Carbonaceous resin capsule for vapor-phase monitoring of volatile hydrocarbons in soil: partitioning and kinetic model verification

The resin capsule system (RCS) was tested as a means of providing data on the presence and forms of volatile hydrocarbons. Results indicated that resin capsules provided data showing sensitivity to soil variables (texture and moisture content) and time. The objectives of this paper are to evaluate the RCS methodology and to determine whether carbonaceous resin capsules provide results that can be described by fundamental chemical partitioning and kinetic principles. Findings revealed a significant relationship between quantities of benzene, toluene, ethylbenzene, and xylene adsorbed on the capsule and quantities partitioned into the vapor phase. Kinetic evaluation indicated that the vapor adsorption by the resin capsule is regulated by diffusion processes. No verification of rate-limiting processes was possible due to limitations imposed by the experimental design, but it appears that during early stages, adsorption rate was limited by vapor diffusion through the soil. The resin capsule data also reflected differences that would be expected due to properties of the organic liquids present. These results provide further evidence that the RCS could be developed to suggest direct in situ monitoring to reveal quantities and nature of organic substances in soils.     

Degradation of ammonium dinitramide (ADN) in digested sewage sludge under strict anaerobic conditions

The biodegradation of one popular nitramine energetics, ammonium dinitramide (ADN) by mixture of denitrifying bacterial species was investigated. ADN was observed to be effectively mineralized in the anaerobic mixed culture. The initial ADN concentration of 250 mg/L was reduced to non‐detectable levels (> 99% removal efficiency) in 5 days of incubation under anaerobic conditions. Final products generated from anaerobic degradation of nitramine energetics by anaerobic metabolism were NH₄ ⁺, CH₄, and CO₂ that were released to the environment with the denitrifiers’ growth. In addition, it was found that the activity of denitrifiers was inhibited by high concentration of ammonia generated through the degradation reactions of energetic nitrites.     

Structural effect of the in situ generated titania on its ability to oxidize and capture the gas-phase elemental mercury

Structural effect of the in situ generated TiO(2) sorbent particle was examined for its ability to capture elemental mercury under UV irradiation in a simulated combustion flue gas. Titania particles were prepared by thermal gas-phase oxidation of Titanium (IV) isopropoxide (TTIP) using a high temperature electric furnace reactor. The structural characteristics of the in situ generated TiO(2) at various synthesis temperatures were investigated; size distribution and the geometric mean diameter were measured using a scanning mobility particle sizer, while fractal dimension and radius of gyration were evaluated from the transmission electron microscopy images. Results from the Hg(0) capture experiment show that with increasing titania synthesis temperature, the overall aggregate size increases and the morphology becomes more open-structured to gas-phase Hg(0) and UV light, resulting in the improved mercury removal capability.     

Synthesis of mesoporous magnesium oxide: Its application to CO2 chemisorption

Mesoporous magnesium oxide (MgO) was synthesized using mesoporous carbon CMK-3 obtained from mesoporous SBA-15 as exotemplate. P123 was used as the structure-directing template and rice husk ash (RHA) as the silica source for the synthesis of SBA-15, which was subsequently treated with sucrose and sulphuric acid to obtain mesoporous carbon (CMK-3). X-ray powder diffraction (XRD) results and the type-IV adsorption isotherm with H1 hysteresis obtained by N₂ adsorption/desorption study for SBA-15, CMK-3 and mesoporous MgO suggests its resemblance with materials synthesized using conventional silica sources. Mesoporous MgO was subjected for CO₂ adsorption study in TGA; adsorption was 8 and 10 wt% at 25 and 100 °C, respectively. Finally, mesoporous MgO is selective to CO₂ gas, thermally stable and regenerable. Thus, this study contributes a better route to enhance CO₂ gas adsorption and use ecological waste rice husk for the synthesis of such efficient mesoporous materials.     

Significance of anion exchange in pentachlorophenol sorption by variable-charge soils

Sorption data and subsequent predictive models for evaluating acidic pesticide behavior on variable-charge soils are needed to improve pesticide management and environmental stewardship. Previous work demonstrated that sorption of pentachlorophenol (PCP), a model organic acid, was adequately modeled by accounting for pH-and pKa-dependent chemical speciation and using two organic carbon-normalized sorption coefficients; one each for the neutral and anionic species. Such models do not account for organic anion interaction to positively charged surface sites, which can be significant for variable-charge minerals present in weathered soils typical of tropical and subtropical regions. The role of anion exchange in sorption of ionizable chemicals by variable-charge soils was assessed by measuring sorption of PCP by several variable-charge soils from aqueous solutions of CaCl2, CaSO4, Ca(H2PO4)2 as a function of pH. Differences in sorption from phosphate and chloride electrolyte solutions were attributed to pentachlorophenolate interactions with anion exchange sites. Suppression of PCP sorption by phosphate ranged from negligible in a soil with essentially no positively charge sites, as measured by negligible anion exchange capacity, to as much as 69% for variable-charge soils. Pentachlorophenolate exchange correlated well with the ratio of pH-dependent anion exchange capacity to net surface charge. Sorption reversibility of PCP by both CaCl2 and Ca(H2PO4)2 solutions was also demonstrated. Results for PCP clearly demonstrate that sorption to anion exchange sites in variable-charge soils should be considered in assessing pesticide mobility and that phosphate fertilizer application may increase the mobility of acidic pesticides.     

