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991.
Risk to humans of consuming metals in anchovy (<Emphasis Type="Italic">Coilia</Emphasis> sp.) from the Yangtze River Delta 总被引:1,自引:0,他引:1
Fengyan Liu Jiachun Ge Xin Hu Teng Fei Yuehua Li Yuan Jiang Zhiqiang Xu Shuyan Ding John P. Giesy 《Environmental geochemistry and health》2009,31(6):727-740
Concentrations of metals were determined in four species of anchovy (Coilia sp.) from the Yangtze River, Taihu Lake, and Hongze Lake in Jiangsu Province, China. Concentrations of Cr in anchovy fish
muscle ranged from 2.6 × 10−2 to 5.0 mg/kg ww, and Coilia nasus taihuensis in Jiaoshan, Taihu Lake contained the highest concentrations of Cr, which was almost 111-fold higher than the mean value
at other locations. Concentrations of Pb ranged from 1.5 × 10−2 to 1.3 × 10−1 mg/kg ww. Comparisons of concentrations of lead (Pb) among the four species indicated that anadromous species contained higher
concentrations of Pb than did freshwater species. However, concentrations of Pb in C. nasus from the Nanjing and Haimen locations in the Yangtze River were not significant higher than those of two freshwater species:
C. nasus taihuensis from Taihu Lake and C. brachygnathus from Hongze Lake (Duncan’s test, α = 0.05). While concentrations of Cd and Zn ranged from 7.0 × 10−4 to 3.6 × 10−3 mg/kg ww and 3.4 to 4.8 mg/kg ww, respectively, there were no significant differences in concentrations among the eight locations.
The only concentration of the metals studied that exceeded the Chinese National Standard was Cr in Coilia from Jiaoshan, Taihu Lake, which was 2.5-fold higher than the standard. These results indicate that people who consume the
genus Coilia are not at risk due to concentrations of metals, except Cr in C. nasus taihuensis from Jiaoshan in Taihu Lake. Concentrations of all of the metals studied except for Cr were similar to or less than those
of metals in most other areas in the world. 相似文献
992.
Comparative study of the fate and mobility of metals discharged in mining and urban effluents using sequential extractions on suspended solids 总被引:1,自引:0,他引:1
Christian Gagnon Patrice Turcotte Bernard Vigneault 《Environmental geochemistry and health》2009,31(6):657-671
The fate, bioavailability and environmental impacts of metals discharged in municipal and mining wastewater discharge will
depend to a large extent on chemical speciation and distribution. Previous studies on metal bioaccumulation have shown that
total metal concentrations are not a good predictor of bioavailability in the dispersion plumes of municipal effluents. The
objective of this study was to determine the solid phase speciation of metals in surface waters receiving urban and mining
effluents in order to assess their fate and relative mobility in the receiving environment. Suspended particulate matter was
sampled using sediment traps at several sites downstream of effluent outfall plumes as well as at reference upstream sites.
Particulate metal in operationally defined fractions—exchangeable/carbonates, reducible, oxidisable and residual—were determined
in suspended particulate matter with a series of selective chemical extractions. Metal enrichment in suspended particles was
generally observed in both mining and urban effluent discharges. When compared to its receiving environment, the mining effluent
appeared to release more particulate metals (Cu, Fe, Zn) in the most reactive fractions (i.e. exchangeable/carbonates + reducible
forms, 23–43%), while other released metals, such as Cd and Mn, were predominantly in the least reactive forms (i.e., oxidisable + residual,
73–97%). In contrast, the reactivity of all particulate metals, with the exception of Mn, from the urban effluent was much
higher, with up to 65, 42, 30 and 43% for Cd, Cu, Fe and Zn, respectively, in the two most reactive fractions. As expected
in effluent dispersion plumes, parameters such as the organic carbon, Fe oxide and carbonate contents have specific effects
on the partitioning of several trace metals, particularly Cd, Cu and Zn. Our results indicated that the relative distributions
of metals among geochemical fractions varied in the effluent receiving waters where organic carbon and Fe oxides appeared
as the most important parameters. This could therefore decrease the exposure for aquatic organisms that are exposed to those
contaminated sediments as well as the risk to human health. 相似文献
993.
