Effect of lead on growth and nitrate assimilation of Vigna radiata (L.) Wilczek seedlings in a salt affected environment

The inhibition of seedling growth and nitrate reductase activity in 5 d old Vigna radiata (L.) Wilczek cv. Pusa Baisakhi in the presence of 1.0 mM lead acetate increased drastically, if NaCl (6 and 12 EC) was also present in the nutrient media along with the metal salt. Correspondingly higher endogenous Na+ levels were accumulated in the roots and leaves of seedlings in presence of the two stresses. On the other hand, the levels of endogenous lead get reduced in presence of NaCl in both the roots and leaves. Roots accumulated more Pb2+ and Na+ than the leaves. The two stresses affect more drastically in the additive or even synergistic manner during the early growth phase of the seedlings.     

Nanotechnology and water purification: Indian know-how and challenges

Water contamination being ubiquitous problem across the world. A significant strata of population worldwide are still struggling to get drinkable water. This demand to develop technologies to provide clean water at affordable price is unveiling the need of rigorous research in this area. There are several technologies available for removal of persistent as well as emerging pollutants from water. Nanotechnology-based technology are providing the promising solution because of its extraordinary characteristics like large surface area, low cost maintenance and reuse, etc. During the past decade, there is an advancement in the field of nanotechnology and diligent efforts of researchers in achieving milestones in developing nanosorbents, nanostructured catalytic membranes, efficient photo catalysts, bioactive nanoparticles and new filtration regime. This article gives an overview of nanotechnology applications in water purification in India with an attempt to ponder indigenous technologies for implementation. A bibliometric approach is applied to bring the indigenous technologies available. In addition, we discuss some challenges associated with the development of convincing material and building water processing plants for purification of the wastewater.     

The effect of landuse on soil organic carbon chemistry and sorption of pesticides and metabolites

Earlier studies had shown significant differences in sorption of nine pesticides in soils collected from two landuses (native vegetation and market gardens), which could not be explained on the basis of organic carbon content alone. Consequently it was hypothesised that the differences in sorption behaviour between the two landuses may be due to variation in the chemistry of the organic carbon. In this study the relationship between sorption behaviour of the nine chemicals and soil organic carbon chemistry, as determined by solid-state (13)C NMR spectroscopy, was investigated. No significant differences were found between the two landuses in the distribution of the four main spectral regions of the (13)C NMR spectra of soil OC, except for the carbonyl fraction (165-220ppm), which may reflect the low OC content of the soils from both landuses. For all chemicals, except prometryne, the most significant (P<0.01 or P<0.001) relationship between K(d) values and types of OC was found with the aromatic (110-165ppm) or the alkyl (0-45ppm) fraction. A comparison was made of the variability of K(d) values normalized over OC (i.e. K(oc)), alkyl, aromatic and alkyl+aromatic fractions. Expressing K(d) values for all chemicals, except azinphos methyl, in soils under native vegetation as K(alkyl) or K(aromatic) greatly decreased the variability compared with the K(oc) value. However in the cultivated soils only the sorption coefficients for DEA, DIA and fenamiphos showed a decrease in variability when expressed as K(alkyl) or K(aromatic). This reflected the stronger relationship between sorption coefficients and the alkyl and aromatic fraction of soil OC in soils from native vegetation compared with those determined from the market garden soils. The different relationships between sorption coefficients and types of OC of the two landuses also suggests that the type of aromatic and alkyl carbon under the two landuses is different and NMR characterisation of the OC was not sufficient to distinguish these differences.     

Release behavior of triazine residues in stabilised contaminated soils

This paper reports the release behavior of two triazines (atrazine and simazine) in stabilised soils from a pesticide-contaminated site in South Australia. The soils were contaminated with a range of pesticides, especially with triazine herbicides. With multiple extractions of each soil sample with deionised water (eight in total), 15% of atrazine and 4% of simazine residues were recovered, resulting in very high concentrations of the two herbicides in leachate. The presence of small fractions of surfactants was found to further enhance the release of the residues. Methanol content up to 10% did not substantially influence the concentration of simazine and atrazine released. The study demonstrated that while the stabilisation of contaminated soil with particulate activated carbon (5%) and cement mix (15%) was effective in locking the residues of some pesticides, it failed to immobilise triazine herbicides residues completely. Given the higher water solubility of these herbicides than other compounds more effective strategies to immobilise their residues is needed.     

Designing a community-based insurance scheme to reduce human–wildlife conflict

Environment, Development and Sustainability - Globally, human–wildlife conflict (HWC) is a burning issue, which the conservationists have attempted to address through various conservation...     

Atrazine and simazine degradation in Pennisetum rhizosphere

The ability of rhizosphere of four plant species to promote the degradation of charcoal-fixed atrazine and simazine in cement blocks of a long-term contaminated soil when mixed with a normal soil at 1:1 ratio was tested. Of the four selected plants viz., rye grass (Lolium perenne), tall fescue (Festuca arundinacae), Pennisetum (Pennisetum clandestinum) and a spring onion (Allium sp.) used in this study, only P. clandestinum was able to survive in herbicide contaminated soil while other plants died within few days after germination/transplanting. Both atrazine and simazine were degraded at a faster rate in contaminated soil planted to P. clandestinum than in unplanted soil. Within 80 days, nearly 45% and 52% of atrazine and simazine, respectively, were degraded in soil planted to P. clandestinum while only 22% and 20% of the respective herbicide were degraded in the unplanted soil. During 80-day experimental period, both microbial biomass and soil dehydrogenase activity were significantly increased (7-fold) in soil planted to P. clandestinum over that in unplanted soil. The suspension of contaminated rhizosphere soil, planted to P. clandestinum exhibited an exceptional capability to degrade both atrazine (300 microg) and simazine (50 microg) in a mineral salts medium over that of non-rhizosphere soil suspension. Results indicate that P. clandestinum, a C4 plant, may be useful for remediation of soils contaminated with atrazine and simazine.     

