微波-化学方法除去原煤无机硫的穆斯堡尔谱研究

采用~(17)Fe穆斯堡尔谱学方法研究原煤中无机硫的形态和微波-化学方法脱硫的机理和规律.结果表明,煤中无机硫主要以黄铁矿形式存在.低铁硫酸盐则是原煤风化程度的一种表征;微波选择性介质加热,导致煤中黄铁矿与煤组分进行原位热化学反应,产生能溶于稀盐酸的铁硫化合物Fe_(1-x)S_x(0相似文献   

Modeling the probability of freeway lane-changing collision occurrence considering intervehicle interaction

Objective: To better capture the relationships between lane-changing collisions and explanatory variables, a microscopic model is developed for freeway lane-changing collisions based on the interactions between lane-changing vehicles.

Methods: The model applies an intervehicle interaction structure to account for the occurrence mechanism of lane-changing collisions. The occurrence mechanism can be described as the failure of a vehicle driver of an adjacent lane in avoiding the lane-changing vehicle, which disturbs the smooth movement of the adjacent lane vehicle and requires the driver's brake action to avoid an angle collision. This model is examined using data collected from freeways in Washington State during 2010 to 2011 and validated using lane-changing collision data for the SR 520 freeway.

Results: The findings of this study show that generalized truck percentage has a significant decreasing effect on lane-changing collision risk, whereas average spacing and several roadway characteristics have significant increasing effects. The frequency of slight collisions during peak hours is higher than that during off-peak hours. Young female drivers are more likely to be involved in collisions during lane-changing than young male drivers, but the result for senior drivers is opposite, with older male drivers having a higher probability of lane-changing collisions than female drivers in the same age group.

Conclusion: The process of lane-changing collisions is a complicated maneuver. Truck percentage, average spacing, and good roadway characteristics, such as straight and level segment, in the target lane have a significant effect on the occurrence of lane-changing collisions. Age and gender are also 2 important factors contributing to the relationship between lane-changing collisions and explanatory variables.     

逆境对木兰科树种伤害机理研究进展

逆境对木兰科树种伤害机理的研究已受到广泛重视,但关于木兰科树种抗逆性机制的研究和综合评价缺乏系统性.文章论述了近年来逆境对木兰科树种伤害机理的研究进展,特别是对其光合生理的影响,主要包括植物生物量、净光合速率(Pn)、细胞间隙CO2浓度(Ci)、气孔导度(Gs)、叶绿素含量(Chl)、蒸腾速率(Tr)及叶绿素荧光等参数,并概述了逆境对木兰科树种细胞膜稳定性和渗透调节作用的影响.提出应加强逆境胁迫下木兰科树种抗性机制的研究,并结合实际的栽培环境,运用多个生理生态指标,对木兰科树种的环境适应性进行综合评价,以期科学指导木兰科树种的保护栽培和引种驯化.     

Modeling patterns of nonlinearity in ecosystem responses to temperature, CO2, and precipitation changes.

It is commonly acknowledged that ecosystem responses to global climate change are nonlinear. However, patterns of the nonlinearity have not been well characterized on ecosystem carbon and water processes. We used a terrestrial ecosystem (TECO) model to examine nonlinear patterns of ecosystem responses to changes in temperature, CO2, and precipitation individually or in combination. The TECO model was calibrated against experimental data obtained from a grassland ecosystem in the central United States and ran for 100 years with gradual change at 252 different scenarios. We primarily used the 100th-year results to explore nonlinearity of ecosystem responses. Variables examined in this study are net primary production (NPP), heterotrophic respiration (R(h)), net ecosystem carbon exchange (NEE), runoff, and evapotranspiration (ET). Our modeling results show that nonlinear patterns were parabolic, asymptotic, and threshold-like in response to temperature, CO2, and precipitation anomalies, respectively, for NPP, NEE, and R(h). Runoff and ET exhibited threshold-like pattern in response to both temperature and precipitation anomalies but were less sensitive to CO2 changes. Ecosystem responses to combined temperature, CO2, and precipitation anomalies differed considerably from the responses to individual factors in terms of response patterns and/or critical points of nonlinearity. Our results suggest that nonlinear patterns in response to multiple global-change factors were diverse and were considerably affected by combined climate anomalies on ecosystem carbon and water processes. The diverse response patterns in nonlinearity have profound implications for both experimental design and theoretical development.     

