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31.
R. S. Maharia R. K. Dutta R. Acharya A. V. R. Reddy 《Journal of environmental science and health. Part. B》2013,48(2):174-181
Heavy metal distribution in medicinal plants is gaining importance not only as an alternative medicine, but also for possible concern due to effects of metal toxicity. The present study has been focused on emphasizing the heavy metal status and bioaccumulation factors of V, Mn, Fe, Co, Cu, Zn, Se (essential metals) and Cr, Ni, Cd, As and Pb (potentially toxic metals) in medicinal plants grown under two different environmental conditions e.g., near to Khetri copper mine and those in fertile soils of Haridwar, both in India, using Instrumental Neutron Activation Analysis (relative method) and Atomic Absorption Spectrometry. The copper levels in the medicinal plants from Khetri were found to be 3-4 folds higher (31.6–76.5 mg kg?1) than those from Haridwar samples (7.40–15.3 mg kg?1), which is correlated with very high copper levels (763 mg kg?1) in Khetri soil. Among various heavy metals, Cr (2.60–5.92 mg kg?1), Cd (1.47–2.97 mg kg?1) and Pb (3.97–6.63 mg kg?1) are also higher in concentration in the medicinal plants from Khetri. The essential metals like Mn (36.4–69.3 mg kg?1), Fe (192–601 mg kg?1), Zn (24.9–49.9 mg kg?1) and Se (0.13–0.91 mg kg?1) and potentially toxic metals like Ni (3.09–9.01 mg kg?1) and As (0.41–2.09 mg kg?1) did not show much variations in concentration in the medicinal plants from both Khetri and Haridwar. The medicinal plants from Khetri, e.g., Ocimum sanctum, Cassia fistula, Withania somnifera and Azadirachta Indica were found rich in Ca and Mg contents while Aloe barbadensis showed moderately high Ca and Mg. Higher levels of Ca-Mg were found to correlate with Zn (except Azadirachta Indica). The bioaccumulation factors (BAFS) of the heavy metals were estimated to understand the soil-to-plant transfer pattern of the heavy metals. Significantly lower BAF values of Cu and Cr were found in the medicinal plants from Khetri, indicating majority fraction of these metals are precipitated and were immobilized species unsuitable for plant uptake. Overall, Withania somnifera (Ashwagandha) showed very high metal bioaccumulation. 相似文献
32.
Cypermethrin induced significant alterations in protein metabolic profiles in the central nervous system (CNS) and pedipalpal muscle (PM) of crab, Oziotelphusa senex senex, following ambient exposure. While total and soluble proteins decreased in CNS and PM, free amino acids, protease, alanine and aspartate aminotransferase (AlAT and AAT) were elevated at 24 h after exposure. These results thus confirm the prevailing protein hydrolysis and transamination in these tissues of crab, as a consequence of cypermethrin intoxication. Restoration of normalcy by 48 h demonstrates the importance of these metabolic events in counteracting the effects of cypermethrin. the results also suggests the safer utilization potential and ecological compatibility of cypermethrin. 相似文献
33.
A. Bhagyalakshmi S. Venkata Reddy R. Ramamurthi P. S. Reddy 《Chemistry and Ecology》1995,11(2):97-104
Toxicity of an organochloride insecticide, hexachlorocyclohexane (HCH) on the alterations in the growth and silk qualities of silkworm, Bombyx mori L were investigated. HCH yielded higher growth constants (K), indicating impairment of growth of silkworms and silk gland. the decrement in fibroin content is significant. HCH treatment also resulted in considerable reduction in the cocoon, pupal and shell weights, survival and emergence of pupae and number of eggs laid and deterioration in quality and quantity of silk thread. 相似文献
34.
