Geostatistical analysis to identify hydrogeochemical processes in complex aquifers: a case study (Aguadulce unit, Almeria, SE Spain)

The Aguadulce aquifer unit in southeastern Spain is a complex hydrogeological system because of the varied lithology of the aquifer strata and the variability of the processes that can take place within the unit. Factorial analysis of the data allowed the number of variables to be reduced to 3 factors, which were found to be related to such physico-chemical processes as marine intrusion and leaching of saline deposits. Variographic analysis was applied to these factors, culminating in a study of spatial distribution using ordinary kriging. Mapping of the factors allowed rapid differentiation of some of the processes that affect the waters of the Gador carbonate aquifer within the Aguadulce unit, without the need to recur to purely hydrogeochemical techniques. The results indicate the existence of several factors related to salinity: marine intrusion, paleowaters, and/or leaching of marls and evaporitic deposits. The techniques employed are effective, and the results conform to those obtained using hydrogeochemical methods (vertical records of conductivity and temperature, ion ratios, and others). The findings of this study confirm that the application of such analytical methods can provide a useful assessment of factors affecting groundwater composition.     

Exploring the assumed invariance of implied emission factors for forest biomass in greenhouse gas inventories

Reviews of each nation's annual greenhouse gas inventory submissions including forestland are part of the ongoing reporting process of the United Nations Framework Convention on Climate Change. Goals of these reviews include improving quality and consistency within and among reports. One method of facilitating comparisons is the use of a standard index such as an implied emission factor (IEF), which for forest biomass indicates net rate of carbon emission or sequestration per area. Guidance on the use of IEFs in reviews is limited, but there is an expectation that values should be relatively constant both over time and across spatial scales. To address this hypothesis, we examine IEFs over time, derived from U.S. forests at plot-, state-, and national-levels. Results show that at increasingly aggregated levels, relative heterogeneity decreases but can still be substantial. A net increase in U.S. whole-forest IEFs over time is consistent with results from temperate forests of nations in the European Community. IEFs are better viewed as a distribution of values rather than one constant value principally because of sensitivities to productivity, disturbance, and land use change, which can all vary considerably across a nation's forest land.     

Evidence of enhanced atmospheric ammoniacal nitrogen in Hells Canyon national recreation area: implications for natural and cultural resources

Agriculture releases copious fertilizing pollutants to air sheds and waterways of the northwestern United States. To evaluate threats to natural resources and historic rock paintings in remote Hells Canyon, Oregon and Idaho, deposition of ammonia (NH3), nitrogen oxides (NOx), sulfur dioxide (SO2), and hydrogen sulfide (H2S) at five stations along 60 km of the Snake River valley floor were passively sampled from July 2002 through June 2003, and ozone data and particulate chemistry were obtained from the Interagency Monitoring of Protected Visual Environments (IMPROVE) station at Hells Canyon. NH3 concentrations were high; biweekly averages peaked at 5-19 ppb in spring and summer and the nutrient-laden Snake River is a likely source. Fine particulate ammonium nitrate (NH4NO3) averaged 2.6 microg/m3 during the 20% of worst visibility days with winter drainage of air masses from the Snake River Basin and possibly long distance transport from southern California. Other pollutants were within background ranges. NH3 is corrosive to clay-based pictographs; nitrogen deposition can alter natural biotic communities and terrestrial ecosystem processes at levels reported here.     

Green procurement in the Asian public sector and the Hong Kong private sector

Since the 1980s, green purchasing/green procurement has increasingly been recognised as an effective means of addressing and reducing negative environmental impacts related to product production and consumption around the world. This paper reviews the procurement practices and policies of five Asian countries and Hong Kong, in the context of an international overview of green purchasing and practices. The extent of government involvement in green procurement is found to directly determine its overall effectiveness, and up-to-date information resources clearly enhance delivery and performance. A case study in Hong Kong demonstrates how public leadership on green procurement has advanced green procurement in the private sector.     

The effects of type A behavior dimensions and optimism on coping strategy,health, and performance

Type A behavior dimensions and optimism were examined as predictors of health and performance. In addition, this research also explored the ways that Type As and optimists cope with stressful situations. The achievement striving dimension of the Type A behavior pattern and optimism were positively related to class performance, while the anger/hostility dimension was positively related to the health symptom of anxiety. Optimism, on the other hand, was negatively related to anxiety. The interaction of achievement striving and optimism was negatively related to anxiety. Additionally, while achievement striving was positively related to problem-focused coping, irritability showed a negative association with problem-focused coping strategy. The results of this study provide insights for both individuals and organizations regarding how to cope with daily stresses in order to lower health risks and improve performance.     

