Removal of humic acid using TiO2 photocatalytic process--fractionation and molecular weight characterisation studies

The photocatalytic removal of humic acid (HA) using TiO₂ under UVA irradiation was examined by monitoring changes in the UV₂₅₄ absorbance, dissolved organic carbon (DOC) concentration, apparent molecular weight distribution, and trihalomethane formation potentials (THMFPs) over treatment time. A resin fractionation technique in which the samples were fractionated into four components: very hydrophobic acids (VHA), slightly hydrophobic acids, hydrophilic charged (CHA) and hydrophilic neutral (NEU) was also employed to elucidate the changes in the chemical nature of the HA components during treatment. The UVA/TiO₂ process was found to be effective in removing more than 80% DOC and 90% UV₂₅₄ absorbance. The THMFPs of samples were decreased to below 20 μg l⁻¹ after treatments, which demonstrate the potential to meet increasingly stringent regulatory level of trihalomethanes in water. Resin fractionation analysis showed that the VHA fraction was decreased considerably as a result of photocatalytic treatments, forming CHA intermediates which were further degraded with increased irradiation time. The NEU fraction, which comprised of non-UV-absorbing low molecular weight compounds, was found to be the most persistent component.     

Reply to Discussion

In the Discussion, Nash et al. (2019) estimate the seasonal change in groundwater volume for a portion of the restored Sierra Nevada Meadow that we evaluated (Hunt et al. 2018) and use this estimate as an upper bound on the possible contribution to flow that is attributable to restoration. The authors conclude that raising the channel bed elevation and reconnecting the meadow floodplain most likely reduced summer streamflow. In contrast, we report at least a fivefold increase in baseflow from the meadow in the years following restoration. In addition, we observed that, after restoration, the previously intermittent stream below the meadow flowed continuously throughout the summer months, despite record drought conditions, and in 2015, the lowest snowpack on record. We suggest that the groundwater budget presented in the Discussion may not adequately represent conditions within the meadow because the authors extrapolate from 5 near‐channel groundwater wells across 62 ha of meadow and assume an area of influence that is approximately one‐sixth of the meadow area. We conclude that the conversion of an intermittent stream to perennial flow during drought conditions is a stronger check on our gauge data than the groundwater budget presented in the Discussion.     

Towards resolving the phosphorus chaos created by food systems

Ambio - The chaotic distribution and dispersal of phosphorus (P) used in food systems (defined here as disorderly disruptions to the P cycle) is harming our environment beyond acceptable limits. An...     

Marked spatio-temporal point patterns,periodicity analysis and earthquakes: an analytical extension including hypocenter depth

Environmental and Ecological Statistics - The longitude, latitude and depth of the hypocenter in 3-D space and the date and time of rupture makes an earthquake a “point” in a...     

Trends in onroad transportation energy and emissions

Globally, 1.3 billion on-road vehicles consume 79 quadrillion BTU of energy, mostly gasoline and diesel fuels, emit 5.7 gigatonnes of CO₂, and emit other pollutants to which approximately 200,000 annual premature deaths are attributed. Improved vehicle energy efficiency and emission controls have helped offset growth in vehicle activity. New technologies are diffusing into the vehicle fleet in response to fuel efficiency and emission standards. Empirical assessment of vehicle emissions is challenging because of myriad fuels and technologies, intervehicle variability, multiple emission processes, variability in operating conditions, and varying capabilities of measurement methods. Fuel economy and emissions regulations have been effective in reducing total emissions of key pollutants. Real-world fuel use and emissions are consistent with official values in the United States but not in Europe or countries that adopt European standards. Portable emission measurements systems, which uncovered a recent emissions cheating scandal, have a key role in regulatory programs to ensure conformity between “real driving emissions” and emission standards. The global vehicle fleet will experience tremendous growth, especially in Asia. Although existing data and modeling tools are useful, they are often based on convenience samples, small sample sizes, large variability, and unquantified uncertainty. Vehicles emit precursors to several important secondary pollutants, including ozone and secondary organic aerosols, which requires a multipollutant emissions and air quality management strategy. Gasoline and diesel are likely to persist as key energy sources to mid-century. Adoption of electric vehicles is not a panacea with regard to greenhouse gas emissions unless coupled with policies to change the power generation mix. Depending on how they are actually implemented and used, autonomous vehicles could lead to very large reductions or increases in energy consumption. Numerous other trends are addressed with regard to technology, emissions controls, vehicle operations, emission measurements, impacts on exposure, and impacts on public health.

Implications: Without specific policies to the contrary, fossil fuels are likely to continue to be the major source of on-road vehicle energy consumption. Fuel economy and emission standards are generally effective in achieving reductions per unit of vehicle activity. However, the number of vehicles and miles traveled will increase. Total energy use and emissions depend on factors such as fuels, technologies, land use, demographics, economics, road design, vehicle operation, societal values, and others that affect demand for transportation, mode choice, energy use, and emissions. Thus, there are many opportunities to influence future trends in vehicle energy use and emissions.     

Influence of combustion temperature on the performance of sewage sludge ash as a supplementary cementitious material

The potential for using sewage sludge ash (SSA) as a supplementary cementitious material (SCM) has been investigated. Controlled combustion of sewage sludge collected in Croatia from two wastewater treatment plants produced SSA with different characteristics. These were used to substitute for cement in mortar samples. The chemical composition and physical properties of SSA depend on wastewater composition, the sludge treatment process and the combustion temperature. These factors influence the suitability of SSA to be used as a SCM. For three different combustion temperatures (800, 900 and 1000 °C), it was concluded that properties of fresh mortar were not affected while in the hardened state, the most favorable combustion temperature is 900 °C regarding mechanical properties. Regardless of combustion temperature, for all types of SSA used in mortars as cement replacement (up to 30%), the average decrease in both compressive and flexural strength values was less than 8% for every 10% of added SSA. The results presented indicate that using up to 20% replacement of cement by SSA produces mortars that meet the specific technical requirements analyzed in this work.     

