Freisetzung von Schwermetallen aus dem bodenbildenden Tonmineral Illit durch Aminosäuren

Kaolin W from Lohrheim (51% Illite, 31% Kaolinite, 18% Quarz, no Carbon) was loaded with various amounts of heavy metal ions (0.11–6.0 mmol/100g Cu, Ni, Cd) from their nitrate solutions. In the next step the release of the bound metals was tested with or without aminoacids (penicillamine and histidine) in solutions of weak acidity or alkalinity. It was found an evident influence of the aminoacids to the metal release in dependence of metalcoating, metal-aminoacid-ratio and experimental pH. Especially in alkali environment a multiplication of the copper release (to a factor of 39 (pen) or 27 (his)) was observed. An increased nickel (factor 53) and cadmium release (factor 4.5) was found with histidine. In this cases 80 to 100% of the heavy metals were removed from the clay-mineral-surface.     

Effects of calcium,strontium, and magnesium on the coccolithophorid Cricosphaera (Hymenomonas) carterae. II. Cell division

The effects of calcium-deficiency, magnesium-deficiency and strontium enrichment on cell division in the alga Cricosphaera (Hymenomonas) carterae have been studied. Cell growth was reduced at 10^-3 M Ca and was absent at 5x10^-4 M Ca and lower concentrations. The addition of Sr to Ca-deficient media enabled cells to divide, the effect increasing with Sr concentration. When 4.6x10^-4 M Sr was added to media containing 10^-4 M Ca, the rate of division and the final cell concentration were comparable to the control (10^-2 M Ca). Strontium was 20 times more effective than Ca. The rate of growth was also examined at various Mg concentrations. Cell division was absent, or nearly so, in Mg concentrations below 4.2x10^-5 M. Cell size increased progressively as the Mg concentration decreased; however, the lowest protein concentration was found in the absence of Mg. In media lacking Mg, cells exhibited changes in ultrastructure including rounding-up and apparent fragmentation of chloroplasts and an increase in vacuole size. Also, the number of mitochondria per cell section increased 2.9 times in the absence of Mg while the total cross-sectional area remained the same, indicating fragmentation.     

Chemical mass balance model with fractionation for apportioning PM2.5: a test case for Los Angeles traffic sources

Chemical mass balance receptor models (CMBs) use measured pollutant concentrations, along with source information, to apportion the contributions of primary sources to the measured concentrations. CMBs can be used to evaluate the accuracy of the emission inventories that underlie State Implementation Plan (SIP) modeling, by providing an allocation of emissions to individual source categories. CMBs, however, traditionally have not accounted for the chemical reaction and differential deposition or fractionation that occur between the source and receptor. This means that they have historically had severe limitations in apportioning secondary particulate matter (PM), which is an especially important component of fine PM (PM2.5). Stafford and Liljestrand developed a method to account for fractionation in CMBs using depletion factors based on a solution of the steady-state advection-dispersion equation, including gravitational settling, dry deposition, and first-order chemical reaction.     

Identifying optimal agricultural countermeasure strategies for a hypothetical contamination scenario using the strategy model

A spatially implemented model designed to assist the identification of optimal countermeasure strategies for radioactively contaminated regions is described. Collective and individual ingestion doses for people within the affected area are estimated together with collective exported ingestion dose. A range of countermeasures are incorporated within the model, and environmental restrictions have been included as appropriate. The model evaluates the effectiveness of a given combination of countermeasures through a cost function which balances the benefit obtained through the reduction in dose with the cost of implementation. The optimal countermeasure strategy is the combination of individual countermeasures (and when and where they are implemented) which gives the lowest value of the cost function. The model outputs should not be considered as definitive solutions, rather as interactive inputs to the decision making process. As a demonstration the model has been applied to a hypothetical scenario in Cumbria (UK). This scenario considered a published nuclear power plant accident scenario with a total deposition of 1.7x10(14), 1.2x10(13), 2.8x10(10) and 5.3x10(9)Bq for Cs-137, Sr-90, Pu-239/240 and Am-241, respectively. The model predicts that if no remediation measures were implemented the resulting collective dose would be approximately 36 000 person-Sv (predominantly from 137Cs) over a 10-year period post-deposition. The optimal countermeasure strategy is predicted to avert approximately 33 000 person-Sv at a cost of approximately 160 million pounds. The optimal strategy comprises a mixture of ploughing, AFCF (ammonium-ferric hexacyano-ferrate) administration, potassium fertiliser application, clean feeding of livestock and food restrictions. The model recommends specific areas within the contaminated area and time periods where these measures should be implemented.     

Associations between grab sample and integrated radon measurements in dwellings in Maine and Texas

Radon concentrations were measured in several locations in each of approximately 100 dwellings in central Maine and in Houston, TX. Integrated samples were taken during the heating (or cooling) seasons with commercially available passive alpha track devices, while grab samples were taken at the time of integrated sampler deployment. It was found that both indoor and outdoor measurements in both areas were distributed log normally, and that the geometric mean of indoor measurements in Maine was three times higher than that of corresponding measurements in the Houston area. It was also noted that the mean of the indoor grab sample measurements was not significantly different from the mean of the indoor integrated measurements, and that the degree of correlation between the grab samples and a given indoor integrated sample was nearly as good as between integrated samples taken at different living area locations.