A national critical loads framework for atmospheric deposition effects assessment: IV. Model selection,applications, and critical loads mapping

The critical loads approach is emerging as an attractive means for evaluating the effects of atmospheric deposition on sensitive terrestrial and aquatic ecosystems. Various approaches are available for modeling ecosystem responses to deposition and for estimating critical load values. These approaches include empirical and statistical relationships, steady-state and simple process models, and integrated-effects models. For any given ecosystem, the most technically sophisticated approach will not necessarily be the most appropriate for all applications; identification of the most useful approach depends upon the degree of accuracy needed and upon data and computational requirements, biogeochemical processes being modeled, approaches used for representing model results on regional bases, and desired degree of spatial and temporal resolution. Different approaches are characterized by different levels of uncertainty. If the limitations of individual approaches are known, the user can determine whether an approach provides a reasonable basis for decision making. Several options, including point maps, grid maps, and ecoregional maps, are available for presenting model results in a regional context. These are discussed using hypothetical examples for choosing populations and damage limits. The research described in this article has been funded by the US Environmental Protection Agency. This document has been prepared at the EPA Environmental Research Laboratory in Corvallis, Oregon, through contract #68-C8-0006 with ManTech Environmental Technology, Inc., and Interagency Agreement #1824-B014-A7 with the U.S. Department of Energy and at Oak Ridge National Laboratory managed by Martin Marietta Energy Systems, Inc., under Contract DE-AC05-84OR21400 with the US Department of Energy. Environmental Sciences Division Publication No. 3904. It has been subjected to the agency’s peer and administrative review and approved for publication. Mention of trade names or commercial products does not constitute endorsement or recommendation for use.     

DECLINING INTENSITY OF ACID MINE DRAINAGE IN THE NORTHERN APPALACHIAN BITUMINOUS COAL FIELDS: MAJOR ALLEGHENY RIVER TRIBUTARIES1

ABSTRACT: For more than 30 years, a program of continuous monitoring of pH, acidity, alkalinity, and other parameters has been maintained on a network of large streams degraded by acid mine drainage in the northern Appalachian high sulfur coal region. Continuous records since 1952 are available at a number of stations, and at several stations, acidity records date back to 1930. Comparable analysis techniques were maintained over the period of record, assuring the long term continuity of the database. This monitoring program has captured integrated long term trends within large and complex watersheds with numerous and varied types of mine discharges. The focus of this paper is a historical trend analysis of lightly to severely acid degraded major tributaries of the Allegheny River. Over the past three decades, all of the Allegheny River drainage basin stations have demonstrated steady and substantial declines in acidity and associated increases in pH and alkalinity. The average recorded decline in total acidity at four stations monitored since the 1950s was 94 percent. Since the 1970s, acidity declined by an average of 63 percent at 10 stations. Oxidative exhaustion of pyritic minerals exposed by mining is proposed as a major factor influencing these trends.     

Significance of anion exchange in pentachlorophenol sorption by variable-charge soils

Sorption data and subsequent predictive models for evaluating acidic pesticide behavior on variable-charge soils are needed to improve pesticide management and environmental stewardship. Previous work demonstrated that sorption of pentachlorophenol (PCP), a model organic acid, was adequately modeled by accounting for pH-and pKa-dependent chemical speciation and using two organic carbon-normalized sorption coefficients; one each for the neutral and anionic species. Such models do not account for organic anion interaction to positively charged surface sites, which can be significant for variable-charge minerals present in weathered soils typical of tropical and subtropical regions. The role of anion exchange in sorption of ionizable chemicals by variable-charge soils was assessed by measuring sorption of PCP by several variable-charge soils from aqueous solutions of CaCl2, CaSO4, Ca(H2PO4)2 as a function of pH. Differences in sorption from phosphate and chloride electrolyte solutions were attributed to pentachlorophenolate interactions with anion exchange sites. Suppression of PCP sorption by phosphate ranged from negligible in a soil with essentially no positively charge sites, as measured by negligible anion exchange capacity, to as much as 69% for variable-charge soils. Pentachlorophenolate exchange correlated well with the ratio of pH-dependent anion exchange capacity to net surface charge. Sorption reversibility of PCP by both CaCl2 and Ca(H2PO4)2 solutions was also demonstrated. Results for PCP clearly demonstrate that sorption to anion exchange sites in variable-charge soils should be considered in assessing pesticide mobility and that phosphate fertilizer application may increase the mobility of acidic pesticides.     

Evaluation of California's safety belt law change from secondary to primary enforcement

Some states allow an officer to stop a vehicle for an observed belt law violation alone (primary). Most require that the initial stop be made for some other violation before a belt law citation can be issued (secondary). On January 1, 1993, California became the first state to implement an uninterrupted change from secondary to primary belt law enforcement. In six study communities, the percentage of drivers observed wearing seat belts increased from 58% prior to the law change to 76% soon thereafter. Drivers surveyed at DMV offices indicated that they had knowledge of the new law and were more likely to wear their belts now than in the past.