Biogeochemical transfer and dynamics of iodine in a soil–plant system

Radioactive iodide (¹²⁵I) is used as a tracer to investigate the fate and transport of iodine in soil under various leaching conditions as well as the dynamic transfer in a soil–plant (Chinese cabbage) system. Results show that both soils (the paddy soil and the sandy soil) exhibit strong retention capability, with the paddy soil being slightly stronger. Most iodine is retained by soils, especially in the top 10 cm, and the highest concentration occurs at the top most section of the soil columns. Leaching with 1–2 pore volume water does not change this pattern of vertical distributions. Early breakthrough and long tailing are two features observed in the leaching experiments. Because of the relatively low peak concentration, the early breakthrough is really not an environmental concern of contamination to groundwater. The long tailing implies that the retained iodine is undergoing slow but steady release and the soils can provide a low but stable level of mobile iodine after a short period. The enrichment factors of ¹²⁵I in different plant tissues are ranked as: root > stem > petiole > leaf, and the ¹²⁵I distribution in the young leaves is obviously higher than that in the old ones. The concentrations of ¹²⁵I in soil and Chinese cabbage can be simulated with a dual-chamber model very well. The biogeochemical behaviors of iodine in the soil-cabbage system show that cultivating iodized cabbage is an environmentally friendly and effective technique to eliminate iodine deficiency disorders (IDD). Planting vegetables such as cabbage on the ¹²⁹I-contaminated soil could be a good remediation technique worthy of consideration.     

城市暴雨灾害风险评估及防御对策研究——以江苏省南京市为例

以江苏省南京市为例,从气象灾害发生维度评估城市暴雨气象灾害风险性。从致灾因子、孕灾环境和承灾体三方面构建南京暴雨灾害风险评价体系,采用2003-2012年统计数据对南京暴雨灾害风险评价指标进行等级划分,构建隶属函数判定评价因素与评价等级的隶属程度,建立二级模糊综合评价模型评估南京暴雨灾害风险,并选取2012年南京暴雨实例进行数据演算,验证该评价模型的有效性,最后提出南京暴雨灾害的防御对策。     

智能型城市防洪除涝决策支持系统总体设计研究

智能型城市防洪除涝决策支持系统是城市防洪除涝减灾的一种综合性非工程 措施。本文根据作者的经验总结和研究工作,着重阐述了其总体设计的思路、原 则、特点、及结构设计,并对专家系统、GIS技术、遥感遥测技术等高新科技在 城市防洪除涝减灾辅助决策中的作用,作了专门论述。     

PM2.5 concentration declining saves health expenditure in China

● Monthly hospitalization expenses are sensitive to increases in PM_2.5 exposure. ● The increased PM_2.5 causes patients with CHD and LRI to stay longer in the hospital. ● The impact of PM_2.5 on total expenses for stroke is greater in southern China. ● Males may be more sensitive to air pollution than females. Air pollution has been a severe issue in China. Exposure to PM_2.5 has adverse health effects and causes economic losses. This study investigated the economic impact of exposure to PM_2.5 pollution using monthly city-level data covering 88.5 million urban employees in 2016 and 2017. This study mainly focused on three expenditure indicators to measure the economic impact considering lower respiratory infections (LRIs), coronary heart disease (CHD), and stroke. The results show that a 10 µg/m³ increase in PM_2.5 would cause total monthly expenses of LRIs, CHD, and stroke to increase by 0.226%, 0.237%, and 0.374%, respectively. We also found that LRI, CHD, and stroke hospital admissions increased significantly by 10%, 8.42%, and 5.64%, respectively. Furthermore, the total hospital stays of LRIs, CHDs, and strokes increased by 2.49%, 2. 51%, and 1.64%, respectively. Our findings also suggest heterogeneous impacts of PM_2.5 exposures by sex and across regions, but no statistical evidence shows significant differences between the older and younger adult subgroups. Our results provide several policy implications for reducing unequal public health expenditures in overpolluted countries.     

微波焙烧法与马弗炉焙烧法处理废脱硝催化剂的效果比较

用Na_2CO_3作为助溶剂、Na_2O_2作为消解剂,采用微波焙烧法和马弗炉焙烧法消解处理废钒钨钛脱硝催化剂。通过XRF、BET、XRD和NH_3-TPD技术对两种消解方法制得的钛钨粉样品进行了表征。表征结果显示,与马弗炉焙烧法相比,微波焙烧法得到的钛钨粉纯度更高,TiO_2与WO_3含量之和大于96.7%(w),且该钛钨粉还具有更高的比表面积和酸性,可以作为钒钨钛脱硝催化剂的生产原料再利用。     

Natech事件风险评估研究进展

Natech(自然灾害诱发事故灾难)事件在全球大范围内发生,造成了严重的人员伤亡、经济损失和环境破坏,已经成为风险评估领域新的研究热点之一。回顾了Natech事件的相似研究和被单独提出后的研究历程,包括:灾害链和灾害链式理论研究、多米诺效应研究和Natech事件定量风险评估研究。简要评析了目前主要的三类Natech事件研究思路:损失模型、评估指标体系和预警时间指标,并根据Natech风险评估结果,对应对Natech事件提出建议。