Graham Bird Mark G. Macklin Paul A. Brewer Sorin Zaharia Dan Balteanu Basarab Driga Mihaela Serban 《Environmental geochemistry and health》2009,31(6):741-758
Groundwater, accessed using wells and municipal springs, represents the major source of potable water for the human population
outside of major urban areas in northwestern Romania, a region with a long history of metal mining and metallurgy. The magnitude
and spatial distribution of metal contamination in private-supply groundwater was investigated in four mining-affected river
catchments in Maramureş and Satu Mare Counties through the collection of 144 groundwater samples. Bedrock geology, pH and
Eh were found to be important controls on the solubility of metals in groundwater. Peak metal concentrations were found to
occur in the Lapuş catchment, where metal levels exceed Dutch target and intervention values in up to 49% and 14% of samples,
respectively. A 700 m wide corridor in the Lapuş catchment on either side of the main river channel was identified in which
peak Cd (31 μg l−1), Cu (50 μg l−1), Pb (50 μg l−1) and Zn (3,000 μg l−1) concentrations were found to occur. Given the generally similar bedrock geologies, lower metal levels in other catchments
are believed to reflect differences in the magnitude of metal loading to the local environment from both metal mining and
other industrial and municipal sources. Sampling of groundwater in northwestern Romania has indicated areas of potential concern
for human health, where heavy metal concentrations exceed accepted environmental quality guidelines. The presence of elevated
metal levels in groundwater also has implications for the implementation of the EU Water Framework Directive (WFD) and achieving
‘good’ status for groundwater in this part of the Danube River Basin District (RBD). 相似文献
994.
The concentration of uranium was determined in 944 samples from stream water by the inductively coupled plasma quadrupole
mass spectrometry (ICP-QMS) method and represented on a color-shaded contour map. Uranium concentrations in surface water
were determined to be between 0.007 μg/l and 43.7 μg/l with median of 0.33 μg/l. The regional distribution of uranium is influenced
primarily by lithological and anthropogenic factors. In Mecklenburg, northern Brandenburg, and eastern Schleswig-Holstein,
elevated uranium concentrations coincide with the extent of the last Weichselian ice sheet. The maximum concentrations are
observed in the surface waters of the old mining districts in the western part of the Ore Mountains and in eastern Thuringia.
Elevated concentrations are found in areas of agriculturally used loess soils. These concentrations correlate with the use
of phosphate fertilizers. There is a zone of elevated concentrations up to 10.0 μg U/l in the Keuper Sandstone area south
of the Thuringian Forest and from northwest of Stuttgart as far as Coburg. The distribution of elevated values in mineral
water shows a clear correlation with the elevated values in surface water and the geology of those locations. Bunter and Keuper
strata are the most important uranium source. 相似文献
995.
Mixtures can be divided into simple (chemicals with comparable properties—health risk assessments on the chemicals) and complex,
which can be further subdivided into defined (a reasonably distinct composition, created at a specific time and place despite
dissimilar components—risk assessments on the common source) and coincidental (chemicals without similar properties or constant
composition in time or space—risk assessments on the receptor). Interactions recognized are: independent action, dose addition
(additivity), and potentiation (synergy and antagonism). Unpredicted outcomes need recognition. New approaches in higher education
and multidisciplinary investigations are essential. The community of the Society for Environmental Geochemistry and Health
should help clarify points such as when transformations in mixtures may become important enough to alter the classification
and the risk assessment. The multidisciplinary community is also well placed to support the integration of nonchemical influences
into mixture analysis and to contribute to the investigation of cumulative and multiple exposures. 相似文献
996.
Natural muds used as or in cosmetics may expose consumers to toxic metals and elements via absorption through the skin, inhalation
of the dried product, or ingestion (by children). Despite the extensive therapeutic and cosmetic use of the Dead Sea muds,
there apparently has been no assessment of the levels of such toxic elements as Pb, As, or Cd in the mud and mud-based products.
Inductively coupled plasma mass spectrometry analysis of eight toxic elements in samples collected from three black mud deposits
(Lisan Marl, Pleistocene age) on the eastern shore of the Dead Sea in Jordan revealed no special enrichment of toxic elements
in the mud. A similar analysis of 16 different commercial Dead Sea mud cosmetics, including packaged mud, likewise revealed
no toxic elements at elevated levels of concern. From a toxic element standpoint, the Dead Sea black muds and derivative products
appear to be safe for the consumer. Whatever the therapeutic benefits of the mud, our comparison of the elemental fingerprints
of the consumer products with those of the field samples revealed one disturbing aspect: Dead Sea black mud should not be
a significant component of such items as hand creams, body lotions, shampoo, and moisturizer. 相似文献
997.
