     

Impact of December 26, 2004 tsunami on the hydrobiology of Kudankulam coast, Gulf of Mannar, India

Tsunami is a serious form of natural disasters that affects the coastal ecosystem. The present paper gives a comparative account of selected hydrobiological parameters of the tsunami affected Kudankulam coast for a period of 32 months from May 2003 to December 2005. The concentration of nitrates, nitrites, and phosphates and phytoplankton density showed higher values immediately after the tsunami. The dissolved oxygen content and the zooplankton abundance decreased considerably. Post-tsunami data indicated that the coastal ecosystem recovered from the impact within five months.     

Mobility and efficacy of 2,4-D herbicide from slow-release delivery systems based on organo-zeolite and organo-bentonite complexes

This research aimed to develop slow-release formulations (SRFs) of 2,4-dichlorophenoxyacetic acid (2,4-D) using zeolite and bentonite minerals modified with cetyltrimethylammonium (CTMA) surfactant. Adsorption–desorption, greenhouse bioassay and column experiments were carried out to assess the potential of the SRFs to control weeds while reducing the herbicide leaching losses to deep layers of soil. The results showed that only 6.5 mmol 2,4-D kg^?1 was retained by Na-bent, and the herbicide was not adsorbed by Na-zeol at all. The surface modification with CTMA surfactant, however, improved the 2,4-D adsorption capacity of the zeolite and bentonite up to 207.5 and 415.8 mmol kg^?1, respectively. The synthesized organo-minerals slowly released the retained 2,4-D discharging 22 to 64% of the adsorbed 2,4-D to the solution phase within 7 days. The SRFs significantly (P = 0.05) reduced the herbicide mobility within the soil columns keeping a great portion of the herbicide active ingredient in the upper 5 cm soil layer. The SRFs were significantly (P = 0.05) as effective as the free technical herbicide in weed control without harming the ryegrass as the main plant. Therefore, the synthesized SRFs could be considered as useful tools for weed control in sustainable agriculture.     

Perceptions and attitudes towards gas flaring in the Niger Delta,Nigeria

Gas flaring is the burning of crude oil’s associated gas. In Nigeria’s Niger Delta, the flaring process is usually very close to communities and their farmlands and has been implicated in serious environmental degradation of the region. Studies have suggested links between gas flaring and health problems in the communities and others have established relationships between gas flaring and poor agricultural yields. This study explores how the people in the region perceive gas flaring and what their attitudes are toward it. Ubeji town, a community where gas flaring takes place, was selected as a case study. It was found that the residents perceive gas flaring as hazardous to health, environment, and general well-being of the community. Most residents seem to be resigned to the continued presence of gas flaring activities in the community. The study, however, raised several questions on modeling perception and attitudes toward environmental problems in areas where political tension and economic adversity are prevalent.     

How much e-waste is there in US basements and attics? Results from a national survey

The fate of used electronic products (e-waste) is of increasing concern because of their toxicity and the growing volume of e-waste. Addressing these concerns requires developing the recycling infrastructure, but good estimates of the volume of e-waste stored by US households are still unavailable. In this context, we make two contributions based on a national random survey of 2136 US households. First, we explain how much e-waste is stored by US households using count models. Significant explanatory variables include age, marital and employment status, ethnicity, household size, previous e-waste recycling behavior, and to some extent education, home ownership, and understanding the consequences of recycling, but neither income nor knowledge of e-waste recycling laws. Second, we estimate that on average, each US household has 4.1 small (≤10 pounds) and 2.4 large e-waste items in storage. Although these numbers are likely lower bounds, they are higher than recent US Environmental Protection Agency (EPA) estimates (based on narrower product categories). This suggests that the backlog of e-waste in the US is likely larger than generally believed; it calls for developing the recycling infrastructure but also for targeted recycling campaigns.     

