News from the SETAC Europe Student Advisory Council - September 2012

The Student Advisory Council is the speaking tube of SETAC Europe??s students aiming to support young researchers in becoming fully-fledged members of the Society. In this article we report our latest activities during the 6^th SETAC World Congress/SETAC Europe 22^nd Annual Meeting in Berlin, Germany, and the upcoming 3^rd Young Environmental Scientists (YES) Meeting in Krakow, Poland.     

Macrofauna diversity in<Emphasis Type="Italic"> Posidonia oceanica</Emphasis> detritus: distribution and diversity of mobile macrofauna in shallow sublittoral accumulations of<Emphasis Type="Italic"> Posidonia oceanica</Emphasis> detritus

The mobile macrofauna in submerged detritus accumulations (SDAs) of the seagrass Posidonia oceanica was investigated in the Bay of Calvi, Corsica, Mediterranean Sea. The distribution of the macrofauna was related to the exposure of the habitat and to the degree of packing and decomposition of the SDAs. In the less decomposed, younger SDAs, the number of individuals per species, but also species richness, was relatively low. In the more decomposed, older SDAs, the abundance and number of species increased, showing predominance of a few crustacean taxa such as gammaridean amphipods, shrimps and the leptostracan Nebalia bipes. Many of the macrofaunal species in the SDAs are members of the animal communities of surrounding seagrass meadows or adjacent hard or soft bottoms, while others, like N. bipes, apparently live in closer association with the SDAs.Communicated by O. Kinne, Oldendorf/Luhe     

Mobilität von Nitroaromaten im Sandstein infolge Schwefelsäureeintrag zur Uranlaugung

As a result of former in situ leaching activities with sulfphuric acid, nitroaromatic compounds have invaded into cenomanian and turonian sandstone aquifers and mining waters in parts of the uranium mining of Königstein, Germany (Saxony). In the mining area contamination levels of nitrobenzene, mononitrotoluene and dinitrotoluene lead to a partial excess in the drining water guide values. For environmental protection, control and remediation efforts by flooding, more knowledge about contaminant mobility in sandstone, and in intercalated clays and silts, is demanded. A selected experimental area has been flooded to realize and study transport processes under real mining conditions. In this work, we have examined the mobilization of nitroaromatic compounds by flooding waters. The interactions between the nitroaromatic compounds, which are dissolved in the mining water, and the host rocks are discussed. The existing data for strata of varying lithologic conditions suggest that the sorption processes of the compounds investigated are negligible in pure sandstone aquifer layers and significant in the lithologic conditions with a complex mixture of mudstone, siltstone and clay. Several lithologic conditions are demonstrated in contaminant sinks and sources caused by adsorption processes and mobilization of newly connected stagnant pore waters.     

Determination of deployment specific chemical uptake rates for SDB-RPD Empore disk using a passive flow monitor (PFM)

The use of the adsorbent styrenedivinylbenzene-reverse phase sulfonated (SDB-RPD) Empore disk in a chemcatcher type passive sampler is routinely applied in Australia when monitoring herbicides in aquatic environments. One key challenge in the use of passive samplers is mitigating the potentially confounding effects of varying flow conditions on chemical uptake by the passive sampler. Performance reference compounds (PRCs) may be applied to correct sampling rates (R_s) for site specific changed in flow and temperature however evidence suggests the use of PRCs is unreliable when applied to adsorbent passive samplers. The use of the passive flow monitor (PFM) has been introduced for the assessment of site-specific changes in water flow. In the presented study we have demonstrated that the R_s at which both atrazine and prometryn are accumulated within the SDB-RPD-Empore disk is dependent on the flow conditions. Further, the calibration of the measured R_s for chemical uptake by the SDB-RPD-Empore disk to the mass lost from the PFM has shown that the PFM provides an accurate measure of R_s for flow velocities from 0 to 16 cm s⁻¹. Notably, for flow rates >16 cm s⁻¹, a non linear increase in the R_s of both herbicides was observed which indicates that the key resistance to uptake into the SDB-RPD Empore disk is associated with the diffusion through the overlying diffusion limiting membrane. Overall the greatest uncertainty remains at very low flow conditions, which are unlikely to often occur in surface waters. Validation of the PFM use has also been undertaken in a limited field study.     

The performance of passive flow monitors and phosphate accumulating passive samplers when exposed to pulses in external water flow rate and/or external phosphate concentrations

Passive samplers are typically calibrated under constant flow and concentration conditions. This study assessed whether concentration and/or flow pulses could be integrated using a phosphate passive sampler (P-sampler). Assessment involved three 21-day experiments featuring a pulse in flow rate, a pulse of filterable reactive phosphate (FRP) concentration and a simultaneous concentration and flow pulse. FRP concentrations were also determined by parallel grab sampling and the P-sampler calibrated with passive flow monitors (PFMs) and direct measurement of flow rates. The mass lost from the PFM over the deployment periods predicted water velocity to within 5.1, 0.48 and 7.1% when exposed to a flow rate pulse (7.5-50 cm s⁻¹), concentration pulse (5-100 μg P L⁻¹), or both simultaneously. For the P-sampler, good agreement was observed between the grab and passive measurements of FRP concentration when exposed to a pulse in flow (6% overestimation) or concentration (2% underestimation).     