Nonparametric Monte Carlo Simulation for Flood Frequency Curve Derivation: An Application to a Korean Watershed1

Abstract: A mix of causative mechanisms may be responsible for flood at a site. Floods may be caused because of extreme rainfall or rain on other rainfall events. The statistical attributes of these events differ according to the watershed characteristics and the causes. Traditional methods of flood frequency analysis are only adequate for specific situations. Also, to address the uncertainty of flood frequency estimates for hydraulic structures, a series of probabilistic analyses of rainfall‐runoff and flow routing models, and their associated inputs, are used. This is a complex problem in that the probability distributions of multiple independent and derived random variables need to be estimated to evaluate the probability of floods. Therefore, the objectives of this study were to develop a flood frequency curve derivation method driven by multiple random variables and to develop a tool that can consider the uncertainties of design floods. This study focuses on developing a flood frequency curve based on nonparametric statistical methods for the estimation of probabilities of rare floods that are more appropriate in Korea. To derive the frequency curve, rainfall generation using the nonparametric kernel density estimation approach is proposed. Many flood events are simulated by nonparametric Monte Carlo simulations coupled with the center Latin hypercube sampling method to estimate the associated uncertainty. This study applies the methods described to a Korean watershed. The results provide higher physical appropriateness and reasonable estimates of design flood.     

Asbestos exposure among Seoul metropolitan subway workers during renovation of subway air-conditioning systems

Air quality in underground spaces has seldom been evaluated in Korea. Accordingly, the current study recently evaluated asbestos exposure among Seoul metropolitan subway workers during the renovation of the subway's air-conditioning system. To identify possible routes of asbestos exposure, suspected sources, including gaskets, ceiling boards, ceiling materials, and dust settled inside ducts, were all sampled. Personal air samples were also taken to evaluate any asbestos exposure during the renovation. The asbestos fibers found in the samples were analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer (EDX). Twelve out of eighteen bulk samples contained asbestos, the majority of which was chrysotile fibers. Asbestos was detected in 9 out of 72 personal air samples and the level ranged from 0.003 to 0.02 fibers/cm(3). While asbestos levels were below Korean occupational limit of 2 fibers/cm(3), they were still detectable and therefore further monitoring would be appropriate.     

Potential source of asbestos in non-asbestos textile manufacturing company

Recently, a worker with lung carcinoma and a metastatic brain tumor was diagnosed as having a work-related disease. He had been employed in a non-asbestos textile company for 25 years. Consequently, to identify and explore possible causative agents for lung cancer in a non-asbestos textile manufacturing company and establish a causal relationship between exposure and lung cancer, an epidemiological investigative study was conducted and the work processes the worker was engaged in were examined. Air samples were taken from the workplace and during the drilling processes, and a suspected causative material was analyzed. The study revealed that the subject had been employed in the non-asbestos textile manufacturing company for 25 years from 1973 and his responsibilities included repairing spinning machines. In particular, the subject was involved in drilling B-bushings that were used to protect against gear abrasion in the spinning machines. An analysis of the B-bushings using a transmission electron microscope equipped with an energy dispersive X-ray analyzer indicated that they contained crocidolite asbestos fibers. Air samples obtained when drilling the B-bushings clearly indicated that the subject had most likely been exposed to crocidolite fibers when installing the B-bushings in the spinning machines. The frequency and duration of the work suggested that there would be a sufficient degree of exposure to crocidolite fibers to cause lung cancer. Except for smoking and asbestos exposure, no other chemical exposure was suspected for developing lung cancer in the workplace. Smoking appeared to be more of a potentiating risk factor in conjunction with the asbestos exposure. Accordingly, this case may provide significant evidence in identifying the cause of the mesothelioma or lung carcinoma found among workers in non-asbestos textile manufacturing companies elsewhere.     

A review of source tracking techniques for fine sediment within a catchment

Excessive transport of fine sediment, and its associated pollutants, can cause detrimental impacts in aquatic environments. It is therefore important to perform accurate sediment source apportionment to identify hot spots of soil erosion. Various tracers have been adopted, often in combination, to identify sediment source type and its spatial origin; these include fallout radionuclides, geochemical tracers, mineral magnetic properties and bulk and compound-specific stable isotopes. In this review, the applicability of these techniques to particular settings and their advantages and limitations are reviewed. By synthesizing existing approaches, that make use of multiple tracers in combination with measured changes of channel geomorphological attributes, an integrated analysis of tracer profiles in deposited sediments in lakes and reservoirs can be made. Through a multi-scale approach for fine sediment tracking, temporal changes in soil erosion and sediment load can be reconstructed and the consequences of changing catchment practices evaluated. We recommend that long-term, as well as short-term, monitoring of riverine fine sediment and corresponding surface and subsurface sources at nested sites within a catchment are essential. Such monitoring will inform the development and validation of models for predicting dynamics of fine sediment transport as a function of hydro-climatic and geomorphological controls. We highlight that the need for monitoring is particularly important for hilly catchments with complex and changing land use. We recommend that research should be prioritized for sloping farmland-dominated catchments.