Long-term trends in sodium and chloride in the Mohawk River,New York: the effect of fifty years of road-salt application

Ecological studies have demonstrated the adverse effects of road-salt, primarily NaCl, on water quality, flora, and fauna. In this study, we quantified changes in ionic composition and solute flux of water draining the Mohawk River Basin (9103 km(2)) in New York State, from 1952 to 1998. Using various statistical, graphical, and modeling techniques, we showed that concentrations ofNa+ and Cl- have increased by 130 and 243%, respectively, while other constituents have decreased or remained constant. The use of de-icing salt on roads within the watershed, which we estimate at 39 kg km(-2) day(-1), appears to be the primary mechanism responsible for reported increases, accounting for the increase in NaCl export from 16 to 46 kg km(-2) day(-1) over the 47-year period.Moreover, despite population decline within this rural upstate watershed, increased environmental stewardship, and The Clean Water Act, concentrations of Na+ and Cl- still increased during the 1990s.     

A quantitative methodology for indexing environmental sensitivity and pollution potential

A methodology for rating the suitability of sites forthe location of industrial facilities is formulated and appliedto the case of a coal-fired power plant location. The methodologycomprises two major interlinked components: the environmentalplant location indexing component, which involves theidentification, scaling and weighting of environmentalsensitivity factors; and the impact analysis component, whichinvolves the superimposition of the pollution generation impactsof an industrial facility on spatially gridded zones of variousenvironmental sensitivities. For each rectangular areal unitdefined by a square grid, the Unit Pollution Potential Index isdetermined by the severity and distribution of key environmentalsensitivity factors and the coverage of superimposed pollutanteffects as determined by contaminant fate and transport models.For any alternative site of a planned facility, the summation ofthe unit indices over the area of influence of the facilityprovides the quantitative Pollution Index, which can be used as abasis for comparison of alternative sites for planned facilities.For this paper, this methodology is applied to the hypotheticalcase of the siting of a coal-fired power plant in thenortheastern region of the United States, in which threealternative sites are considered. The three sites: A, B and Cyielded indices of 47.83, 47.91 and 47.6, respectively, indicatingthat site C is the most suitable for siting the power plant.     

Gasoline prices and economic policy uncertainty: what causes what,and why does it matter? Evidence from 18 selected countries

In this paper, we examine asymmetric causal relationships between gasoline prices and economic policy uncertainty in a panel of 18 countries over the period 1998–2017, using the recently introduced panel causality approach of Hatemi et al (Appl Econ, 48:2301–2308, 2016) that accounts for asymmetric dynamics and is robust to both cross-sectional dependence and slope heterogeneity. Empirical findings reveal asymmetric causal relationships between gasoline prices and economic policy uncertainty in the sampled countries. Specifically, results show that economic policy uncertainty and gasoline prices have positive and negative asymmetric bidirectional causal relations in 13 countries. No feedback causality was detected between gasoline prices and economic policy uncertainty in 5 countries. Based on the results, we infer that positive and negative asymmetric causal relations exist between economic policy uncertainty and gasoline price, with attendant policy implications in sampled regions.

     

Distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in Sediment Cores of Selected Creeks in Delta State,Nigeria

The spatial and seasonal distribution and concentrations of polycyclic aromatic hydrocarbons (PAHs) were investigated in core sediments of Ubeji, Ifie, and Egbokodo creeks in the Niger Delta, Nigeria. A total of 222 core sediment samples were collected during the wet season (August 2010) and the dry season (January 2011). The samples were dried, Soxhlet extracted, fractionated, and injected into a gas chromatograph with flame ionization detector (GC-FID). The concentrations of PAHs ranged from not detected to 2,654 μg/kg (wet season) and not detected to 3,513 μg/kg (dry season). In general, the concentrations of PAHs for a number of stations in this study are comparable to sites with high anthropogenic activities in the Niger Delta. The toxicity risk assessment based on the total BaP equivalent quotient of the seven carcinogenic PAHs (BaA, Chry, BbF, BkF, BaP, DBA, and Iper) was 97.416 μg/kg and did not exceed the method B cleanup level for benzo(a)pyrene (137 μg/kg), according to toxic equivalency factors, which implied that PAHs in sediments of the present study currently have minimal adverse effects. This study provided information on the concentrations and profiles of PAHs sediment cores, which is useful for source diagnosis, environmental quality management, contamination history, and environmental forensic studies.