Fluoride concentration of groundwater reserves occurs in many places in the world. A critical area for such contamination
in India is alluvial soil of the plain region, consisting of five blocks (Jhajjar, Bahadurgarh, Beri, Matanhail, and Sahalawas)
of the Jhajjar District adjacent to the National Capital Territory of India, New Delhi. The purpose of this study was to assess
the association between water fluoride levels and prevalence of dental fluorosis among school children of the Jhajjar District
of Haryana, India. The fluoride content in underground drinking water sources was found to vary in villages. Hence, the villages
were categorized as high-fluoride villages (1.52–4.0 mg F/l) and low/normal-fluoride villages (0.30–1.0 mg F/l). The source
of dental fluorosis data was school-going children (7–15 years) showing different stages and types of fluorosis who were permanent
resident of these villages. The fraction of dental fluorosis-affected children varied from 30% to 94.85% in the high-fluoride
villages and from 8.80% to 28.20% in the low/normal-fluoride villages. The results of the present study revealed that there
existed a significant positive correlation between fluoride concentration in drinking water and dental fluorosis in high-fluoride
villages (r = 0.508; p < 0.001) and insignificant correlation in low-fluoride villages. 相似文献
998.
Characterization of Santa Catarina (Brazil) coal with respect to human health and environmental concerns 总被引:1,自引:0,他引:1
Silva LF Oliveira ML da Boit KM Finkelman RB 《Environmental geochemistry and health》2009,31(4):475-485
The current paper presents the concentration, distribution, and modes of occurrence of trace elements of 13 coals from south
Brazil. The samples were collected in the state of Santa Catarina. Chemical analyses and the high ash yields indicate that
all studied coals are rich in mineral matter, with SiO2 and Al2O3 dominating as determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES). Quartz is the main mineral
species and is associated with minor levels of feldspars, kaolinite, hematite, and iron-rich carbonates. The contents of trace
elements, including As, Pb, Cd, Ni, Cr, Mn, Be, V, U, Zn, Li, Cu, Tl, and Ni, in coals were determined. A comparison of ranges
and means of elemental concentrations in Santa Catarina, Brazil, and world coals shows that the ranges of most elements in
Santa Catarina coal are very close to the usual worldwide concentration ranges in coal. 相似文献
999.
To understand trace radionuclide (uranium) migration occurring in rocks, a granitic batholith located at the Korea Atomic
Energy Research Institute (KAERI) site was selected and investigated. The rock samples obtained from this site were examined
using mineralogical methods, including scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The changes
in the distribution pattern of uranium (U) and small amounts of trace elements, and the mineralogical textures affected by
weathering, were examined. Based on the element distribution analyses, it was found that Fe2+ released from fresh biotite is oxidized in short geological time, forming amorphous iron oxides, such as ferrihydrite, around
silicate minerals. In that case, the amorphous ferrihydrite does not show distinct adsorption for U. However, as it gradually
crystallizes to goethite or hematite, the most U-rich phases were found to be associated with the secondary iron oxides having
granular forms. This evidence suggests that the geological subsurface environment is favorable for the crystallized iron oxides
to keep their structures more stable for a long time as compared with the amorphous phases. There is a possibility that the
long residence of U which is in contact with the stable crystalline phases of iron may finally lead to the partial sequestration
of U in their structure. Consequently, it seems that Fe-oxide crystallization can be a dominating mechanism for U uptake and
controls long-term U transport in granites with low U contents. 相似文献
1000.
Arsenite [As(III)]-oxidizing bacteria play important roles in reducing arsenic [As] toxicity and mobility in As-contaminated
areas. As-resistant bacteria were isolated from the soils of two abandoned mines in the Republic of Korea. The isolated bacteria
showed relatively high resistances to As(III) up to 26 mM. The PCR-based 16S rRNA analysis revealed that the isolated As-resistant
bacteria were close relatives to Serratia marcescensa, Pseudomonas putida, Pantoea agglomerans, and Alcaligenes sp. Among the five As-resistant bacterial isolates, Alcaligenes sp. strain RS-19 showed the highest As(III)-oxidizing activity in batch tests, completely oxidizing 1 mM of As(III) to As(V)
within 40 h during heterotrophic growth. This study suggests that the indigenous bacteria have evolved to retain the ability
to resist toxic As in the As-contaminated environments and moreover to convert the species to a less toxic form [e.g., from
As(III) to As(V)] and also contribute the biogeochemical cycling of As by being involved in speciation of As. 相似文献