Field methods and example applications for the Min-Trap® mineral sampler

Important reactive minerals are commonly created during in situ groundwater remediation activities; for example, iron sulfides formed during enhanced reduction approaches can abiotically degrade many chlorinated solvents. However, cost-effective tools to evaluate these treatment processes in field applications are limited and the collection of samples to evaluate in situ mineral formation is costly due to drilling requirements. The new passive Min-Trap sampler is a simple and cost-effective tool that can directly measure the formation of reactive minerals in situ without the need for additional drilling or soil core collection. The methods presented here describe how Min-Traps deployed in conventional monitoring wells can measure reactive minerals and how these minerals can be identified through commercially available analytical methods. Several examples are presented that show how Min-Traps can be used to characterize the rate and spatial variability of reactive mineral precipitation and these data may support operation and optimization decisions.     

Toward an improved ecosystem based management approach: incorporating catchment characteristics into better management and planning of the Great Barrier Reef marine ecosystem

Discharge from the Great Barrier Reef Catchment (GBRC) is considered the second most serious threat to the Great Barrier Reef, Australia. Utilising principal component analysis (PCA) and cluster analysis (CA), this research aimed to assess the variability and co-variation of 28 water basins (WBs) within the GBRC, in order to improve the institutional arrangements and regulation of water quality and increase collaboration horizontally between management organisations, and vertically between government tiers. Water basin variability was measured by nine variables: size (ha), population, agricultural land use (ha), number of major water storages, major rivers and major towns, total nitrogen exported (T/yr), total phosphorus exported (T/yr) and herbicide use (ha). The Fitzroy WB, with PC scores of 7.0081, 2.2897 and ?1.6504, was identified as the most dissimilar and therefore needing to be managed differently. Many WBs within the same regions were very dissimilar to each other, indicating that current management practices, based largely on geographic location, are unlikely to be the most efficient and effective. Instead, managing groups of WBs with similar geo-political properties (determined by the CA) could be more effective and efficient. Coordination and collaboration are key to successful ecosystem based management, therefore managing similar WBs together through inter-NRM (natural resource management) agreements, irrespective of their geographical location, facilitates management bodies building strong, cooperative working relationships.     

Identifying correlates of success and failure of native freshwater fish reintroductions

Reintroduction of imperiled native freshwater fish is becoming an increasingly important conservation tool amidst persistent anthropogenic pressures and new threats related to climate change. We summarized trends in native fish reintroductions in the current literature, identified predictors of reintroduction outcome, and devised recommendations for managers attempting future native fish reintroductions. We constructed random forest classifications using data from 260 published case studies of native fish reintroductions to estimate the effectiveness of variables in predicting reintroduction outcome. The outcome of each case was assigned as a success or failure on the basis of the author's perception of the outcome and on whether or not survival, spawning, or recruitment were documented during post‐reintroduction monitoring. Inadequately addressing the initial cause of decline was the best predictor of reintroduction failure. Variables associated with habitat (e.g., water quality, prey availability) were also good predictors of reintroduction outcomes, followed by variables associated with stocking (e.g., genetic diversity of stock source, duration of stocking event). Consideration of these variables by managers during the planning process may increase the likelihood for successful outcomes in future reintroduction attempts of native freshwater fish. Identificación de Correlaciones de Éxito y Fracaso de Reintroducciones de Peces de Nativos Agua Dulce     

Preserving Environmental Integrity in standardised baselines: The role of additionality and uncertainty

The European Union EU project PROBASE hasexplored a range of possible multi projectstandardised benchmarks as a way ofencouraging projects under Joint Implementation (JI) and the Clean Development Mechanism (CDM)by minimising transaction costs. The aim ofthis paper is to examine the environmentalintegrity of the use of standardisedbaselines and to explore the role ofadditionality. The environmental integritydepends on the uncertainty in emissionreductions, which was estimated bygenerating scenario baselines and comparingthese with the standardised baselines. Thishas allowed a comparison of selected multiproject baselines with the envelope ofuncertainty on the reductions. The projectsincluded a range of electricity supply,heat sector, cogeneration and methane(CH$_{4}$) projects in different countries. Theanalysis showed that the key uncertaintieswere in the technology fuel selection inthe baseline, the continued additionalityof the project emission reductions,uncertainties in some project emissions(e.g. spinning reserve emissions for wind)and data uncertainties. The effect on theestimation of reductions was in the range±12% to ±46% for the electricityprojects and from ±19% to ±57%for the heat and Combined Heat and Power CHP sector projects.Comparison with the envelope of uncertaintyfor the range of projects showed that multiproject electricity sector baselines whichhave been weighted or use high technologyperformance benchmarks (e.g. Organization for Economic Cooperation and Development OECD)can provide conservative estimates buttheir general nature can lead to variationsbetween countries. We would recommend thatthe country-specific context must be takeninto account so that standardised baselinesfor the electricity sector are generated onthe basis of country specificcharacteristics, the project type, andwhether it provides new or existing demand.The conservative scenario produced shouldthen be weighted. Whereas weightings havebeen applied to account for uncertaintiesor to bias towards renewables, we havesuggested a weighting factor of 25% on theelectricity baseline for large projectsbased on an analysis of the effect ofnon-additionality on emission reductionuncertainty. For heat projects, theappropriate benchmark is a technology/fuelbenchmark which is deemed relevant for theheat sector in that (part of the) country.Again we suggest that a weighted sectorbaseline is required to take account of theuncertainties. These recommendations applyto large projects only for a 10-yearcrediting lifetime.     

