ISO14000环境管理标准对我国企业发展的促进作用

ISO14000环境管理系列标准是国际标准化组织制定的关于环境管理体系的国际通用标准。目的在于激发企业自觉采取预防措施和持续性改善措施来改善环境。推行ISO14000认证不仅可以规范环境管理行为,而且提高绿色管理水平和资源利用效率,从而促进中国经济发展。需要政府进一步采取积极措施推广ISO14000环境管理体系认证。     

中国科学院环境科技发展回顾(Ⅰ)

对中国科学院自1949年建院之初至知识创新工程试点工作启动之前的1997年这段时间内,中科院在环境科学研究和技术创新、队伍建设、科技基础设施建设、规划与管理等方面的工作进行了介绍.从1949年至1997年,中科院的环境科技工作经历了思想萌芽、初步发展、快速发展和稳定发展等四个发展阶段.从1998年开始,中科院的环境科技工作进入创新跨越阶段,更加注重环境污染形成机理、生态毒理等方面的原始创新和清洁生产前沿关键技术的突破与集成.     

稀土系列催化剂对焦化废水的催化湿式氧化

以稀土元素Ce制得催化剂系列 ,在高温高压条件下对焦化废水进行催化湿式氧化研究 ,考察载体、焙烧温度、活性组分的配比对催化剂的催化活性的影响以及反应温度、氧气分压、反应时间和催化剂用量对氧化过程的影响 ,设计正交实验确定最佳的工艺参数反应温度为 2 4 0℃、氧气分压 3 .0MPa ,催化剂用量 30 g/L ,此时废水的COD去除率达到 90 %以上。     

江苏盱眙金矿化带的基本特征及找矿远景

江苏盱眙金矿化带位于古桑乡石牛山-小团山一带,根据土壤和基岩的化探资料,确定了6个金异常点;通过1:1万地质草测,确定了区内矿化带的空间分布、规模和产状.金矿化主要与南北向断裂有关.围岩蚀变主要有硅化、碳酸盐化及褐铁矿化.金矿化可分两类:一是破碎蚀变岩型,二是侵入接触带型.前者是在地层间的平缓碎裂岩和糜棱岩带,具泥化或红土化现象;后者系岩体与地层接触,形成硫化物或铁帽.盱眙一带金矿找矿前景以断裂附近的岩浆岩体侵入接触带为好.     

钼酸盐复合缓蚀剂对海水中碳钢缓蚀性及机理研究

采用失重法、电极化法和X-射线光电子能谱XPS技术对钼酸盐复合缓蚀剂的缓蚀性及缓蚀机理进行了研究。实验结果表明:单一钼酸盐对海水中碳钢的缓蚀率随着钼酸盐使用浓度的增加而增加,但低浓度使用缓蚀率较低。通过失重法确定了与钼酸盐有较好协同效应的缓蚀剂配方-钼酸盐、柠檬酸钠、有机膦酸盐(HEDP)和锌盐,当缓蚀剂各组分浓度分别为10mg/L、40mg/L、10mg/L和4mg/L时,该缓蚀剂对海水中碳钢的缓蚀率超过93%。动电位极化曲线测试结果表明:单一钼酸盐缓蚀剂和钼酸盐复合缓蚀剂均为抑制阳极反应为主的阳极型缓蚀剂;X-射线光电子能谱XPS实验结果表明:添加了缓蚀剂的碳钢表面形成了以氧化铁和有机铁络合物为主要成分,钼与磷也参与成膜的不溶性沉淀膜,有效的抑制了海水对碳钢表面的腐蚀。     

Environmental fate and behavior of silver nanoparticles in natural estuarine systems

Silver nanoparticles (AgNPs) are widely used in many consumer products, whereas their environmental behaviors in natural aquatic systems remain unknown, especially in natural brackish media. Therefore, it is urgent to investigate the environmental fate of AgNPs in natural brackish waters. Here, we investigated the stability of citrate-coated AgNPs in natural brackish water collected from 6 different sites with distinct salinities in the Xinglinwan Reservoir, located in Xiamen City, southeast China. The obtained results showed that AgNP colloids remained stable in low-salinity waters, which was mainly determined by the effects of dissolved organic matter (DOM) promoting the stability of the nanoparticles. However, the environmental fate of AgNPs in high-salinity waters was dominated by the salinity or ionic strength, especially the free ion concentrations of Cl^?, SO₄^2?, or S^2?, resulting in rapid sedimentation and dissolution. In addition, both DOM and salinity contributed to the environmental behavior of AgNPs in moderate-salinity waters, ultimately resulting in either colloidal stability or sedimentation. Overall, these results may reveal that AgNPs remain relatively stable for a long period in low-salinity natural waters, and that the stability might gradually decrease as AgNPs are transferred from freshwaters through brackish waters and eventually end up in seawater along the bay. Our findings also further indicate that the toxicity and potential risks of AgNPs may present more serious threats to the environment and organisms in natural freshwaters than in natural estuarine systems or seawater.     