Intra- and inter-annual variability of VOC emissions from natural and semi-natural vegetation in Europe and neighbouring countries

Biogenic VOC emission estimates from the earth's surface are crucial input parameters in air quality models. Knowledge accumulated in the last years about BVOC source distributions and chemical compound species emission profiles in Europe as well as the demand of air quality modellers for a finer resolution in space and time of BVOC estimates have led to the set-up of new emission modelling systems. An updated fast BVOC emission modelling platform explicitly considering the seasonality of emission potentials and leaf temperature gradients in forest canopies by the semi-empirical emission module (seBVOC) will be proposed and used for estimating hourly values of chemical compound-specific emissions in Europe (33–68° north; 10° west to 40° east) in the years 1997, 2000, 2001, and 2003. Spatial resolution will be 10 km by 10 km. The database used contains latest land and forest distributions, updated foliar biomass densities, leaf area indices (LAI), and plant as well as chemical compound-specific emission potentials, if available. Meteorological input parameters for the respective years will be generated using the non-hydrostatic meteorological model MM5. Highest BVOC emissions occur in daytime hours around noon from the end of May to mid-August in the Mediterranean area and from the mid of June to the end of July in the boreal forests. Comparison of 3 BVOC model approaches will reveal that for July 2003, the European isoprene and monoterpene totals range from 1124 Gg to 1446 Gg and from 338 Gg to 1112 Gg, respectively. Small-scale deviations may be as high as ±0.6 Mg km^?2 for July 2003, reflecting the current uncertainty range for BVOC estimates. Key sources of errors in inventories are still insufficiently detailed land use data for some areas and lacking chemically speciated plant-specific emission potentials in particular in boreal, south-eastern, and northern African landscapes. The hourly emissions of isoprene, speciated terpenes, and oxyVOC have been made available by the NatAir database.     

Participatory Impact Assessment of Soil and Water Conservation Scenarios in Oum Zessar Watershed, Tunisia

Environmental threats and progressive degradation of natural resources are considered critical impediments to sustainable development. This paper reports on a participatory impact assessment of alternative soil and water conservation (SWC) scenarios in the Oum Zessar watershed, Tunisia. The first objective was to assess the impact of three SWC scenarios on key social, economic and environmental land use functions. The second objective was to test and evaluate the applicability of the 'Framework for Participatory Impact Assessment (FoPIA)' for assessing scenario impacts in the context of a developing country, in this case Tunisia. The assessed scenarios included: the originally planned SWC policy implementation at 85 % coverage of arable land of the watershed, the current implementation (70 %), and a hypothetical expansion of SWC measures to the entire watershed (100 %). Our results suggest that implementation of the SWC policy at 100 % coverage of arable land achieves the maximum socioeconomic benefit. However, if stakeholders' preferences regarding land use functions are taken into account, and considering the fact that the implementation of SWC measures also implies some negative changes to traditional landscapes and the natural system, SWC implementation at 85 % coverage of arable land might be preferable. The FoPIA approved to be a useful tool for conducting a holistic sustainability impact assessment of SWC scenarios and for studying the most intriguing sustainability problems while providing possible recommendations towards sustainable development. We conclude that participatory impact assessment contributes to an enhanced regional understanding of key linkages between policy effects and sustainable development, which provides the foundation for improved policy decision making.     

Assessment of the natural attenuation of chlorinated ethenes in an anaerobic contaminated aquifer in the Bitterfeld/Wolfen area using stable isotope techniques, microcosm studies and molecular biomarkers

The in situ degradation of chlorinated ethenes was assessed in an anaerobic aquifer using stable isotope fractionation approaches, microcosm studies and taxon specific detection of specific dehalogenating groups of bacteria. The aquifer in the Bitterfeld/Wolfen region in Germany contained all chlorinated ethenes, benzene and toluene as contaminants. The concentrations and isotope composition of the chlorinated ethenes indicated biodegradation of the contaminants. Microcosm studies confirmed the presence of in situ microbial communities capable of the complete dechlorination of tetrachloroethene. Taxon specific investigation of the microbial communities indicated the presence of various potential dechlorinating organisms including Dehalococcoides, Desulfuromonas, Desulfitobacterium and Dehalobacter. The integrated approach, using metabolite spectra, molecular marker analysis and isotope studies, provided several lines of evidence for natural attenuation of the chlorinated ethenes.