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51.
对南京市1984—2015年Landsat 4/5/7/8卫星TM/ETM+/OLI传感器获取的遥感数据,利用ENVI遥感软件的FLAASH大气校正模块,进行了区域大气能见度( VIS)遥感反演。结果表明,时间跨度达30余年的Landsat卫星遥感数据影像序列反演的VIS呈明显的下降趋势,20世纪80年代数值较高,“差”能见度(<10 km)的观测率不到6%,21世纪以来VIS下降明显,“差”能见度的观测率为20%~25%。与2010—2015年南京市PM10、PM2.5监测数据进行了对比,在城市空气清洁及污染较轻时,星地监测结果有较好的一致性,但中到重污染天气时FLAASH算法反演VIS偏高,侧重于代表离主城区距离远的偏远乡野山林地区的能见度状况。  相似文献   
52.
We describe here a one-step method for the synthesis of Au/TiO2 nanosphere materials, which were formed by layered deposition of multiple anatase TiO2 nanosheets. The Au nanoparticles were stabilized by structural defects in each TiO2 nanosheet, including crystal steps and edges, thereby fixing the Au–TiO2 perimeter interface. Reactant transfer occurred along the gaps between these TiO2 nanosheet layers and in contact with catalytically active sites at the Au–TiO2 interface. The doped Au induced the formation of oxygen vacancies in the Au–TiO2 interface. Such vacancies are essential for generating active oxygen species (*O) on the TiO2 surface and Ti3 + ions in bulk TiO2. These ions can then form Ti3 +–O–Ti4 + species, which are known to enhance the catalytic activity of formaldehyde (HCHO) oxidation. These studies on structural and oxygen vacancy defects in Au/TiO2 samples provide a theoretical foundation for the catalytic mechanism of HCHO oxidation on oxide-supported Au materials.  相似文献   
53.
对2017年9月~2018年8月深圳市北部大气PM2.5中水溶性有机物(WSOM)的质量浓度、质谱及来源结构进行测量和分析.结果表明:PM2.5的质量浓度为(32.3±18.4)μg/m3,WSOM的质量浓度为(9.4±5.7)μg/m3,占颗粒物总有机物的(77.6%±14.0%).质谱分析显示,WSOM的氧碳比(O/C)平均值达到(0.57±0.09),属于二次有机物的O/C值范围,且生物质燃烧排放的离子碎片C2H4O2+的丰度显著,说明WSOM的来源中有显著的生物质燃烧排放的有机气溶胶.为了明确WSOM的来源结构,利用正矩阵因子分解法(PMF)模型进行来源解析,发现3个合理因子:高氧化态有机气溶胶(MO-OOA),低氧化态有机气溶胶(LO-OOA)和生物质燃烧(BBOA),贡献比例分别为51.7%,31.8%和16.5%.MO-OOA和BBOA贡献浓度均呈现秋冬高、春夏低的季节变化特征,反向轨迹分析显示其与...  相似文献   
54.
企业环境绩效评价模型的构建及其检验   总被引:1,自引:0,他引:1       下载免费PDF全文
以企业社会绩效的“原则—过程—结果”理论为基础,借鉴已有研究成果,构建了一套包含4 个过程因子、2 个结果因子的具有二阶结构的企业环境绩效(CEP)评价模型,并运用验证性因子分析法,以252 家日本企业的调查数据为基础,对此模型构建进行了实证检验.验证性因子分析结果表明,CEP 是由6 个特征明显而又相互联系的一阶因子组成的多维结构,而且CEP 是能够解释这6 个一阶因子相关性的二阶因子,证明本研究构建的CEP 评价模型具有合理性.  相似文献   
55.
进入新时代,具有“邻避”效应的重大项目和基础设施建设仍然是我国城镇化发展的“刚需”和重要支撑,环境“邻避”问题必将是当前及今后一定时期内城镇化进程中面临的常态。本文选取南方某省作为典型对象进行深入研究,结果表明,环境“邻避”问题总体风险形势平稳可控,防控重点领域仍以传统领域为主,公众诉求反应和抗争表达方式由激烈转变为相对理性,城市规划与建设的矛盾风险问题增多,风险传播快传导性强。本文系统总结出明确组织领导统筹机制、强化联动发挥协作效能、建设项目高标准实施、惠民措施灵活有效、社会力量聚合治理等地方实践经验。建议重点着力防范化解好传统领域风险,常态化推动机制发挥作用,充分发挥共建共治共享作用,以环境社会治理共享发展成果,提升环境“邻避”问题系统应对能力。  相似文献   
56.