Distribution and diet of juvenile Patagonian toothfish on the South Georgia and Shag Rocks shelves (Southern Ocean)

The distribution and diet of juvenile (<750 mm) Patagonian toothfish are described from four annual trawl surveys (2003–2006) around the island of South Georgia in the Atlantic sector of the Southern Ocean. Recruitment of toothfish varies inter-annually, and a single large cohort dominated during the four years surveyed. Most juveniles were caught on the Shag Rocks shelf to the NW of South Georgia, with fish subsequently dispersing to deeper water around both the South Georgia and Shag Rocks shelves. Mean size of juvenile toothfish increased with depth of capture. Stomach contents analysis was conducted on 795 fish that contained food remains and revealed that juvenile toothfish are essentially piscivorous, with the diet dominated by notothenid fish. The yellow-finned notothen, Patagonotothen guntheri, was the dominant prey at Shag Rocks whilst at South Georgia, where P. guntheri is absent, the dominant prey were Antarctic krill and notothenid fish. The diet changed with size, with an increase in myctophid fish and krill as toothfish grow and disperse. The size of prey also increased with fish size, with a greater range of prey sizes consumed by larger fish.     

The value of energy efficiency programs for US residential and commercial buildings in a warmer world

US residential and commercial buildings were responsible for about 41 exajoules (EJ) of primary energy use per year in 2002, accounting for approximately 9% of the world fossil-fuel related anthropogenic carbon (C) emissions of 6.7 Gt that contribute to climate change. US Government-sponsored building energy efficiency research and implementation programs are focused on reducing energy consumption in US residential and commercial buildings and reducing these carbon (C) emissions. Although not specifically intended for adaptation to a warmer climate and less effective than under today’s cooler climate, these programs also could help reduce energy demand in a future warmer world. Warming scenarios projected by the United Nations Intergovernmental Panel on Climate Change (IPCC) in 2001 imply net overall decreases in both site energy and primary energy consumption in US residential and commercial buildings, largely because of the reduced need for heating. However, there would be as much as a 25% increase in building space cooling demand and a significant part of the increase could be offset by energy-efficiency improvements in buildings. Overall, in the US, buildings-related energy efficiency programs would reduce site energy consumption in buildings in the US by more than 2 EJ in 2020 and primary energy by more than 3.5 EJ, more than enough to offset the projected growth in cooling energy consumption due to climate change and growth in the US building stock. The savings would have an estimated annual net value at 2005 energy prices of between $45.0 and $47.3 billion to consumers.

Human maternal and umbilical cord blood concentrations of polybrominated diphenyl ethers

Polybrominated diphenyl ethers (PBDEs), widely used as flame retardants in commercial products, have become ubiquitous environmental contaminants. Although adult human exposure to PBDEs is well documented, developmental exposure is less well characterized. The objectives of this study were to measure maternal and fetal exposure to nine PBDE congeners and to investigate potential associations with birth weight. PBDE congeners were quantified in maternal serum at 24-28 weeks of pregnancy, delivery, and umbilical cord serum (UCS) by gas chromatography-mass spectrometry (GC/MS/MS). Complete blood sample sets were obtained from 97 pregnant women (mean age 33.1 ± 0.5 years). PBDE-28, -47 and -99 were quantified in all samples tested and PBDE-47 was the most abundant congener measured in both maternal (mid-pregnancy and delivery samples geometric mean = 26.9 and 26.9, respectively) and UCS (GM = 56.0 ng g⁻¹ lipid). The UCS concentration for all congeners with the exception of PBDE-153 was higher vs. maternal delivery samples (p < 0.001). Only the UCS concentration of PBDE-17 and -99 were significantly associated (β = −49.860, p = 0.032, and β = −3.645, p = 0.05) with birth weight. However, after adjustment for potential confounders only the association between PBDE-99 and birth weight remained significant (β = −3.951 and p = 0.016). We conclude that: the fetus is exposed to PBDEs from at least the second trimester of pregnancy onward; PBDE congeners are higher in UCS compared to maternal serum samples collected at delivery; and that developmental PBDE exposure is potentially associated with lower birth weight.     

Three-dimensional characterization of the ammonia plume from a beef cattle feedlot

In Canada approximately 45% of ammonia (NH₃) emissions are attributed to dairy and beef cattle industries. The present study focused on NH₃ emissions from a beef feedlot with a one-time capacity of 17,220 head. The aim was to improve the Canadian NH₃ emission inventories and air quality forecasting capabilities. A Cessna 207, equipped with a fast-response NH₃/NO_y detector and a quadrupole aerosol mass spectrometer, was flown in a grid pattern covering an area of 8 × 8 km centered on a feedlot (800 × 800 m) at altitudes ranging from 30 to 300 m above ground. Stationary ground measurements of NH₃ concentration and turbulence parameters were made downwind of the feedlot. Three flights were conducted under varying meteorological conditions, ranging from very calm to windy with near-neutral stratification. NH₃ mixing ratios up to 100 ppbv were recorded on the calm day, up to 300 m above ground. An average feedlot NH₃ emission rate of 76 ± 4 μg m^?2 s^?1 (equivalent to 10.2 g head^?1 h^?1) was estimated. Characteristics of the measured NH₃ plume were compared to those predicted by a Lagrangian dispersion model. The spatially integrated pattern of NH₃ concentrations predicted and measured agreed but the measured was often more complex than the predicted spatial distribution. The study suggests that the export of NH₃ through advection accounted for about 90% of the emissions from the feedlot, chemical transformation was insignificant, and dry deposition accounted for the remaining 10%.