Michael M. Reddy Kotra V. Krishnamurty Eugene Shpirt G. Anders Carlson Leo Hetling 《Environment international》1982,7(5):315-323
Total and particulate metal concentrations, measured during intensive synoptic studies of the Genesee River, NY, correlated with suspended-sediment concentration and river discharge. Dissolved metal concentrations, on the other hand, showed little systematic variation over the length of the river. Metal and sediment fluxes for two elevated-discharged periods peaked at a midbasin sampling site. For most metals at most sampling sties particulate materials comprised over one-half of the total material. Comparison of particulate material metal concentrations, normalized to the measured suspended-sediment concentrations had with basinwide average values shows that sites having low suspended-sediment concentrations had high particulate material metal contents relative to the basin averages, while sites with high suspended-sediment concentration had low metal contents. These results are consistent with a metal transport mechanism in the Genesee River involving (1) a nearly constant dissolved component, (2) a fine acid-soluble component, and (3) a coarse component that is effectively a neutral diluent in the sediment. Chemical factors, such as sediment organic content, also appear to affect metal transport in the Genesee River. 相似文献
35.
Garampalli RH Deene S Reddy CN 《Journal of environmental biology / Academy of Environmental Biology, India》2005,26(4):705-708
In the present investigation a pot culture experiment was conducted using sterile, phosphorus deficient soil to study the effect of flyash at 3 different concentrations (10g, 20g and 30g flyash/kg soil) on the infectivity and effectiveness of VAM fungus Glomus aggregatum in pigeonpea (Cajanus cajan (L.) Millsp.) cv Maruti. The flyash amendment in soil at all the 3 different concentrations was found to affect significantly the intensity of VAM fungal colonization inside the plant roots and also suppressed the formation of VAM fungal structure (vesicles and arbuscules) completely at higher concentration (30g flyash/kg soil). The response of the pigeonpea plants, as judged by their higher and dry weight, under the influence of flyash amendment in VAM fungus infested soils was found to be considerably less (though not significant enough) when compared to the control plants (without flyash) that have otherwise shown significant increase in growth over the plants without Glomus aggregatum inoculation. However, flyash amendment without VAM inoculation was also found to enhance the growth of plants as compared to control plants (without flyash and VAM inoculum). 相似文献
36.
Teuten EL Pedler BE Hangsterfer AN Reddy CM 《Environmental pollution (Barking, Essex : 1987)》2006,144(1):336-344
Three novel halogenated organic compounds (HOCs) have been identified in the blubber of marine mammals from coastal New England with the molecular formulae C(9)H(3)N(2)Br(6)Cl, C(9)H(3)N(2)Br(7), and C(9)H(4)N(2)Br(5)Cl. They were identified using high and low resolution gas chromatography mass spectrometry (GCMS) and appear to be highly brominated analogues of Q1, a heptachlorinated HOC suspected to be naturally produced. These compounds were found in Atlantic white sided dolphin (Lagenorhynchus acutus), bottlenose dolphin (Tursiops truncatus), common dolphin (Delphinus delphis), Risso's dolphin (Grampus griseus), harbor porpoise (Phocoena phocoena), beluga whale (Delphinapterus leucas), fin whale (Balaenoptera physalus), grey seal (Halichoerus grypus), harp seal (Phoca groenlandica) and a potential food source (Loligo pealei) with concentrations as high as 2.7 microg/g (lipid weight). The regiospecificity of C(9)H(3)N(2)Br(6)Cl is suggestive of a biogenic origin. Debromination of C(9)H(3)N(2)Br(6)Cl may be significant in the formation of C(9)H(4)N(2)Br(5)Cl. 相似文献
37.
