Clean Water State Revolving Fund Loans and Landowner Investments in Agricultural Best Management Practices in Iowa1

Arbuckle, Jr., J. Gordon, 2012. Clean Water State Revolving Fund Loans and Landowner Investments in Agricultural Best Management Practices in Iowa. Journal of the American Water Resources Association (JAWRA) 1‐9. DOI: 10.1111/j.1752‐1688.2012.00688.x Abstract: Clean Water State Revolving Fund (CWSRF) loan programs for water quality have traditionally funded infrastructure projects at the community, municipality, or state level. They are increasingly being used to support individual landowner adoption of agricultural best management practices (BMPs) for nonpoint source pollution abatement. In 2005, the Iowa CWSRF initiated the Local Water Protection Program (LWPP) to increase the scope, scale, and rate of agricultural BMP establishment. This research examines the effectiveness of that program through a comparison of survey data from LWPP participants and state cost‐share recipients who were eligible for loans, but did not take them. Loan recipients’ assessments of the program were overwhelmingly positive, with near‐universal satisfaction with both the loan product and process. Results of statistical analyses indicate that loan recipients invested substantially more in conservation than nonrecipients. Evidence suggests that by helping program participants to overcome financial constraints, loans are facilitating larger and accelerated investments in conservation. Although findings indicate that conservation loans can play an important role in funding conservation, loan recipients also still depend on cost‐share. Loans are not necessarily a substitute for traditional forms of conservation funding, but rather another tool that landowners and conservation professionals can employ to facilitate investments in BMPs.     

Structuring expert input for a knowledge-based approach to watershed condition assessment for the Northwest Forest Plan, USA

Assessments of watershed condition for aquatic and riparian species often have to rely on expert opinion because of the complexity of establishing statistical relationships among the many factors involved. Such expert-based assessments can be difficult to document and apply consistently over time and space. We describe and reflect on the process of developing a computer-based decision support application from expert judgments for assessing aquatic and riparian conditions over the 100,000?km² managed by the US federal government under the Northwest Forest Plan. The decision support system helped structure and document the assessment process and provided consistency and transparency to the evaluation methodology. However, many decisions and trade-offs were required in the expert engagement and model-building processes. Knowledge elicitation in an interactive group had a number of benefits over nominal group or Delphi processes, but efficient knowledge capture required considerable planning and expertise in the subject matter and modeling process. Communicating model results for validation was problematic and only effectively accomplished via in-person workshops. The choice to use different expert groups for each biophysical province provided more opportunities for participation and promoted greater ownership in the assessment, but it also led to increased variation among the resulting model structures. We propose three possible approaches for better managing the consistency of assessment models when multiple expert groups are involved.     

Functional flax fiber with UV-induced switchable wettability for multipurpose oil-water separation

● A PAA-ZnO-HDTMS flax fiber with UV-induced switchable wettability was developed. ● The property of flax fiber could be switched from hydrophobicity to hydrophilicity. ● The mechanism of the acquired UV-induced switchable wettability was discussed. ● The developed flax fiber was successfully used for multipurpose oil-water separation. The large number of oily wastewater discharges and oil spills are bringing about severe threats to environment and human health. Corresponding to this challenge, a functional PAA-ZnO-HDTMS flax fiber with UV-induced switchable wettability was developed for efficient oil-water separation in this study. The developed flax fiber was obtained through PAA grafted polymerization and then ZnO-HDTMS nanocomposite immobilization. The as-prepared PAA-ZnO-HDTMS flax fiber was hydrophobic initially and could be switched to hydrophilic through UV irradiation. Its hydrophobicity could be easily recovered through being stored in dark environment for several days. To optimize the performance of the PAA-ZnO-HDTMS flax fiber, the effects of ZnO and HDTMS concentrations on its switchable wettability were investigated. The optimized PAA-ZnO-HDTMS flax fiber had a large water contact angle (~130°) in air and an extremely small oil contact angle (~0°) underwater initially. After UV treatment, the water contact angle was decreased to 30°, while the underwater oil contact angle was increased to more than 150°. Based on this UV-induced switchable wettability, the developed PAA-ZnO-HDTMS flax fiber was applied to remove oil from immiscible oil-water mixtures and oil-in-water emulsion with great reusability for multiple cycles. Thus, the developed flax fiber could be further fabricated into oil barrier or oil sorbent for oil-water separation, which could be an environmentally-friendly alternative in oil spill response and oily wastewater treatment.     

Molecular dating and biogeography of the neritic krill Nyctiphanes

The genus Nyctiphanes (Malacostraca, Euphausiacea) comprises four neritic species that display antitropical geographic distribution in the Pacific (N. simplex and N. australis) and Atlantic (N. couchii and N. capensis) Oceans. We studied the origin of this distribution applying methods for phylogenetic reconstruction and molecular dating of nodes using a Bayesian MCMC analysis and the DNA sequence information contained in mtDNA 16S rDNA and cytochrome oxidase (COI). We tested hypotheses of vicariance by contrasting the time estimates of cladogenesis with the onset of the major barriers to ocean circulation. It was estimated that Nyctiphanes originated in the Pacific Ocean during the Miocene, with a lower limit of 18 miilion years ago (Mya). An Atlantic–Pacific cladogenic event (95% HPD 3.2–9.6) took place after the closure of the Tethyan Sea, suggesting that dispersal occurred from the Indo-Pacific, most likely via southern Africa. Similarly, the antitropical distribution pattern observed in the eastern Atlantic Ocean likely resulted from recent Pliocene–Pleistocene (95% HPD 1.0–4.97) northward dispersal from the southern hemisphere. Our results imply that dispersal appears to have had a significant role to play in the evolution of this group. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Reform,Justice, and Sovereignty: A Food Systems Agenda for Environmental Communication

