Assessing the recycling potential of industrial wastewater to replace fresh water in concrete mixes: application of polyvinyl acetate resin wastewater

This study presents the use of industrial wastewater released from polyvinyl acetate resin manufacturing plant to totally replace the fresh water in concrete composites. Seventy-two laboratory prepared concrete composites were tested to investigate the effect of using various PVAW/C ratios of 0.30, 0.35, 0.40, and 0.45 on the slump, compressive strength, flexural strength, and dry density of the concrete mixes. Results indicated a slight to moderate increase in compressive strength and hard density values compared to those of the control concrete made with fresh water at 7 and 28 day curing. On the contrary, a reduction in the slump values of the PVAW–concrete was observed compared to the slump of the control mixes. However, the slump values increased with increasing the PVAW/C ratios. On the other hand, the waste material leaching test revealed that none of the PVAW toxic constituents was detected. The findings of this work would form basic information for recycling PVAW in concrete mixes and indicate a potential alternative for diminution the adverse effects on the environment posed by the hazardous effluent of the polyvinyl acetate resin industry.     

Heavy metals in freshwater snails of Kuala Klawang's rice field,Negeri Sembilan,Malaysia

A study of heavy metal contents in freshwater snails from rice fields have been made. The results indicate that the levels of heavy metals, Pb, Cu, Zn and Cd, are low and within the permissible limit of Malaysian Food Regulations. The results can serve as background data for further reference.     

Virtual water trade in industrial products: evidence from Malaysia

Virtual water embodied in international trade is equivalent to nearly one-third of global water withdrawal, confirming that trade plays a significant role in redistributing global water resources. This paper extends a virtual water analysis by measuring the extent to which virtual water embodied in traded industrial products affects the distribution of global virtual water. The distribution of global virtual water can be improved if trade in industrial products promotes virtual water outflows from water-abundant to water-scarce countries. Analyses were performed using an input–output model that can decompose water consumption into domestic demand and exports by destinations of trade. Focusing on Malaysia, the results indicate that trade in industrial products between Malaysia and its main trading partners have a limited capacity to improve the distribution of global virtual water. This limitation can be due to two reasons. Firstly, exports of Malaysian industrial products are mainly driven by less water-intensive sectors. Therefore, the amount of virtual water that outflows into other countries is also low. Secondly, trade in Malaysian industrial products largely involves water flows with other water-abundant countries. Only several water-scarce countries benefit from virtual water trade in industrial products with Malaysia, namely the Netherlands, Australia and China.     

Effects of metsulfuron‐methyl on microbial biomass and populations in soils

Abstract

Effects of the herbicide metsulfuron‐methyl on soil microorganisms and their activities in two soils were evaluated under laboratory conditions. Measurements included their populations, soil respiration, and microbial biomass. In the clay soil, bacterial populations decreased with increasing concentration of metsulfuron‐methyl during the first 9 days of incubation but exceeded that of the control soil from day 27 onward. In the sandy loam soil, the herbicide reduced bacterial populations during the first 3 days after application, but these increased to the level of untreated controls after 9 days’ incubation. Fungal populations in both soils increased with increasing metsulfuron‐methyl concentrations, especially in the sandy loam soil. CO₂ evolution was stimulated in both soils in the presence of the herbicide initially, but decreased during days 3 to 9 of the incubation period before increasing again afterward. The presence of metsulfuron‐methyl in the soil increased microbial biomass, except in sandy loam soil at the first day of incubation.     

Assessing different sources of uncertainty in hydrological projections of high and low flows: case study for Omerli Basin,Istanbul, Turkey

This study investigates the assessment of uncertainty contribution in projected changes of high and low flows from parameterization of a hydrological model and inputs of ensemble regional climate models (RCM). An ensemble of climate projections including 15 global circulation model (GCM)/RCM combinations and two bias corrections (change factor (CF) and bias correction in mean (BC)) was used to generate streamflow series for a reference and future period using the Hydrologiska Byråns Vattenbalansavdelning (HBV) model with the 25 best-fit parameter sets based on four objective functions. The occurrence time of high flows is also assessed through seasonality index calculation. Results indicated that the inputs of hydrological model from ensemble climate models accounts for greater contribution to the uncertainty related to projected changes in high flows comparing to the contribution from hydrological model parameterization. However, the uncertainty contribution is opposite for low flows, particularly for CF method. Both CF and BC increases the total mean variance of high and low flows. The variability in the occurrence time of high flows through RCMs is greater than the variability resulted from hydrological model parameters with and without statistical downscaling. The CF provides more accurate timing than BC and it shows the most pronounced changes in flood seasonality.     

Risk-optimal highway design: Methodology and case studies

Highway geometric design in mountainous areas has been a typical challenge. The combination of short horizontal curves and restricted right-of-way is a common ground for contemplating design exception in British Columbia, Canada. In practice, collision modification factors (CMFs) are advocated as quantitative measures of changes in road features on safety. However, in many situations, there are no CMFs in the literature to predict the safety impact of changing particular road features. An important example of these road features is sight distance restriction on horizontal curves. A mechanism for risk measurement has been proposed in earlier work to assist designers in comparing the safety impact of different deviations from sight distance requirements. This paper attempts to answer the questions as to whether it is possible to reduce overall risk and achieve consistency in such reduction without demanding wider right-of-way. This problem was formulated in a multi-objective optimization framework. Following this methodology, it was possible to achieve an average reduction in risk of 25% on the nine critical cross-sections. This reduction in risk was achieved without demanding wider right-of-way and without creating measurable increase in expected collision frequency due to independent re-dimensioning of different geometric elements. On theoretical grounds, this paper represents another step into the direction of developing fully probabilistic geometric design standards. On practical grounds, this paper provides an important decision mechanism that enables the efficient use of available right-of-way for new highway construction. Case studies in this paper have been applied on a major highway development in British Columba, Canada.     

Allozyme polymorphisms and heavy metal levels in the green-lipped mussel Perna viridis (Linnaeus) collected from contaminated and uncontaminated sites in Malaysia

It has been widely reported that heavy metal contamination in coastal waters can modify the allozyme profiles of marine organisms. Previous studies have recorded elevated metal concentrations in sediments and mussel tissues off Peninsular Malaysia. In the present study, horizontal starch gel electrophoresis was carried out to estimate the levels of allelic variation of the green-lipped mussel, Perna viridis, collected from one contaminated and three relatively uncontaminated sites off Peninsular Malaysia. Fourteen polymorphic loci were observed. In addition, the concentrations of cadmium, copper, lead, mercury and zinc were determined in the sediments and in the soft tissues of the mussels. Mussels from contaminated site, evidenced by high metal pollution indices (MPI) of the sediment and the mussel tissues, showed the highest percentage of polymorphic loci (78.6%), while those collected from the uncontaminated sites had lower MPI of the sediment and mussel tissue, and exhibited lower percentages of polymorphic loci (35.7-57.1%). The population from the contaminated site showed the highest excess of heterozygosity (0.289) when compared to that of the populations from the three uncontaminated sites (0.108-0.149). Allozyme frequencies at the phosphoglucomutase (PGM; E.C. 2.7.5.1) locus also differed between the contaminated and uncontaminated populations. Previous studies have shown that exposure to heavy metals can select or counter-select for particular alleles at this locus. The present results suggest that allozyme polymorphism in P. viridis is a potential biomonitoring tool for heavy metal contamination but further validation is required.