Gustavo M. Riggio Judith C. Chow Paul M. Cropper Xiaoliang Wang Reddy L.N. Yatavelli Xufei Yang 《Journal of the Air & Waste Management Association (1995)》2018,68(5):463-476
A thermal/optical carbon analyzer (TOA), normally used for quantification of organic carbon (OC) and elemental carbon (EC) in PM2.5 (fine particulate matter) speciation networks, was adapted to direct thermally evolved gases to an electron impact quadrupole mass spectrometer (QMS), creating a TOA-QMS. This approach produces spectra similar to those obtained by the Aerodyne aerosol mass spectrometer (AMS), but the ratios of the mass to charge (m/z) signals differ and must be remeasured using laboratory-generated standards. Linear relationships are found between TOA-QMS signals and ammonium (NH4+), nitrate (NO3?), and sulfate (SO42-) standards. For ambient samples, however, positive deviations are found for SO42-, compensated by negative deviations for NO3?, at higher concentrations. This indicates the utility of mixed-compound standards for calibration or separate calibration curves for low and high ion concentrations. The sum of the QMS signals across all m/z after removal of the NH4+, NO3?, and SO42- signals was highly correlated with the carbon content of oxalic acid (C?H?O?) standards. For ambient samples, the OC derived from the TOA-QMS method was the same as the OC derived from the standard IMPROVE_A TOA method. This method has the potential to reduce complexity and costs for speciation networks, especially for highly polluted urban areas such as those in Asia and Africa.Implications: Ammonium, nitrate, and sulfate can be quantified by the same thermal evolution analysis applied to organic and elemental carbon. This holds the potential to replace multiple parallel filter samples and separate laboratory analyses with a single filter and a single analysis to account for a large portion of the PM2.5 mass concentration. 相似文献
38.
Hilarydoss Sharon Delhiraja Krithika Reddy Kalvala Srinivas Philip Ligy Chand Drupad Benny Belmin 《Environmental science and pollution research international》2021,28(45):63572-63588
Environmental Science and Pollution Research - Sustainable desalination can be achieved by adopting renewable energy-based low-cost and low-impact desalting techniques. In this investigation,... 相似文献
39.
A major, often unrecognized variable regulating plant growth in semi-closed environment is air contaminant. The vapor of propylene glycol (PG), which was used as coolant in growth chambers, has been found to be toxic to corn (Zea mays L.) and soybean (Glycine max L.) plants. PG solution leaked from a valve packing system and volatilized to vapor, which was trapped in a semi-closed growth chamber. Symptoms of leaf edge chlorosis, later developing into necrosis, were observed on the third day of emergence or on the third day after moving healthy plants into the chamber. For young soybean plants, symptoms were slightly different from those observed in corn plants; the chlorosis symptoms were not uniformly distributed on all leaves. Some soybean leaves curled up and others had white spots. This problem was identified by using a portable photoionization detector to obtain instantaneous readings of total volatile organic compound concentrations inside the chambers. The presence of PG in selected chambers was verified using sample collection with solid phase microextraction (SPME) followed by analysis with multi-dimensional gas chromatography mass spectrometry (MD-GC-MS). This information is pertinent to researchers who use controlled environment to grow plants. 相似文献
40.
Effect of pH control at the anode for the electrokinetic removal of phenanthrene from kaolin soil 总被引:14,自引:0,他引:14
Polycyclic aromatic hydrocarbon (PAH)-contaminated soils exist at numerous sites, and these sites may threaten public health and the environment because many PAH compounds are toxic, mutagenic, and/or carcinogenic. PAHs are also hydrophobic and persistent, so conventional remediation methods are often costly or inefficient, especially when the contaminants are present in low permeability and/or organic soils. An innovative technique, electrokinetically enhanced in situ flushing, has the potential to increase soil-solution-contaminant interaction and PAH removal efficiency for low permeability soils; however, the electrolysis reaction at the anode may adversely affect the remediation of low acid buffering capacity soils, such as kaolin. Therefore, the objective of this study was to improve the remediation of low acid buffering soils by controlling the pH at the anode to counteract the electrolysis reaction. Six bench-scale electrokinetic experiments were conducted, where each test employed one of three different flushing solutions, deionized water, a surfactant, or a cosolvent. For each of these solutions, tests were performed with and without a 0.01 M NaOH solution at the anode to control the pH. The test using deionized water with pH control generated a higher electroosmotic flow than the equivalent test performed without pH control, but the electroosmotic flow difference between the surfactant and cosolvent tests with and without pH control was minor compared to that observed with the deionized water tests. Controlling the pH was beneficial for increasing contaminant solubilization and migration from the soil region adjacent to the anode, but the high contaminant concentrations that resulted in the middle or cathode soil regions indicates that subsequent changes in the soil and/or solution chemistry caused contaminant deposition and low overall contaminant removal efficiency. 相似文献