Evaluation of a Three‐Dimensional Hydrodynamic Model Applied to Chesapeake Bay Through Long‐Term Simulation of Transport Processes

A numerical model, the Curvilinear Hydrodynamics in 3‐Dimensions, Waterway Experiment Station version (CH3D‐WES), was applied to represent transport processes of the Chesapeake Bay. Grid resolution and spatial coverage, tied with realistic bathymetry, ensured dynamic responses along the channel and near the shoreline. The model was run with the forcing ranges from high frequency astronomical tides to lower frequency meteorological forcing, given by surface wind and heat flux, as well as hydrological forcing given by fresh water inflows both from upstream and distributed sources along the shoreline. To validate the model, a long‐term simulation over seven‐year time period between 1994 and 2000 was performed. The model results were compared with existing observation data including water level time series, which spans over a wide spectrum of time scales, and long‐term variations in salinity structures over varying parts of the Bay. The validated model is set to provide an appropriate transport mechanism to the water quality model through linkage, warranting that the model takes into account the complexity in time and spatial scales associated with the dynamic processes in the Chesapeake.     

Indoor radon distribution of subway stations in a Korean major city

The overall survey on indoor radon concentration was conducted at all subway stations in a major city, Daejeon in the central part of Korea. It was quarterly performed from September 2007 to August 2008. The annual arithmetic mean of indoor radon concentration of all the stations was 34.1 ± 14.7 Bq m⁻³, and the range of values was from 9.4 to 98.2 Bq m⁻³. The radon concentrations in groundwater (average 31.0 ± 0.8 Bq m⁻³) were not significantly high in most stations, but the concentration (177.9 ± 2.3 Bq L⁻¹) of one station was over the level of 148 Bq L⁻¹ in drinking water proposed by U.S. EPA. Based on indoor survey results, the approximate average of the annual effective dose by radon inhalation to the employees and passengers were 0.24 mSv y⁻¹, and 0.02 mSv y⁻¹, respectively. Although the effective dose based on the UNSCEAR report was potentially estimated, for more accurate assessment, the additional survey on the influence by indoor radon will be necessary.     

Assessment of phytotoxicity of ZnO NPs on a medicinal plant, Fagopyrum esculentum

Fagopyrum esculentum commonly named as buckwheat plant is pseudocereal food crops and healthy herbs but is not known as a bioindicator of environmental condition. In the present study, the effects of ZnO nanoparticles (NPs) and microparticles (MPs) on plant growth, bioaccumulation, and antioxidative enzyme activity in buckwheat were estimated under hydroponic culture. The significant biomass reduction at concentrations of 10–2,000 mg/L was 7.7–26.4 % for the ZnO NP and 11.4–23.5 % for the ZnO MP treatment, (p?<?0.05). ZnO NPs were observed in root cells and root cell surface by scanning electron microscopy and transmission electron microscopy analysis. Zn bioaccumulation in plant increased with increasing treatment concentrations. The upward translocation (translocation factor <0.2) of Zn in plant was higher with the ZnO NP treatment than that with the ZnO MP treatment. Additionally, reactive oxygen species generation by ZnO NPs was estimated as the reduced glutathione level and catalase activity, which would be a predictive biomarker of nanotoxicity. The results are the first study to evaluate the phytotoxicity of ZnO NPs to medicinal plant. F. esculentum can be as a good indicator of plant species in NP-polluted environment.     

Development of extended speech act coding scheme to observe communication characteristics of human operators of nuclear power plants under abnormal conditions

Communication problems have long been regarded as one of the biggest causes of trouble in many workplaces. Consequently, as a part of human error analysis, extensive research has been conducted into communication. The existing research indicates that maintaining reliable communication is essential to securing the safety of a large and complex process or system. To observe the characteristics of communication, verbal protocol analysis using speech act coding schemes have been widely used in much of the related research. However, as existing speech act coding schemes do not provide a sufficient analysis information other than the distribution rate of each pattern, the development of extended communication categories is essential to overcoming the weaknesses of protocol analysis. The objective of this study is to suggest an extended speech act coding scheme and to elucidate the communication pattern characteristics of an operator’s conversation during a simulated abnormal condition in a nuclear power plant (NPP). The expected results are that conversation between operators using Multi-Way communication can increase the accuracy of information delivery and eliminate the possibility of improper operation. Therefore, communication quality control can be regarded as an important research area to minimize the occurrence of human error during communication. From this perspective, the results of this study would be a good starting point to improving the quality of communications in the workplace.     

Sources of fine particles in the South Coast area,California

PM_2.5 (particulate matter less than 2.5 μm in aerodynamic diameter) speciation data collected between 2003 and 2005 at two United State Environmental Protection Agency (US EPA) Speciation Trends Network monitoring sites in the South Coast area, California were analyzed to identify major PM_2.5 sources as a part of the State Implementation Plan development. Eight and nine major PM_2.5 sources were identified in LA and Rubidoux, respectively, through PMF2 analyses. Similar to a previous study analyzing earlier data (Kim and Hopke, 2007a), secondary particles contributed the most to the PM_2.5 concentrations: 53% in LA and 59% in Rubidoux. The next highest contributors were diesel emissions (11%) in LA and Gasoline vehicle emissions (10%) in Rubidoux. Most of the source contributions were lower than those from the earlier study. However, the average source contributions from airborne soil, sea salt, and aged sea salt in LA and biomass smoke in Rubidoux increased.To validate the apportioned sources in this study, PMF2 results were compared with those obtained from EPA PMF (US EPA, 2005). Both models identified the same number of major sources and the resolved source profiles and contributions were similar at the two monitoring sites. The minor differences in the results caused by the differences in the least square algorithm and non-negativity constraints between two models did not affect the source identifications.     