Food ecologies and economies are vital to the survival of communities, non-human species, and our planet. While environmental communication scholars have legitimated food as a topic of inquiry, the entangled ecological, cultural, economic, racial, colonial, and alimentary relations that sustain food systems demand greater attention. In this essay, we review literature within and beyond environmental communication, charting the landscape of critical food work in our field. We then illustrate how environmental justice commitments can invigorate interdisciplinary food systems-focused communication scholarship articulating issues of, and critical responses to, injustice and inequity across the food chain. We stake an agenda for food systems communication by mapping three orientations—food system reform, justice, and sovereignty—that can assist in our critical engagements with and interventions into the food system. Ultimately, we entreat environmental communication scholars to attend to the bends, textures, and confluences of these orientations so that we may deepen our future food-related inquiries.     

Adsorption/desorption of arsenite and arsenate on chitosan and nanochitosan

Equilibrium sorption studies of anionic species of arsenite, As(III) ions and arsenate As(V) ions onto two biosorbents, namely, chitosan and nanochitosan, have been investigated and compared. The results and trends in the sorption behavior are novel, and we have observed during the sorption process of the As(III) and As(V) on chitosan, a slow process of desorption occurred after an initial maximum adsorption capacity was achieved, before reaching a final but lower equilibrium adsorption capacity. The same desorption trend, however, is not observed on nanochitosan. The gradual desorption of As(III) and As(V) in the equilibrium sorption on chitosan is attributed to the different fractions of the dissociated forms of arsenic on the adsorbent surface and in solution and the extent of protonation of chitosan with the changing of solution pH during sorption. The change of solution pH during the sorption of arsenite ions on chitosan was also influenced by the interaction between the buffering effect of the arsenite species in the aqueous medium and the physical properties of chitosan. The final equilibrium adsorption capacity of chitosan for As(III) and As(V) was found to be around 500 and 8000 μg/g, respectively, whereas the capacities on nanochitosan are 6100 and 13,000 μg/g, respectively.

     

Effect of Moisture on the Pollutant Concentration Measurement

The effects of removing moisture from gaseous samples on the measurement of pollutant concentration were studied. Simple mathematical analysis was conducted to derive the formula for correcting the measured results. It was found that the error increases with increase in relative humidity or increase in temperature. The error may become significant under extreme conditions.     

Using flue gas desulfurization gypsum to remove dissolved phosphorus from agricultural drainage waters

High levels of accumulated phosphorus (P) in soils of the Delmarva Peninsula are a major source of dissolved P entering drainage ditches that empty into the Chesapeake Bay. The objective of this study was to design, construct, and monitor a within-ditch filter to remove dissolved P, thereby protecting receiving waters against P losses from upstream areas. In April 2007, 110 Mg of flue gas desulfurization (FGD) gypsum, a low-cost coal combustion product, was used as the reactive ingredient in a ditch filter. The ditch filter was monitored from 2007 to 2010, during which time 29 storm-induced flow events were characterized. For storm-induced flow, the event mean concentration efficiency for total dissolved P (TDP) removal for water passing through the gypsum bed was 73 ± 27% confidence interval (α = 0.05). The removal efficiency for storm-induced flow by the summation of load method was 65 ± 27% confidence interval (α = 0.05). Although chemically effective, the maximum observed hydraulic conductivity of FGD gypsum was 4 L s(-1), but it decreased over time to <1 L s(-1). When bypass flow and base flow were taken into consideration, the ditch filter removed approximately 22% of the TDP load over the 3.6-yr monitoring period. Due to maintenance and clean-out requirements, we conclude that ditch filtration using FGD gypsum is not practical at a farm scale. However, we propose an alternate design consisting of FGD gypsum-filled trenches parallel to the ditch to intercept and treat groundwater before it enters the ditch.     

Energy supplies and future engines for land, sea, and air

The years 2012 and beyond seem likely to record major changes in energy use and power generation. The Japanese tsunami has resulted in large countries either scaling back or abolishing the future use of nuclear energy. The discovery of what seems like vast amounts of economically deliverable natural gas has many forecasting a rapid switch from coal- to gas-fired generating plants. On the other hand, environmentalists have strong objections to the production of natural gas and of petroleum by hydraulic fracturing from shale, or by extraction of heavy oil. They believe that global warming from the use of fossil fuels is now established beyond question. There has been rapid progress in the development of alternative energy supplies, particularly from on-shore and off-shore wind. Progress toward a viable future energy mix has been slowed by a U.S. energy policy that seems to many to be driven by politics. The author will review the history of power and energy to put all of the above in context and will look at possible future developments. He will propose what he believes to be an idealized energy policy that could result in an optimum system that would be arrived at democratically.