Bioaccumulation of toxic metals (Cr, Cd, Pb and Cu) by seeds of Euryale ferox Salisb. (Makhana) W

The level of toxic metals Cr, Cd, Pb and Cu was determined in seeds, water and sediments collected from nine closed waterbodies of Darbhanga, north Bihar, used for cultivation of the edible aquatic macrophyte Euryaleferox Salisb. during harvesting season of the crop for two successive years (1996 and 1997). Seeds bioconcentrated appreciable amount of these toxic metals in the order Pb > Cr > Cu > Cd. The increased load of metal pollution due to domestic and municipal discharges threatened the habitats of the plant. The toxic metal contents in seeds were found positively correlated with the ambient concentration of metals in water and sediments. The importance of these findings has been discussed for national water resource economy of the country and human health perspectives.     

Cadmium adsorption and desorption behaviour on goethite at low equilibrium concentrations: effects of pH and index cations

The transport and bioavailability of cadmium is governed mainly by its adsorption-desorption reactions with minerals such as goethite--a common iron oxide mineral in variable charged and highly weathered tropical soils. Soil factors such as pH, temperature, solution Cd concentration, ionic strength and ageing affect Cd adsorption on goethite. The desorption behaviour of Cd from goethite at low concentrations is not fully understood. This study investigates the adsorption-desorption of Cd at low Cd concentrations (Cd adsorbed on goethite from 20 to 300 microM Cd solutions) in Na and Ca nitrate solutions of 0.03 M nominal ionic strengths. Synthetic goethite prepared by ageing a ferric hydroxide gel at high pH and room temperature was used for Cd adsorption and desorption studies. For desorption experiment 10 successive desorptions were made for the whole range of initial Cd concentrations (20-300 microM) in the presence of 0.01 M Ca(NO3)2 or 0.03 M NaNO3 solutions. Cadmium adsorption was found to be higher in Na+ than Ca2+ probably due to the competition of Ca2+ ions with Cd2+ ions for adsorption sites on the surfaces of goethite. The effect of index cation on Cd adsorption diminished with increase in pH from 5.0 to 6.0. Cadmium desorption decreased with increase in pH from 5.0 to 6.0 in both Na and Ca systems. After 10 successive desorptions with 0.03 M NaNO3 at the lowest initially adsorbed Cd approximately 45%, 20% and 7% of the adsorbed Cd was desorbed at pH 5.0, 5.5 and 6.0, respectively. The corresponding desorptions in the presence of 0.01 M Ca(NO3)2 were 49%, 22% and 8%, respectively. The Freundlich parameter, k, based on each progressive step of desorption at different adsorbed concentration increased with increasing desorption step, which may indicates that a fraction of Cd was resistant to desorption. Low Cd desorbability from goethite may be due to its specific adsorption and/or possibly as a result of Cd entrapment in the cracks or defects in goethite structure.     

Simultaneous analysis of triasulfuron, metsulfuron-methyl and chlorsulfuron in water and alkaline soils by high-performance liquid chromatography

A method capable of simultaneously detecting residues of three sulfonylurea herbicides at microgram/l and microgram/kg level in water and alkaline soils has been described. The method is based on solid phase extraction and HPLC with UV detection. In alkaline soils especially those containing low organic carbon it was possible to extract the herbicides with de-ionised water and no clean up step was needed. Soil samples spiked with technical grade triasulfuron, metsulfuron-methyl and chlorsulfuron were extracted twice by shaking with de-ionised water for one hour and centrifuging at 10,000 rpm for 15 minutes. Supernatants filtered through glass micro-fibre filters were passed through C18 cartridges previously pre-conditioned with methanol and de-ionised water at a flow rate of < 20 ml/min. Residues of the herbicides retained on the cartridge were eluted with acidified methanol. The eluate was analysed by HPLC. A C18 column was used with a mobile phase of methanol/water (40 + 60, V/V for for the herbicide residues were 1.0 microgram/l and 3 micrograms/kg in water and soil, respectively. The average recoveries for water samples ranged from 73-94%, while for soil samples recoveries were 77-97% for the three compounds studied.     

Atmospheric particle-bound polycyclic aromatic compounds over two distinct sites in Pakistan: Characteristics, sources and health risk assessment

Much attention is drawn to polycyclic aromatic hydrocarbons（PAHs） as an air pollutant due to their toxic, mutagenic and carcinogenic properties. Therefore, to understand the levels, seasonality, sources and potential health risk of PAHs in two distinct geographical locations at Karachi and Mardan in Pakistan, total suspended particle（TSP） samples were collected for over one year period. The average total PAH concentrations were 31.5 ± 24.4 and 199 ± 229 ng/m³ in Karachi and Mardan, re...