Seasonal changes in the diet and feeding behaviour of a top predator indicate a flexible response to deteriorating oceanographic conditions

Shifts in the diet of top predators can be linked to changes in environmental conditions. In this study, we tested relationships between environmental variation and seasonal changes in diet of a top predator, the grey-headed albatross Thalassarche chrysostoma, breeding at Bird Island, South Georgia in an austral summer of 1999/2000. Oceanographic conditions in that year around South Georgia were abnormal (i.e. anomalously high sea surface temperature to a relative 19-year long-term mean). The diet of grey-headed albatrosses showed high seasonal variation, shifting from cephalopods (42.9 % by mass) in late February to Antarctic krill Euphausia superba (58.3 %) in late April, and grey-headed albatrosses breeding performance was low (16.8 %). This study shows these albatrosses did not manage to find sufficient alternative prey and highlight the risk to top predators if there is an increase in the frequency or severity of food shortages in Antarctic waters.     

Preparation of a highly sensitive enzyme electrode using gold nanoparticles for measurement of pesticides at the ppt level

A highly sensitive enzyme electrode was prepared based on gold nanoparticles for measurement of pesticides. Gold nanoparticles of 25-30 nm were synthesized on a glassy carbon electrode by double-pulse technique while the coverage was controlled by applied potential and time. The gold nanoparticles were modified to form a self-assembled monolayer, followed by covalent binding of tyrosinase. The TYR-AuNP-GC electrode was compared with bare GC, AuNP-GC, and modified AuNP-GC and TYR-Au (plate type) electrodes in terms of cyclic voltammetry. The voltammograms well represent the sensitivity of enzymatic oxidation of catechol, substrates for the enzyme activity. The prepared electrode integrated into a continuous flow system and was tested to detect pesticides, such as 2,4-D, atrazine, and ziram. Under the optimized conditions of the flow system, the electrode performed reasonably according to the inhibition mechanism in the concentration range of 0.001-0.5 ng mL(-1). The enhanced performance was attributed to the favored microenvironment for the enzyme activity provided by SAM on gold nanoparticles.     

Preparation and Use of Spatially and Temporally Resolved Emission Inventories in the San Francisco Bay Region

Three regional agencies recently prepared an Air Quality Maintenance Plan for the San Francisco Bay Area oxidant problem. An Eulerian, photochemical model, LIRAQ, provided the technical basis for the plan recommendations. A major LIRAQ input is an emission inventory accurately resolved to one kilometer and one hour increments. The cooperating agencies prepared such inventories, covering 20,000 sq km, for one base and two future years. Several manual and computer-assisted techniques were developed to utilize a variety of independent data bases. Population, land use, employment and transportation data were oganized into a common system of coordinates and units to produce the needed spatial input. Estimates of hourly variation were made by source category based on production rates, fuel use, traffic patterns, flight schedules, and other factors. The result was a series of consistent, detailed inventories which provide a powerful air quality modeling and planning tool. The detail is attained at considerable expense, but the cost is easily justifiable when compared to implementation costs for control strategies.     

Food security and seasonal climate information: Kenyan challenges

This article examines challenges to food security in areas especially vulnerable to the effects of climate variability and change, and the potential contribution of seasonal climate forecasting. Drawing on long-term study of the way environmental information is developed and circulates, and on recent fieldwork in Western Kenya, the article describes how climate variability exacerbates food insecurity; the kinds of climate information that are now being developed; and the kinds of technologies, organizations, and expertise that will be needed if new forms of climate information are to benefit vulnerable populations. Findings indicate that new forms of expertise need to be developed at all scales, and that linkage among stakeholders and between organizations functioning at different scales will be a considerable challenge.     

Leaching behaviour of elements and evaluation of pre-treatment methods for municipal solid waste incinerator residues in column leaching tests.

Two new pre-treatment methods (water-washing/carbonation and carbonation/phosphate stabilization) of municipal solid waste (MSW) incinerator residues were evaluated by column leaching tests under aerobic conditions and anaerobic conditions (which were changed to aerobic conditions after 10 months). A mixture of bottom ash and fly ash (5:1 ratio) was pre-treated using each method. Shredded incombustible residues (SIR) were added to each ash preparation in proportions similar to the ratios present in landfills. For comparison, landfill wastes typical of Japan, namely, a mixture of bottom ash, chelating-pre-treated fly ash, and SIR, were also examined. Leachate samples were collected periodically and analysed over a 15-month period. When compared with chelating pretreatment, both water-washing/carbonation and carbonation/ phosphate stabilization reduced the leaching of Pb, Al, and Cu by about one to two orders of magnitude. Moreover, the initial concentrations of Ca and Pb in leachates from column of water-washing/carbonation were 56-57% and 84-96% less than those from the column of carbonation/phosphate stabilization. Therefore, water-washing/carbonation was considered to be a promising approach to obtain early waste stabilization and to reduce the release of heavy metals to near-negligible levels. The leaching behaviour of elements was also discussed.