Industrial agriculture is yearly responsible for the loss of 55–100 Pg of historical soil carbon and 9.9 Tg of reactive nitrogen worldwide. Therefore, management practices should be adapted to preserve ecological processes and reduce inputs and environmental impacts. In particular, the management of soil organic matter (SOM) is a key factor influencing C and N cycles. Soil microorganisms play a central role in SOM dynamics. For instance, microbial diversity may explain up to 77 % of carbon mineralisation activities. However, soil microbial diversity is actually rarely taken into account in models of C and N dynamics. Here, we review the influence of microbial diversity on C and N dynamics, and the integration of microbial diversity in soil C and N models. We found that a gain of microbial richness and evenness enhances soil C and N dynamics on the average, though the improvement of C and N dynamics depends on the composition of microbial community. We reviewed 50 models integrating soil microbial diversity. More than 90 % of models integrate microbial diversity with discrete compartments representing conceptual functional groups (64 %) or identified taxonomic groups interacting in a food web (28 %). Half of the models have not been tested against an empirical dataset while the other half mainly consider fixed parameters. This is due to the difficulty to link taxonomic and functional diversity.  相似文献   
57.
MnO2 microspheres with various surface structures were prepared using the hydrothermal method, and Au/MnO2 catalysts were synthesized using the sol-gel method. We obtained three MnO2 microspheres and Au/MnO2 samples: coherent solid spheres covered with wire-like nanostructures, solid spheres with nanosheets, and hierarchical hollow microspheres with nanoplatelets and nanorods. We investigated the properties and catalytic activities of formaldehyde oxidation at room temperature. Crystalline structures of MnO2 are the main factor affecting the catalytic activities of these samples, and γ-MnO2 shows high catalytic performance. The excellent redox properties are responsible for the catalytic ability of γ-MnO2. The gold-supported interaction can change the redox properties of catalysts and accelerate surface oxygen species transition, which can account for the catalytic activity enhancement of Au/MnO2. We also studied intermediate species. The dioxymethylene (DOM) and formate species formed on the catalyst surface were considered intermediates, and were ultimately transformed into hydrocarbonate and carbonate and then decomposed into CO2. A proposed mechanism of formaldehyde oxidation over Au/MnO2 catalysts was also obtained.  相似文献   
58.
The structure of coastal land cover in Estonia is intricate and exhibits considerable differences from site to site. The diverse geomorphology of the seashores is one of the key factors affecting the speed and magnitude of land cover changes. Likewise, the history of human inhabitance on the coast has also shaped the character of land cover. The Estonian coastal zone has experienced abrupt and radical changes in land ownership and its related land use during the last century. The main objectives of this paper are: 1) to give an overview of land use and the trends of development of land cover pattern along different parts of the Estonian coast; and 2) to analyze the relationships of natural and human processes and their cumulative impact on the evolution of coastal land cover pattern in Estonia. This study is based on results obtained during fieldwork in the study areas and on the analysis of large-scale (1:10,000) historical maps. In agriculturally dominant coastal areas, the traditional open landscape of fields and grassland at the beginning of the 20th century had been replaced by woodland and grasslands with shrubs by the start of the 21st century. Expansion of reed beds in areas of former seashore grasslands is another striking phenomenon. The structure of land cover on forested coasts has been fairly stable during the last 100 years. Areas of urban sprawl are characterised by dramatic changes in land cover structure. Rapidly increasing population and expanding settlements imposes on the ecological balance of the fragile dune forests in the coastal zone.  相似文献   
59.
The classical use of synthetic dyes is causing issues of environmental pollution and heath risk. As a consequence natural dyes are gaining interest, but the use of natural dyes still includes toxic reagents such as metals as mordants and acids to enhance color and yield. Therefore, we designed a new chitosan-polypropylene imine dendrimer hybrid at 0–2000 mg/L to treat wool before dyeing with cochineal. We compared dye exhaustion, color depth, color characteristics, and color fastness of the new process with dyed pristine and metal mordanted wool. Results show that wool pretreatment improved dye exhaustion from 48 to 88 %, shifted saturation point toward lower dye concentration from 3000 to 1000 mg/L, and improved color depth from 13.68 for pristine wool and 15.17 for metal mordanted wool to 23.89 for the new process.  相似文献   
60.
Environmental Science and Pollution Research - Microfaunal identification and analysis are very complex; thus, an image analysis method was utilized in this paper to overcome the shortcomings of...  相似文献   
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