野外模拟扰动方式对太湖浮游植物群落结构的影响

浮游植物是水生生态系统的重要生产者,扰动是水体的固有特征.为探究扰动方式对浮游植物的影响,通过野外模拟试验探讨不同扰动方式（持续扰动和间歇扰动）对太湖浮游植物的影响,并在试验期间测定各扰动条件下浮游植物生长和群落结构变化情况.结果表明:①对照组、间歇扰动组和持续扰动组中浮游植物平均生物量分别为5.92、19.42、58.27 mg/L,平均细胞密度为1.06×108、1.23×108、3.48×108 L-1,持续扰动组浮游植物生物量和细胞密度显著高于对照组和间歇扰动组.②在间歇扰动组中,浮游植物优势种始终是微囊藻,其占比平均值为84.61%;对照组和持续扰动组中,浮游植物主要优势种由微囊藻逐渐转变为湖生伪鱼腥藻,其中微囊藻占比从试验开始时的77.84%到试验结束时分别降至4.72%和5.62%,而湖生伪鱼腥藻从试验开始时的0.55%到试验结束时分别升至94.40%和90.52%.③对照组、间歇扰动组和持续扰动组中Shannon-Wiener指数分别为1.02、1.03和1.63,持续扰动组显著高于对照组和间歇扰动组.研究显示,在该试验条件下,间歇扰动有利于维持微囊藻在太湖浮游植物中的优势地位,同时表明扰动方式显著影响太湖浮游植物生长和群落结构.      

中国交通运输碳排放时空演变及差异分析

核算了2003—2012年间中国30个省域的交通运输碳排放量和碳排放强度,分析了交通运输碳排放时空演变规律,分别计算了中国东、中、西部的交通运输碳排放量和碳排放强度的标准差和变异系数以定量分析其差异.结果表明:2003—2012年10年间,中国30个省域交通运输碳排放量呈逐年增长趋势,并整体呈现"西低东高"的特征,其中,湖北、广东和山东三省的总量居前3位,而内蒙古、吉林和重庆这3个省份(直辖市)的增速最快;交通运输碳排放强度整体上全国呈增长趋势,呈现出"西高东低"的非均衡变化特征;交通运输碳排放强度绝对差异增速趋缓,自2008年后三大区域的标准差和变异系数都呈现明显趋同效应.     

Organochlorine pesticide and heavy metal residues in some edible biota collected from Quanzhou Bay and Xinghua Bay, Southeast China

In order to assess the contamination of edible marine organisms in Quanzhou and Xinghua Bays,Fujian Province,China,concentrations of organochlorine pesticides(hexachlorocyclohexane isomers or HCHs and dichlorodiphenyltrichloroethane isomers/derivatives or DDTs) and heavy metals(Cu,Pb,Zn,As,Cr,Cd,Ni and Hg) in 13 species collected from different sites in the bays were analyzed by GC-ECD and ICP-MS.The concentration of the sum of DDTs exceeded that the sum of HCHs in the samples.Most of the organisms showed h...     

Prolonged manganese exposure induces severe deficits in lifespan, development and reproduction possibly by altering oxidative stress response in Caenorhabditis elegans

We examined the possible multiple defects induced by acute and prolonged exposure to high levels of manganese (Mn) solution by monitoring the endpoints of lifespan,development,reproduction,and stress response.Our data suggest that acute exposure (6 h) to Mn did not cause severe defects of life span,development,and reproduction.Similarly,no significant defects could be found for the life span,development,and reproduction in animals exposed to a low concentration of Mn (2.5 μmol/L) for 48 h.In contrast,prolonged exposure (48-h) to high concentrations of Mn (75 and 200 μmol/L) resulted in significant defects of life span,development,and reproduction,as well as the increase of the percentage of population with hsp-16.2::gfp expression indicating the obvious induction of stress responses in exposed animals.Moreover,prolonged exposure (48-h) to high concentrations (75 and 200 μmol/L) of Mn decreased the expression levels of antioxidant genes of sod-1,sod-2,sod-3,and sod-4 compared to control.Therefore,prolonged exposure to high concentrations of Mn will induce the severe defects of life span,development,and reproduction in nematodes possibly by affecting the stress response and expression of antioxidant genes in Caenorhabditis elegans.