Development of injury risk models to guide CT evaluation in the emergency department after motor vehicle collisions

Abstract

Objective: The clinical evaluation of motor vehicle collision (MVC) victims is challenging and commonly relies on computed tomography (CT) to detect internal injuries. CT scans are financially expensive and each scan exposes the patient to additional ionizing radiation with an associated, albeit low, risk of cancer. Injury risk prediction based on regression modeling has been to be shown to be successful in estimating Injury Severity Scores (ISSs). The objective of this study was to (1) create risk models for internal injuries of occupants involved in MVCs based on CT body regions (head, neck, chest, abdomen/pelvis, cervical spine, thoracic spine, and lumbar spine) and (2) evaluate the performance of these risk prediction models to predict internal injury.

Methods: All Abbreviated Injury Scale (AIS) 2008 injury codes were classified based on which CT body region would be necessary to scan in order to make the diagnosis. Cases were identified from the NASS-CDS. The NASS-CDS data set was queried for cases of adult occupants who sought medical care and for which key crash characteristics were all present. Forward stepwise logistic regression was performed on data from 2010–2014 to create models predicting risk of internal injury for each CT body region. Injury risk for each region was grouped into 5 levels: very low (<2%), low (2–5%), medium (5–10%), high (10–20%), and very high (20%). The models were then tested using weighted data from 2015 in order to determine whether injury rates fell within the predicted risk level.

Results: The inclusion and exclusion criteria identified 5,477 cases in the NASS-CDS database. Cases from 2010–2014 were used for risk modeling (n?=?4,826). Seven internal injury risk models were created based on the CT body regions using data from 2010–2014. These models were tested against data from 2015 (n?=?651). In all CT body regions, the majority of occupants fell in the very low or low predicted injury rate groups, except for the head. On average, 57% of patients were classified as very low risk and 15% as low risk for each body region. In most cases the actual rate of injury was within the predicted injury risk range. The 95% confidence interval overlapped with predicting injury risk range in all cases.

Conclusion: This study successfully demonstrated the ability for internal injury risk models to accurately identify occupants at low risk for internal injury in individual body regions. This represents a step towards incorporating telemetry data into a clinical tool to guide physicians in the use of CT for the evaluation of MVC victims.     

On the Field of Environmental Communication: A Systematic Review of the Peer-Reviewed Literature

The field of environmental communication has reached several milestones since the 1990s, particularly the establishment of environmental communication-related divisions at professional associations and the founding of the journal Environmental Communication in 2007. This systematic review characterizes the peer-reviewed literature on environmental communication to date, examining methods, geography, top-cited articles, and analyzing keyword and titles. Drawing on the Web of Science Core Collection, which archives the Social Sciences Citation Index and the Arts & Humanities Citation Index, the review finds that attention to environmental communication has exploded in recent years and that the field is methodologically open-minded. Scholars have shifted focus from general environmental risk to specifically climate change in the last decade. Implications for the field are discussed.     

Development of Regional Curves for Hydrologic Landscape Regions (HLR) in the Contiguous United States

Regional curves relate drainage area to the bankfull channel characteristics discharge, cross‐sectional area, width, and mean depth. These curves are used for a variety of purposes, including aiding in the field identification of bankfull elevation and in the natural channel design process. When developing regional curves, the degree to which landform, geology, climate, and vegetation influence stream systems within a single physiographic province may not be fully considered. This study examined the use of the U.S. Geological Survey's Hydrologic Landscape Regions (HLR), as well as data from 2,856 independent sites throughout the contiguous United States (U.S.), to develop a set of regional curves (bankfull discharge, cross‐sectional area, width, and mean depth) for (1) the contiguous U.S., (2) each of the 20 HLRs, (3) each of the eight physiographic divisions, (4) 22 of the 25 physiographic provinces, and (5) individual HLRs within the physiographic provinces. These regional curves were then compared to each other, as well as those from the literature. Regional curves developed for individual HLRs, physiographic divisions, and physiographic provinces tended to outperform the contiguous U.S. indicating increased stratification was beneficial. Further stratifying physiographic provinces by HLR markedly improved regional curve reliability. Use of HLR as a basis of regional curve development, rather than physiographic region alone, may allow for the development of more robust regional curves.     

Measuring Urban Water Conservation Policies: Toward a Comprehensive Index

This article (1) discusses existing efforts to measure water conservation policies (WCPs) in the United States (U.S.); (2) suggests general methodological guidelines for creating robust water conservation indices (WCIs); (3) presents a comprehensive template for coding WCPs; (4) introduces a summary index, the Vanderbilt Water Conservation Index (VWCI), which is derived from 79 WCP observations for 197 cities for the year 2015; and (5) compares the VWCI to WCP data extracted from the 2010 American Water Works Association (AWWA) Water and Wastewater Rates survey. Existing approaches to measuring urban WCPs in U.S. cities are limited because they consider only a portion of WCPs or they are restricted geographically. The VWCI consists of a more comprehensive set of 79 observations classified as residential, commercial/industrial, billing structure, drought plan, or general. Our comparison of the VWCI and AWWA survey responses indicate reasonable agreement (ρ = 0.76) between the two WCIs for 98 cities where the data overlap. The correlation suggests the AWWA survey responses can provide fairly robust longitudinal WCP information, but we argue the measurement of WCPs is still in its infancy, and our approach suggests strategies for improving existing methods.